Determination of ochratoxin A in organic and non-organic cereals and cereal products from Spain and Portugal

The objective of this work was to know the occurrence of OTA in organic and non-organic cereals and cereal products from Spain and Portugal. A method based on extraction with matrix solid phase dispersion (MSPD) using octylsilica (C₈) followed by liquid chromatography coupled with fluorescence detection (LC–FD) was used to determine OTA from the selected samples. Recoveries of OTA from the studied samples spiked at 10 ng/g level ranged from 78% to 89% with a standard deviation of 3.66. The limits of detection and quantification of this method were 0.05 and 0.19 ng/g, respectively. Furthermore, LC–FD after OTA methylation was used to confirm the identity of OTA in all positive samples. This procedure was applied to 83 organic and non-organic samples including rice, wheat, barley, rye, oats and maize from Spain and Portugal. OTA was detected in 22% of the samples, with concentrations ranging from 0.20 to 27.10 ng/g. From the total OTA contaminated samples (n = 18), 72% were organic cereal and 28% were non-organic cereal samples, with mean concentrations of 1.64 and 0.05 ng/g, respectively. The 66% and 34% of contaminated samples were from Spain and Portugal, respectively, with mean concentrations of 0.93 and 0.64 ng/g for each country. Six contaminated samples exceeded the maximum limits (ML) for OTA fixed by European Commission Regulation (5 μg/kg), among them three were from Spain and three from Portugal.     

Multisensor Demining Robot

The paper describes an advanced multisensor demining robot. The robot transport system is based on a simple structure using pneumatic drive elements. The robot has robust design and can carry demining equipment up to 100 kg over rough terrains. Due to the adaptive possibilities of pedipulators to obstacles, the robot can adjust the working position of the demining sensors while searching for mines. The detection block consists of a metal detector, an infrared detector, and a chemical explosive sensor. The robot is controlled by means of an on-board processor and by an operator remote station in an interactive mode. Experimental results of the transport, control, and detection systems of the robot are presented.Michael Yu. Rachkov is Professor of Automation at the Moscow State Industrial University. He graduated in Automatic Control Systems from Moscow Higher Technical School, 1979. He held academic posts at the Institute for Problems in Mechanics, Russian Academy of Sciences. In 1986 he completed his PhD in industrial robotics and received his DSc in mobile robotics in 1997. Professor Rachkov has been leading in several international projects like EUREKA and REMAPHOS. He has published over 170 papers and several books in the field of automation, robotics and optimal control. He is a member of Russian Cosmonautics Academy and International Informatization Academy.Lino Marques is a research engineer at the Institute of Systems and Robotics of the University of Coimbra. He received the Engineering and MsC. degrees in Electrical Engineering from the Faculty of Science and Technology of this University in 1992 and 1997 respectively. He is currently working toward the Ph.D. degree and teaching in the Electrical and Computer Engineering Department. His current research interests include sensors, mechatronics, mobile robotics and industrial automation.Anábal T. De Almeida graduated in Electrical Engineering, University of Porto, 1972, and received a Ph.D. in Electrical Engineering, from Imperial College, University of London, 1977. Currently he is a Professor in the Department of Electrical Engineering, University of Coimbra, and he is the Director of the Institute of Systems and Robotics since 1993. Professor De Almeida is a consultant of the European Commission Framework Programmes. He is the co-author of five books and more than one hundred papers in international journals, meetings and conferences. He has coordinated several European and national research projects.     

MAOC降凝剂的研究

含蜡原油和柴油低温流动性是迫切需要解决的问题．ＭＡＯＣ降凝剂对大庆原油和鞍山２０重柴油的纯降凝度是１０℃和１３℃．结合热处理加入０．５％～１．０％（Ｗ）ＭＡＯＣ剂，在一定条件下可使大庆原油疑点降低２０～２２℃．同时对ＭＡＯＣ剂的使用条件、影响因素进行了考查．对合成ＭＡＯＣ剂的原料、中间产品和产品进行了分析．推算出ＭＡＯＣ剂的主要结构．     

Water–formaldehyde–hydrogen sulfide system. II. Formation and growth of thiomethylenic chains.

A linear polymer with a high melting point is obtained from the water–formaldehyde–hydrogen sulfide system in the presence of sulfuric acid. This polymer is substantially formed by a polythiomethylene chain with a few oxymethylene units. Its formation involves a topochemical reaction of the mercaptomethanol present in solution on the first separation solid of the system. On heating, the polymer loses oxymethylene units; in the same way, the first solid product separated from the system loses formaldehyde and undergoes a morphological and chemical transformation to polythiomethylene.     

