In Situ Deformation Topology of COFs with Shortened Channels and High Redox Properties for Li–S Batteries

Covalent organic frameworks (COFs) with various topologies are typically synthesized by selecting and designing connecting units with rich shapes. However, this process is time-consuming and labour-intensive. Besides, the tight stacking of COFs layers greatly restrict their structural advantages. It is crucial to effectively exploit the high porosity and active sites of COFs by topological design. Herein, for the first time, inducing in situ topological changes in sub-chemometric COFs by adding graphene oxide (GO) without replacing the monomer, is proposed. Surprisingly, GO can slow down the intermolecular stacking and induce rearrangement of COFs nanosheets. The channels of D- [4+3] COFs are significantly altered while the stacking of periodically expanded framework is weakened. This not only maximizes the exposure of pore area and polar groups, but also shortens the channels and increases the redox activity, which enables high loading while enhancing host-guest interactions. This topological transformation to exhibit the structural features of COFs for efficient application is an innovative molecular design strategy.     

蓝宝石衬底上原子级光滑AlN外延层的MOCVD生长

在蓝宝石衬底表面无氮化、低Ⅴ/Ⅲ比的情况下,采用1200℃的衬底温度、5kPa反应室气压,用MOCVD方法在蓝宝石衬底上生长出了表面原子级光滑的AlN外延层.原子力显微镜测试表明其平均粗糙度为0.44nm,X射线衍射(0002)回摆曲线FWHM为166".实验结果和分析表明,极性和气相反应是影响AlN表面形貌的主要原因.以原子级光滑的AlN为模板生长出了高质量的高Al组分的n型AlGaN,证实了AlN模板具有较好的质量.     

Optimal design of a low-loss 2-bit electrooptic analog-to-digital converter

The structure of the optical waveguide of 2-bit electrooptic A/D converter with proton-exchange micro prisms is optimized by the finite-difference beam propagation method （FD-BPM） The electrode parameters of the converter are optimized by conformal mapping. The optimal parameters are a half- wave voltage of Vπ = 4.5 V and a bandwidth of △f = 1.4 GHz. A normalized transmitted power of 69.75% is obtained by FD-BMP and the output waveguide gap is 300 μm.     

METHOD FOR ALONG-TRACK DUAL-ANTENNA AIRBORNE RADAR''''S GMTI WHEN THE ATENNA ERROR CHANGES PULSE TO PULSE

IntroductionIn recent years the key methods for the airborne radar's Ground Moving Target Indi-cation(GMTI) are Space Time Adaptive Processing (STAP)[1], Synthetic Aperture Radar-Moving Target Indication (SAR-MTI)[2], direct data domain method[3], and so on. Thecharacteristics of the methods are different, STAP needs some space and time degrees offreedom, SAR-MTI needs two precisely corrected SAR images, while direct data domainmethod works with data samples from a single range…     

A variational method for geometric regularization of vascular segmentation in medical images

In this paper, a level-set-based geometric regularization method is proposed which has the ability to estimate the local orientation of the evolving front and utilize it as shape induced information for anisotropic propagation. We show that preserving anisotropic fronts can improve elongations of the extracted structures, while minimizing the risk of leakage. To that end, for an evolving front using its shape-offset level-set representation, a novel energy functional is defined. It is shown that constrained optimization of this functional results in an anisotropic expansion flow which is usefull for vessel segmentation. We have validated our method using synthetic data sets, 2-D retinal angiogram images and magnetic resonance angiography volumetric data sets. A comparison has been made with two state-of-the-art vessel segmentation methods. Quantitative results, as well as qualitative comparisons of segmentations, indicate that our regularization method is a promising tool to improve the efficiency of both techniques.     

