慢走丝电火花线切割粗加工仿真系统的开发

为对电火花线切割加工机理有更深刻的认识,了解加工参数对加工精度的影响规律,介绍了一个电火花线切割加工粗加工的仿真系统。仿真系统通过对放电点的探索、工件的去除以及对线电极丝振动的分析,将实际的加工现象形象地再现于计算机上。为证实仿真系统的正确性,将仿真结果与试验结果进行了比较。在试验结果的获取中,为能够得到很难测量的线电极周围的放电间隙和工件形状数据,提出一种新的三维形状测量方法。通过对仿真结果和试验结果的比较,定性地证明了仿真方法的正确性。研究结果表明:改变线电极张力及伺服电压值时,从仿真过程得到的加工形状结果与试验得到的加工形状结果其倾向基本一致;加工缝端部的形状呈凸形还是呈凹形,取决于加工过程中放电爆发力和静电引力的相对大小。     

NBG焊接质量控制在不锈钢管道上的探索与应用

为了保证焊接质量及生产效率,采用无背部保护气（NBG）工艺将STT半自动封底焊技术应用于316L奥氏体不锈钢管道的对接,实现了管道对接单面焊双面成形。同时,从STT焊接工艺试验以及焊接全过程出发,针对NBG焊口的固定焊,进行了焊接过程控制,并提出了常见焊接缺陷的规避措施。NBG焊接技术的应用,既实现了奥氏体不锈钢管的背部免充氩气保护焊接,同时避免了由于充气导致的潜在不安全因素的产生。研究结果为STT在不锈钢管道焊接质量控制以及推广提供参考。     

FLOW PATTERNS THROUGH TUBE BUNDLES AND PARTICULATE FOULING ONTO CYLINDERS

ABSTRACT

The shear-stress distributions around cylinders in tube bundles were measured by means of the limiting current method and the flow inside the bundle was also visualized. In the case of the staggered bundle, the shear-stress distributions had two peaks by the effect of the jet streams generated at the front row spacing and the adjacent cylinder. While in the bundle with in-line arrangement, the front stagnant point was shifted about 30° downward and the traverse streams among the rows were observed. This traverse streams caused asymmetry of the shear-stress distributions with respect to the main flow axis.

These results were discussed in connection with the fouling experiments investigated in dusty air. Particle deposition around cylinders could be qualitatively predicted from the shear-stress distributions, namely particles tend to deposit at positions where are less shear-stress in both tube arrangements. The size of particle deposited on the wake zone was coarser than that near the stagnant point behind the third row in both arrangements.     

SOL-GEL PREPARATION AND CHARACTERIZATION OF MULTIFERROIC BiFeO3 THIN FILMS WITH VARIOUS BI/FE RATIO

ABSTRACT

BiFeO₃ thin films have been prepared on Pt/TiO₂/SiO₂/Si substrates by sol-gel method using precursor solutions of various elemental ratio (Bi:Fe = 1.1:1.0, 1.0:1.0, and 1.0:1.1). The θ < eqid2 > 2θ scan XRD patterns show all the films consist mainly of polycrystalline perovskite and the crystallinity of Bi:Fe = 1.1:1.0 is better than the others. SEM and AFM images show all BiFeO₃ film have rosette structures, which consist of perovskite phase and matrix phase. The leakage current density measured at the temperature of 80 K is lower than 10^?4 A/cm² in all the films when the electric field reaches 1.6 MV/cm. The leakage mechanism of BiFeO₃ thin film is dominated by Schottky conduction at 80 K. At 80 K, the remanent polarizations at maximum applied voltage of 2.8 MV/cm are 100, 49, and 44 μC/cm² for the ratio of Bi:Fe = 1.1:1.0, 1.0:1.0, and 1.0:1.1, respectively. The saturated magnetization of BiFeO₃ thin films at 80 K were found to be 14, 22.5, 15 emu/cm³ for the ratio of Bi:Fe = 1.1:1.0, 1.0:1.0, and 1.0:1.1, respectively. Among these ratio, BiFeO₃ thin film deposited from precursor of Bi:Fe = 1. 1:1.0 gives the best ferroelectric property.     

A Highly-Sensitive Ba(Ti1—xSnx)O3 Thin Film Dielectric Bolometer for Uncooled IR Sensor

Ba(Ti_1—xSn_x)O₃ (BTS) ferroelectric thin films have been prepared by metal-organic decomposition method whose final annealing temperature was optimized to 700°C for dielectric bolometer. High temperature coefficient of dielectric constant (TCD) of 1–3%/K and low dielectric loss of 0.04 have been obtained in x = 0.15 and 0.17. Field-induced pyroelectricity of the BTS film was calculated to be an excellent value as high as 750 nC/cm²K. A series of dependence of DB output level were examined on important operation factors. The DB output level was increased when the period of supply voltage waveform is longer than both the electrical and thermal time constant of the DB detector. Finally, a stable infrared detection at temperature lower than 30°C was confirmed.     

两种鲤鱼鱼鳞胶原蛋白性质异同分析

本研究以鲤鱼鱼鳞为原料,研究了乙酸提取法和胃蛋白酶提取法得到的两类鱼鳞胶原蛋白ASC(acid solublecollagen)和PSC(pepsin soluble collagen)的异同。经过SDS-凝胶电泳可以看到,两种蛋白之间在分子α-链组成、分子量大小等方面的差异不明显,两种蛋白经蛋白酶K有限酶解以后的肽段图谱也很相似。但从差热分析(DSC)图谱和CD图谱看,二者之间在热稳定性方面存在一定的差异,对于热稳定性存在差异的原因与蛋白质制备过程中胃蛋白酶的作用有关。     

SOLVENT EXTRACTION EQUILIBRIA OF TRIS(BENZOYL- TRIFLUOROACETONATO)COMPLEX OF COBALT(II) AND NICKEL(II) AS ION-PAIRS WITH TETRABUTYLAMMONIUM

Abstract

Solvent extraction of cobalt(Il) and nickel(II) in aqueous 1 mol dm^?3 NaCl solutions with benzoyltrifluoro-acetone(Hbfa) in carbon tetrachloride has been measured in the absence and presence of tetrabutylammonium(tba⁺). In the absence of tba⁺, M(bfa)₂ species is extracted and the extraction of cobalt(II) is better in the higher Hbfa concentration range but in the presence, M(bfa)₃ ^?tba⁺ type ion-pair is extracted and the extraction of nickel-(II) is always better. This is explained in terms that although the bis-nickel(II) complex is more stable, it is much more strongly hydrated than the bis-cobalt(II) complex and consequently its extraction is hindered but in the tris-complexes such a large difference of the hydration may not occur and the more stable nickel(II) complex is extracted better.