Nanolayer CrAlN/TiSiN coating designed for tribological applications

With the goal to produce a hard and tough coating intended for tribological applications, CrAlN/TiSiN nanolayer coating was prepared by alternative deposition of CrAlN and TiSiN layers. In the first part of the article, a detailed study of phase composition, microstructure, and layer structure of CrAlN/TiSiN coating is presented. In the second part, its mechanical properties, fracture and tribological behavior are compared to the nanocomposite TiSiN coating. An industrial magnetron sputtering unit was used for coating deposition. X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy were used for compositional and microstructural analysis. Mechanical properties and fracture behavior were studied by instrumented indentation and focused ion beam techniques. Tribological properties were evaluated by ball-on-disk test in a linear reciprocal mode. A complex layer structure was found in the nanolayer coating. The TiSiN layers were epitaxially stabilized inside the coating which led to formation of dislocations at interfaces, to introduction of disturbances in the coating growth, and as a result, to development of fine-grained columnar microstructure. Indentation load required for the onset of fracture was twice lower for the nanolayer CrAlN/TiSiN, compared to the nanocomposite TiSiN coating. This agrees very well with their mechanical properties, with H³/E² being twice higher for the TiSiN coating. However, the nanolayer coating experienced less severe damage, which had a strong impact on tribological behavior. A magnitude of order lower wear rate and four times lower steady state friction coefficient were found for the nanolayer coating.     

High surface area MoO3/MgO: preparation by the new slurry impregnation method and activity in sulphided state in hydrodesulphurization of benzothiophene

High surface area MoO₂/MgO was prepared by the reaction of MgO (250–300 m² g⁻¹) with a slurry of ammonium heptamolybdate in methanol or anhydrous ethanol at the alcohol boiling point. The low solubility of ammonium heptamolybdate was sufficient for its gradual transport to the support surface: molybdena species were deposited and ammonia was evolved. Catalytic activities in the hydrodesulphurization of benzothiophene of the MoO₃/MgO samples were comparable to the activity of the reference commercial MoO₃/Al₂O₃ catalyst. This revised version was published online in July 2006 with corrections to the Cover Date.     

The energy intensity in Lithuania during 1995–2009: A LMDI approach

The measurement, assessment, and effective mitigation of energy intensity compose a foremost objective of contemporary energy policy. Although the European Union (EU) Member States have been experiencing the convergence in energy efficiency indicators, Lithuania, acceded to the EU in 2004, still remains peculiar with relatively high energy intensity. Our study, therefore, is aimed at analyzing the energy intensity trends in Lithuanian economy as a whole as well as in separate economic sectors. The investigation covers the period of 1995–2009. The Logarithmic Mean Divisia Index was applied for decomposition analysis. Our analysis has shown that energy efficiency falls during economic downturn. In order to facilitate these challenges the Lithuanian Government as well as business should opt for increasing energy efficiency in the most problematic sectors of transport and services. In addition, the analysis of legal acts, namely National Energy Efficiency Programme for 2006–2010 and Energy Efficiency Action plan for 2010–2016, was taken into consideration. Some suggestions, thus, were offered for successful implementation of strategic goals outlined in the aforementioned strategic documents.     

Modeling of the FCC Gasoline Desulfurization Process by Liquid Extraction with Sulfolane

Abstract

Extractive desulfurization of fluid catalytic cracking (FCC) gasoline with sulfolane was studied in a batch apparatus. The influence of three inlet parameters (temperature, inlet sulfur content, and solvent ratio) on the process response, that is, desulfurization efficiency, was investigated with the use of a Box-Behnken experimental design by response surface methodology. A mathematical model that can be used for predicting sulfur content in raffinate after extractive batch processing with sulfolane was statistically developed and proven with analysis of variance. Statistical analysis showed that the largest influence on desulfurization efficiency was solvent ratio, the second most significant influence was inlet sulfur content, followed by temperature, and last the interaction between solvent ratio and inlet sulfur content. The obtained second-order polynomial model shows that maximum desulfurization efficiency of 65.34% can be achieved at temperature of 50°C and higher values of inlet sulfur content and solver ratio in the researched range of inlet parameter values.     

Controllable Broadband Absorption in the Mixed Phase of Metamagnets

Materials with broad absorption bands are highly desirable for electromagnetic filtering and processing applications, especially if the absorption can be externally controlled. Here, a new class of broadband‐absorption materials is introduced. Namely, layered metamagnets exhibit an electromagnetic excitation continuum in the magnetic‐field‐induced mixed ferro‐ and anti­ferromagnetic phase. Employing a series of complementary experimental techniques involving neutron scattering, muon spin relaxation, specific heat, ac and dc magnetization measurements, and electron magnetic resonance, a detailed magnetic phase diagram of Cu₃Bi(SeO₃)₂O₂Br is determined and it is found that the excitations in the mixed phase extend over at least ten decades of frequency. The results, which reveal a new dynamical aspect of the mixed phase in metamagnets, open up a novel approach to controllable microwave filtering.     