Designing waveforms for temporal encoding using a frequency sampling method

In this paper a method for designing waveforms for temporal encoding in medical ultrasound imaging is described. The method is based on least squares optimization and is used to design nonlinear frequency modulated signals for synthetic transmit aperture imaging. By using the proposed design method, the amplitude spectrum of the transmitted waveform can be optimized, such that most of the energy is transmitted where the transducer has large amplification. To test the design method, a waveform was designed for a BK8804 linear array transducer. The resulting nonlinear frequency modulated waveform was compared to a linear frequency modulated signal with amplitude tapering, previously used in clinical studies for synthetic transmit aperture imaging. The latter had a relatively flat spectrum which implied that the waveform tried to excite all frequencies including ones with low amplification. The proposed waveform, on the other hand, was designed so that only frequencies where the transducer had a large amplification were excited. Hereby, unnecessary heating of the transducer could be avoided and the signal-to-noise ratio could be increased. The experimental ultrasound scanner RASMUS was used to evaluate the method experimentally. Due to the careful waveform design optimized for the transducer at hand, a theoretic gain in signal-to-noise ratio of 4.9 dB compared to the reference excitation was found, even though the energy of the nonlinear frequency modulated signal was 71% of the energy of the reference signal. This was supported by a signal-to-noise ratio measurement and comparison in penetration depth, where an increase of 1 cm was found in favor for the proposed waveform. Axial and lateral resolutions at full-width half-maximum were compared in a water phantom at depths of 42, 62, 82, and 102 mm. The axial resolutions of the nonlinear frequency modulated signal were 0.62, 0.69, 0.60, and 0.60 mm, respectively. The corresponding axial resolutions for the reference waveform were 0.58, 0.65, 0.62, and 0.60 mm, respectively. The compression properties of the matched filter (mismatched filter for the linear frequency modulated signal) were tested for both waveforms in simulation with respect to the Doppler frequency shift occurring when probing moving objects. It was concluded that the Doppler effect of moving targets does not significantly degrade the filtered output. Finally, in vivo measurements are shown for both methods, wherein the common carotid artery on a 27-year-old healthy male was scanned.     

Drift velocity and diffusivity of hot carriers in germanium: Model calculations

A simple analytical model with two adjustable parameters is employed in describing the drift velocity and longitudinal diffusion coefficient of charge carriers (electrons and holes) in purified germanium, over a wide range of electric field (10-10⁴ V/cm). The effects of the lattice temperature for the range 130–300 K are also considered, and a comparison with experimental data is made. The model may be used for the simulation of the behaviour of germanium devices.     

Experimental studies on chemical concentration map building by a multi-robot system using bio-inspired algorithms

In this article we describe implementations of various bio-inspired algorithms for obtaining the chemical gas concentration map of an environment filled with a contaminant. The experiments are performed using Khepera III and miniQ miniature mobile robots equipped with chemical gas sensors in an environment with ethanol gas. We implement and investigate the performance of decentralized and asynchronous particle swarm optimization (DAPSO), bacterial foraging optimization (BFO), and ant colony optimization (ACO) algorithms. Moreover, we implement sweeping (sequential search algorithm) as a base case for comparison with the implemented algorithms. During the experiments at each step the robots send their sensor readings and position data to a remote computer where the data is combined, filtered, and interpolated to form the chemical concentration map of the environment. The robots also exchange this information among each other and cooperate in the DAPSO and ACO algorithms. The performance of the implemented algorithms is compared in terms of the quality of the maps obtained and success of locating the target gas sources.     

Biomechanical Strain Exacerbates Inflammation on a Progeria‐on‐a‐Chip Model

Organ‐on‐a‐chip platforms seek to recapitulate the complex microenvironment of human organs using miniaturized microfluidic devices. Besides modeling healthy organs, these devices have been used to model diseases, yielding new insights into pathophysiology. Hutchinson‐Gilford progeria syndrome (HGPS) is a premature aging disease showing accelerated vascular aging, leading to the death of patients due to cardiovascular diseases. HGPS targets primarily vascular cells, which reside in mechanically active tissues. Here, a progeria‐on‐a‐chip model is developed and the effects of biomechanical strain are examined in the context of vascular aging and disease. Physiological strain induces a contractile phenotype in primary smooth muscle cells (SMCs), while a pathological strain induces a hypertensive phenotype similar to that of angiotensin II treatment. Interestingly, SMCs derived from human induced pluripotent stem cells of HGPS donors (HGPS iPS‐SMCs), but not from healthy donors, show an exacerbated inflammatory response to strain. In particular, increased levels of inflammation markers as well as DNA damage are observed. Pharmacological intervention reverses the strain‐induced damage by shifting gene expression profile away from inflammation. The progeria‐on‐a‐chip is a relevant platform to study biomechanics in vascular biology, particularly in the setting of vascular disease and aging, while simultaneously facilitating the discovery of new drugs and/or therapeutic targets.     

Synthesis of Fractional-order PI Controllers and Fractional-order Filters for Industrial Electrical Drives

This paper introduces an electrical drives control architecture combining a fractional-order controller and a setpoint pre-filter. The former is based on a fractional-order proportional-integral (PI) unit, with a non-integer order integral action, while the latter can be of integer or non-integer type. To satisfy robustness and dynamic performance specifications, the feedback controller is designed by a loop-shaping technique in the frequency domain. In particular, optimality of the feedback system is pursued to achieve input-output tracking. The setpoint pre-filter is designed by a dynamic inversion technique minimizing the difference between the ideal synthesized command signal (i.e., a smooth monotonic response) and the prefilter step response. Experimental tests validate the methodology and compare the performance of the proposed architecture with well-established control schemes that employ the classical PIbased symmetrical optimum method with a smoothing pre-filter.