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71.
以2,6-二甲基苯胺为原料,通过重氮化反应制备2,6-二甲基苯腈,经水蒸汽蒸馏法提纯后,采用75%硫酸酸化,再经酸碱法对产物进行脱色和纯化得产物2,6-二甲基苯甲酸,总收率68.4%。工艺简单、操作安全、适合工业化生产。 相似文献
72.
Yong Pan Chen Zhu Wen Bin Zeng Pei Fu Chi Chen Bao Ming Xu Zhong Feng Gao 《Chembiochem : a European journal of chemical biology》2021,22(24):3431-3436
Rapid and sensitive point-of-care testing (POCT) is an extremely critical mission in practical applications, especially for rigorous military medicine, home health care, and in the third world. Here, we report a visual POCT method for adenosine triphosphate (ATP) detection based on Taylor rising in the corner of quadratic geometries between two rod surfaces. We discuss the principle of Taylor rising, demonstrating that it is significantly influenced by contact angle, surface tension, and density of the sample, which are controlled by ATP-dependent rolling circle amplification (RCA). In the presence of ATP, RCA reaction effectively suppresses Taylor-rising behavior, due to the increased contact angle, density, and decreased surface tension. Without addition of ATP, untriggered RCA reaction is favorable for Taylor rising, resulting in a significant height. With this proposed method, visual sensitive detection of ATP without the aid of other instruments is realized with only a 5 μL droplet, which has good selectivity and a low detection limit (17 nM). Importantly, this visual method provides a promising POCT tool for user-friendly molecular diagnostics. 相似文献
73.
测向误差的减小一直以来都是无线电测向精度提高的一个难点,对于不同的测向体制所采用的减小测向误差的方法都不尽相同。本文主要介绍的是相关干涉仪测向体制的基本原理以及通过内插法的应用来减小测向误差的方法。 相似文献
74.
Sumeng Wei Yuling Yang Xiao Feng Shanshan Li Lei Zhou Jingyu Wang Xiaozhi Tang 《International Journal of Food Science & Technology》2020,55(7):2691-2699
Structures and properties of myofibrillar protein gel prepared at different power (300–800 W) were evaluated. Amino acid analysis demonstrated that changes in microwave power did not alter primary structure of gel. However, an increase in microwave power could change higher structures of gel. As microwave power increased, α-helix content decreased and β-sheet content increased. Increased microwave power probably facilitated protein to unfold and expose the internal groups, causing surface hydrophobicity and the formation of disulphide bonds were enhanced, which indicated changes in tertiary and quaternary structures of protein. At 500 W, gel had the best ultrastructure where surface morphology, springiness and water holding capacity reached the optimum. Our findings suggested that microwave at an appropriate power (500 W) could change higher structures of myofibrillar protein gel to achieve desired processing and quality protein gel characteristics. 相似文献
75.
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77.
Li Lei Limin Li Shasha Wang Gaoyang Zhao Yoshifumi Oshima Yang Ren Lei Zhao Lihua Jin Yao Wang Chengshan Li Pingxiang Zhang 《Journal of the European Ceramic Society》2018,38(14):4694-4700
Highly (100)-oriented Ce1-x(Y0.2Zr0.8)xOδ (CYZO) films were prepared on biaxially textured NiW substrates by a chemical solution deposition approach using metal inorganic salts as starting materials. It has been found that both the preferential orientation and surface roughness of CYZO films decrease gradually with increasing of the doping percentage of Y3+ and Zr4+ ions. The epitaxial growth relationship of (220)CYZO//(200)NiW and [00?l]CYZO//[001]NiW was demonstrated by XRD texture measurement as well as atomic resolution STEM observation. XRD, Raman and XPS spectra results indicate that Y3+ and Zr4+ ions were indeed introduced into CeO2 lattice to substitute Ce4+ ions and form cubic fluorite CYZO solid solution. Moreover, CeO2 buffer layer can be endowed a strong enough capability to prevent element diffusion through co-doping of yttrium and zirconium, provided that an optimal doping ratio of them is adopted. This will provide a new approach to fabricating strong-barrier single buffer layer for coated conductor. 相似文献
78.
Han Yan Gu Yi Chen Lei Li Bing Liu Xiang Ming Chen 《International Journal of Applied Ceramic Technology》2020,17(2):790-796
SrLa[Ga1−x(R0.5Ti0.5)x]O4 (R = Mg, Zn) ceramics were prepared by a standard solid state sintering method. The single-phase ceramics with K2NiF4-type layered perovskite structure and I4/mmm space group were obtained, indicating that SrLa(R0.5Ti0.5) and SrLaGaO4 can form the unlimited solid solutions. With increasing x for R = Mg and Zn, εr increases monotonously, the Qf value first increases and then decreases, while τf increases from a negative to a positive value. The optimized microwave dielectric properties were obtained as following: εr = 23.3, Qf = 89 400 GHz, τf = −0.8 ppm/°C for SrLa[Ga0.6(Mg0.5Ti0.5)0.4]O4 and εr = 23.3, Qf = 76 200 GHz, τf = 0.2 ppm/°C for SrLa[Ga0.7(Zn0.5Ti0.5)0.3]O4, indicating that the present solid solution ceramics are the promising candidates as microwave resonator materials for the telecommunication applications. 相似文献
79.
80.
Design and Fabrication of Concentration‐Gradient Generators with Two and Three Inlets in Microfluidic Chips
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A simple and low‐cost method for designing and fabricating concentration‐gradient generators with two and three inlets is proposed which can generate different concentration gradients at varying flow velocities. The microchannel structure was designed in S‐shape and left‐right symmetry. The concentration‐gradient generator was simulated based on the finite element method. The microchannels were processed on a computer numerical control (CNC) engraving and milling machine on poly(methylmethacrylate) substrate, and then two concentration‐gradient generators were fabricated by hot bonding technology. The results of experiment and simulation were compared to prove the feasibility of the method. Flow velocity was an important factor for generating different concentration gradients. The concentration‐gradient profiles of the generators with two and three inlets present approximately linear and quadratic curves. 相似文献