Corrosion and mechanical behavior of fusion bonded epoxy (FBE) in aqueous media

In recent years there have been many reported cases of corrosion failure in cement concrete pipelines. In the majority of cases, the failures have been attributed to rebar corrosion which is caused by the permeability of chloride from low resistivity soil and subsequent attack on a passive layer on an iron bar in the structure. As a possible alternative to cementitious materials, some organic coatings based on olefin, vinyl or epoxy-based polymers have been considered. However, due to a paucity of data on the behavior of these coatings in aqueous media— particularly product water—the possibility of their application in water transmission systems in the Kingdom has not been fully exploited. This paper deals with the studies carried out on the corrosion and mechanical behavior of fusion bonded epoxy (FBE) coating on steel in aqueous media which include product water, distilled water and saline water. The mechanical testings on coating include adhesion, bending and cathodic disbondment testings. The corrosion studies include immersion testing under static and dynamic conditions, autoclave tests and accelerated (salt-fog) tests. The analysis of results indicates chemical inertness of FBE coating in either of the aforementioned water used during testing, good adhesion and no damage to the coating during bending. Cathodic disbondment tests indicate that FBE coating sustains under cathodic protection (CP) conditions. In general, the results of mechanical and corrosion tests indicate that FBE is a promising material for internal coating on steel in water transmission systems.     

Morphological characteristics of copper deposition on stainless steel cathodes

The results of a metallographic study of cathodic copper deposition on 316 stainless steel are presented. In magnetically assisted d.c. electrolysis, characteristic screen-type deposition patterns are observed. Simultaneous hydrogen evolution causes tunnel-type deposits at 30–45° to the horizontal.Nomenclature B _z magnetic flux density, vertical field lines pointing downwards - C electrolyte concentration - CVD cell voltage drop - i _c cathode current density - s cathode-anode separation distance - T temperature - t _e length of electrolysis time     

Mechanical and dynamical mechanical properties of chloroprene rubber and cellulose II composites

Vulcanized composites of chloroprene rubber (CR) with cellulose II (Cel II) as a filler were investigated. Cel II, obtained by the coagulation of cellulose xanthate, was incorporated in the rubber by the traditional method. The filler content varied from 0 to 30 phr. For comparison purposes, carbon black (CB)–CR composites were also studied. The CB amount varied from 0 to 45 phr. The mechanical and dynamic mechanical properties were determined, and the CR composite containing 20 phr of Cel II showed the best set of properties. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2425–2430, 2004     

Crystallization and melting behavior of blends comprising poly(3‐hydroxy butyrate‐co‐3‐hydroxy valerate) and poly(ethylene oxide)

Blends of poly(3‐hydroxy butyrate‐co‐3‐hydroxy valerate) (PHBV) and poly(ethylene oxide) (PEO) were prepared by casting from chloroform solutions. Crystallization kinetics and melting behavior of blends have been studied by differential scanning calorimetry and optical polarizing microscopy. Experimental results reveal that the constituents are miscible in the amorphous state. They form separated crystal structures in the solid state. Crystallization behavior of the blends was studied under isothermal and nonisothermal conditions. Owing to the large difference in melting temperatures, the constituents crystallize consecutively in blends; however, the process is affected by the respective second component. PHBV crystallizes from the amorphous mixture of the constituents, at temperatures where the PEO remains in the molten state. PEO, on the other hand, is surrounded during its crystallization process by crystalline PHBV regions. The degree of crystallinity in the blends stays constant for PHBV and decreases slightly for PEO, with ascending PHBV content. The rate of crystallization of PHBV decreases in blends as compared to the neat polymer. The opposite behavior is observed for PEO. Nonisothermal crystallization is discussed in terms of a quasi‐isothermal approach. Qualitatively, the results show the same tendencies as under isothermal conditions. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2776–2783, 2006     

Hydrogenolysis of alkanes and olefin polymerization on the silica-supported zirconium hydrides: A comparative DFT study

The model reactions of ethylene polymerization and hydrogenolysis of linear alkanes (propane, n-butane, and n-pentane) on the silica-supported zirconium hydrides (Si–O)₃Zr^IVH, (Si–O)₂Zr^IVH₂, and (Si–O)₂Zr^IIIH were studied using the DFT approach. Catalytic processes under study were shown to occur involving different surface hydrides. The ethylene polymerization was found to proceed at comparable rates on the zirconium monohydrides, (Si–O)₃ZrH, and dihydrides, (Si–O)₂ZrH₂. Cleavage of linear alkanes on the monohydrides (Si–O)₃ZrH is thermodynamically unfavorable; however, the dihydrides (Si–O)₂ZrH₂ can act as catalysts of the process under mild conditions. Hydrides of the trivalent zirconium, (Si–O)₂Zr^IIIH, can also contribute to the hydrogenolysis reaction. A feature of all the systems studied is low regioselectivity of the corresponding processes.     