基于EPON智能电能表光通信模块的设计与实现

智能电能表光通信模块的研究,在智能电网建设中发挥着重要作用。通过对EPON(以太网无源光网络)、PLC(电力载波通信)和WiMAX(全球微波互联接入)技术的对比分析,选择EPON作为智能电能表通信接入网技术,并设计了通信流程。基于QCA8829嵌入式芯片,在Redhat Linux 2.6.x开发平台上采用可接入EPON系统的光纤接口技术,实现了智能电能表主站与从站的通信系统。经测试表明,基于EPON智能电表光通信模块实现了智能电网配电侧信息全采集、全覆盖,并使远程电费控制及负载控制到户。     

Evaluation of Diffusion Barrier Between Lead-Free Solder Systems and Thermoelectric Materials

The intermetallic compound SnTe rapidly formed at interfaces between p-type bismuth telluride (Bi_0.5Sb_1.5Te₃) thermoelectric materials and lead-free solders. The intermetallic compound influences the mechanical properties of the joints and the reliability of the thermoelectric modules. Various lead-free solder alloys, Sn-3.5Ag, Sn-3Ag-0.5Cu, Sn-0.7Cu, and Sn-2.5Ag-2Ni, were used to investigate the interfacial reactions. The results thus obtained show that Ag and Cu preferentially diffused into the Te-rich phase in Bi_0.5Sb_1.5Te₃, so layers of Ag-Te and Cu-Te compounds could not form an effective diffusion barrier. Electroless nickel-phosphorus was plated at the interfaces to serve as a diffusion barrier, and the (Cu,Ni)₆Sn₅ compound formed instead of SnTe. Furthermore, the intermetallic compound NiTe formed between nickel- phosphorus and Bi_0.5Sb_1.5Te₃ and also served as a diffusion barrier. A plot of thickness as a function of annealing time yielded the growth kinetics of the intermetallic compounds in the thermoelectric material systems. The activation energy for the growth of the NiTe intermetallic compound is 111 kJ/mol.     

A sub-1 V high-precision CMOS bandgap voltage reference

A third-order, sub-1 V bandgap voltage reference design for low-power supply, high-precision applications is presented. This design uses a current-mode compensation technique and temperature-dependent resistor ratio to obtain high-order curvature compensation. The circuit was designed and fabricated by SMIC 0.18 μm CMOS technology. It produces an output reference of 713.6 mV. The temperature coefficient is 3.235 ppm/℃ in the temperature range of -40 to 120 ℃, with a line regulation of 0.199 mV/V when the supply voltage varies from 0.95 to 3 V. The average current consumption of the whole circuit is 49 μA at the supply voltage of 1 V.     

前视阵高速雷达空时处理方法研究

多普勒严重模糊,训练样本有限是高速平台雷达面临的重要问题,协方差矩阵估计误差以及目标约束误差将使处理器性能严重下降。针对上述问题,该文对前视阵杂波自由度进行了研究,分析表明杂波特征谱与孔径带宽积、时宽带宽积以及空时耦合特性有关。该文提出基于主瓣区域空时多波束的鲁棒空时处理方法,首先通过空时多波束降低杂波自由度,然后利用多普勒区间约束的方法,提高了处理器的性能和系统鲁棒性。仿真实验证明了该文方法的有效性,当样本中存在目标信号时,该文方法相比传统固定约束矢量的方法输出信杂噪比性能平均提高5 dB左右。     

meta-Linked spirobifluorene/phosphine oxide hybrids as host materials for deep blue phosphorescent organic light-emitting diodes

This study investigated the use of a novel modification in molecular design to get two new electron-transport host materials, SF3PO and BSF3PO. By linking the phosphine oxide moieties at meta-position of spirobifluorene rings, higher triplet energies could be easily achieved for these two new materials. The steric spirobifluorene structures could guarantee their good thermal stabilities. According to these properties, their applications as host materials for deep blue phosphorescent organic light-emitting diodes (PHOLEDs) were explored. As expected, the deep blue emitting devices with Ir-complex FIr6 as phosphorescent dopants and SF3PO and BSF3PO as hosts had been fabricated and showed high efficiency of 28.5 and 22.0 cd/A, respectively, which were significantly higher than that of the para-linked analogue SPPO1.