Primary vacuum standard for UHV range — Standing experience and present problems

Accurate calibrations of gauges to ever lower pressures (higher vacuum) are increasingly becoming necessary. The calibrations over the entire ultra high vacuum (UHV) range i.e. up to 10⁻¹⁰ Pa are already sometimes demanded by the users of vacuum measuring devices. Standards covering part of this range are available in some national metrological laboratories while primary standards covering the entire UHV range are under development. However, the most suitable principle of the primary standard for generating such a low pressure is still not clear. In spite of some attempts during the last century no sufficiently accurate absolute (“calibration-free”) gauge for high vacuum (HV) and UHV ranges has been developed to date. Apparatuses for generating gas pressure in a dynamic flow control method will continue to be used as primary standards for the UHV range, but, by virtue of technical difficulties, the equilibrium (Maxwellian velocity distribution) will be severely disturbed during the process of pressure generation that the pressure in the chamber will not be defined as a simple scalar quantity. This principal problem must be solved first by the development of a primary UHV standard. Another serious problem in the design of an apparatusfor generating controlled pressures on the order of 10⁻¹⁰ Pa requires the uncontrolled changes of gas pressure to 10⁻¹² Pa or lower. Hence an extremely high vacuum (XHV) apparatus must be used in which the requirements concerning the pumps and the outgassing rate from the materials are kept very strict.     

Distribution of the carbide phase in the viscoplastic layer during the rotational friction-welding of various steels

The paper presents the viscoplastic phenomena observed during the rotational friction-welding process of high-speed steel M2 (AISI SAE) with carbon steel 1060 (AISI SAE). The structure, phase composition and distribution of the carbide phase in the friction plane and adjoining zones are examined by using optical microscopy (OM) with a system for quantitative analysis, and scanning electron microscopy (SEM) in addition to EDS analysis. The experimentally-checked mathematical relationship is suggested for the calculation of the radial movements of the carbide phase, immediately next to the friction plane. On the basis of qualitative and quantitative evaluation of the microstructural and rheological appearances, a model of carbide phase distribution is also established in the viscoplastic and viscous layers in the area of the friction plane.     

Mechanochemical reaction in the K2CO3–Nb2O5 system

We studied the mechanochemical synthesis of KNbO₃, starting from a powder mixture of K₂CO₃ and Nb₂O₅. The milling experiments were designed with different ball-impact energies in order to investigate the mechanochemical reactions. X-ray diffraction, thermogravimetric analysis, infrared spectroscopy, Raman spectroscopy and transmission electron microscopy were used to characterize the samples. Based on the results, we propose a mechanism for the mechanochemical reaction between K₂CO₃ and Nb₂O₅. The first stage of the reaction is characterized by the formation of an amorphous carbonato complex, which decomposes after prolonged milling at higher ball-impact energy giving rise to the crystallization of KNbO₃ and other niobate phases with a molar ratio K/Nb < 1. The reaction course is discussed and compared with the Na₂CO₃–Nb₂O₅ system.     

“Tropicalisation” of Feed-in Tariffs: A custom-made support scheme for hybrid PV/diesel systems in isolated regions

The interest and actions towards introducing renewables for off-grid regions has increased due to their ostensible cost-effectiveness, eco-friendliness and quality services provided. Nevertheless, in many isolated areas diesel generators appear as a common option, confirming that there is a need for financial support mechanisms that aid the introduction of renewables due to their higher initial investment costs.This paper proposes a so-called ‘tropicalisation’ of the Feed-in Tariff scheme to promote the introduction of hybrid systems in isolated communities based on the idea of awarding for each kWh produced by renewable energies a premium value during a guaranteed period of time. The proposed Renewable Energy Premium Tariff (RPT) scheme is an alternative mechanism to the usual initial investment donation for off-grid energy development projects by recognising the production of renewable electricity and opting for a long-term sustainability of the projects. Ecuador presents ideal conditions to study the introduction of such a ‘tropicalised’ scheme since a Feed-in Law including off-grid projects was established in 2002 and since there are governmental and local efforts for the introduction of renewable hybrids in isolated regions.Modelling of the introduction of photovoltaics (PVs) into diesel systems for several mini-grids located in isolated regions of Ecuador has been performed, and included a detailed financial analysis for optimisation of RPT values and a comparison with existing stand-alone diesel systems. The results show the cost-effectiveness of PV/diesel hybrids over diesel gensets, taking into account present and future diesel prices. To obtain long-term sustainability of the project, the RPT values are set at 0.70–1.20$ kWh covering the operability of the whole system for 20 years, where the renewable fraction should have the largest share in the hybrid system. The proposed mechanism is expected to aid the introduction of renewable technologies to bring solutions and sustainable energy options to final users of off-grid isolated regions.     

Modeling the energy potential of biomass – H2RES

Modeling biomass as a renewable energy source poses many challenges with respect to feedstock variability, which are difficult to account for. It is found that at the preliminary stages of energy planning, heating value and moisture content of the feedstock are the most important factors. In addition, the effects of harvesting, transportation and storage are found to be significant even though they are often overlooked. Using the gathered information a biomass module for energy planning is created and integrated to H₂RES, a renewable energy planning program. Using this excel based software, a case study for a wood processing factory is performed, using the waste wood as feedstock. Comparing various scenarios, it is concluded that using a combination of solid oxide fuel cells, solar panels and steam turbines can satisfy the factories energy requirements with excess sold to the grid.