Kinetics of non-congruent dissolution of E-glass fiber in saturated calcium hydroxide solution

The kinetics of non-congruent dissolution of long E-glass fiber in saturated calcium hydroxide solution has been investigated at 25°C in a closed reactor adopting the rotating disc method for the sample holder. The fiber dissolution rate (), measured from the relative loss weight of the fiber after selective dissolution of the attack layer in acetic acid, is a linear function of time, what implies an interfacial dissolution process. However, the kinetics does not stay regular for a long time due to local detachment of the attack layer. The comparison between = f (t) and ′ = f (t) curves, where ′ is the formation rate of the attack layer, shows that the formation of the layer does not only imply the deposit of a bad-crystalline hydrated calcium silicate but the nucleation and growth of solid calcium hydroxide and calcium carbonate resulting from the transfert, to the interface, of ions coming from the liquid phase. This phenomenon was precedently observed by some other authors in the case of glass-fiber reinforced cement matrix.     

(BaTiO3)1-x + (Co0.5Ni0.5Nb0.06Fe1.94O4)x nanocomposites: Structure,morphology, magnetic and dielectric properties

Two phase-based nanocomposites consisting of dielectric barium titanate (BaTiO₃ or BTO) and magnetic spinel ferrite Co_0.5Ni_0.5Nb_0.06Fe_1.94O₄ (CNNFO) have been synthesized through solid state route. Series of (BaTiO₃)_1-x + (Co_0.5Ni_0.5Nb_0.06Fe_1.94O₄)_x nanocomposites with x content of 0.00, 0.25, 0.50, 0.75, and 1.00 were considered. The structure has been examined via X-rays diffraction (XRD) and indicated the occurrence of both perovskite BTO and spinel CNNFO phases in various nanocomposites. A phase transition from tetragonal BTO structure to cubic structure occurs with inclusion of CNNFO phase. The average crystallites size of BTO phase decreases, whereas that for the CNNFO phase increases with increasing x in various nanocomposites. The morphological observations revealed that the porosity is highly reduced, and the connectivity between grains is enhanced with increasing x content. The optical properties have been investigated by UV−vis diffuse reflectance spectroscopy. The deduced band gap energy (E_g) value is found to reduce with increasing the content of spinel ferrite phase. The magnetic as well as the dielectric properties were also investigated. The analysis showed that CNNFO ferrite phase greatly affects the magnetic properties and dielectric response of BTO material. The obtained findings can be useful to enhance the performances of magneto-dielectric composite-based systems.     

On ℤ2ℤ2[u]-additive codes

In this paper, a new class of additive codes which is referred to as ?₂ ?₂[u]-additive codes is introduced. This is a generalization towards another direction of recently introduced ?₂ ?₄-additive codes [J. Borges, C. Fernández-Córdoba, J. Pujol, J. Rif´a, and M. Villanueva, ?₂ ?₄-linear codes: Generator matrices and duality, Designs Codes Cryptogr. 54(2) (2010), pp. 167–179]. ?₂ ?₄-additive codes have shown to provide a promising class of codes with their algebraic structure and applications such as steganography. The standard generator matrices are established and by introducing orthogonality the parity-check matrices are also obtained. A MacWilliams-type identity that relates the weight enumerator of a code with its dual is proved. Furthermore, a Gray map that maps these codes to binary codes is defined and some examples of optimal codes which are the binary Gray images of ?₂ ?₂[u]-additive codes are presented.     

Implementation and performance evaluation of a scheduling algorithm for divisible load parallel applications in a cloud computing environment

Cloud computing is an emerging technology in which information technology resources are virtualized to users in a set of computing resources on a pay‐per‐use basis. It is seen as an effective infrastructure for high performance applications. Divisible load applications occur in many scientific and engineering applications. However, dividing an application and deploying it in a cloud computing environment face challenges to obtain an optimal performance due to the overheads introduced by the cloud virtualization and the supporting cloud middleware. Therefore, we provide results of series of extensive experiments in scheduling divisible load application in a Cloud environment to decrease the overall application execution time considering the cloud networking and computing capacities presented to the application's user. We experiment with real applications within the Amazon cloud computing environment. Our extensive experiments analyze the reasons of the discrepancies between a theoretical model and the reality and propose adequate solutions. These discrepancies are due to three factors: the network behavior, the application behavior and the cloud computing virtualization. Our results show that applying the algorithm result in a maximum ratio of 1.41 of the measured normalized makespan versus the ideal makespan for application in which the communication to computation ratio is big. They show that the algorithm is effective for those applications in a heterogeneous setting reaching a ratio of 1.28 for large data sets. For application following the ensemble clustering model in which the computation to communication ratio is big and variable, we obtained a maximum ratio of 4.7 for large data set and a ratio of 2.11 for small data set. Applying the algorithm also results in an important speedup. These results are revealing for the type of applications we consider under experiments. The experiments also reveal the impact of the choice of the platforms provided by Amazon on the performance of the applications under study. Considering the emergence of cloud computing for high performance applications, the results in this paper can be widely adopted by cloud computing developers. Copyright © 2014 John Wiley & Sons, Ltd.