Fracture toughness and fracture mechanisms of PBT/PC/IM blend

The static and impact fracture toughnesses of a polybutylene terephthalate/polycarbonate/impact modifier (PBT/PC/IM) blend were studied at different temperatures. The static fracture toughness of the blend was evaluated via the specific fracture work concept and the J-integral analysis. A comparison of these two analytical methods showed that the specific essential fracture work, W _e, was equivalent to the obtained by the ASTM E813-81 procedure, representing the crack initiation resistance of the material. The discrepancy between W _e and of ASTM E813-89 was caused by the extra energy component in consumed by a 0.2 mm crack growth. Impact fracture toughness was also analysed using the specific essential fracture work approach. When the fracture was elastic, W _e was equivalent to the critical potential energy release rate, G _IC, obtained via LEFM analysis. Temperature and strain-rate effects on the fracture toughness were also studied. The increase in impact toughness with temperature was attributed to two different toughening mechanisms, namely, the relaxation processes of the rubbery particles and the parent polymers in a relatively low-temperature range and thermal blunting of the crack tip at higher temperatures. The enhancement in static fracture toughness at temperatures below — 60 °C was thought to be caused by plastic crack-tip blunting, but the monotonic reduction in yield stress was largely responsible for the toughness decreasing with higher temperatures. The temperature-dependent fracture toughness data obtained in static tests could be horizontally shifted to match roughly the data for the impact tests, indicating the existence of a time-temperature equivalence relationship.     

The essential work of fracture for tearing of ductile metals

A simple energy balance analysis is presented for the tearing of ductile sheet metals using the trousers test. It is shown that the specific essential work of fracture (w _e ) for tearing can be estimated by extrapolating the straight line relationship between the tearing force per unit thickness and the trousers leg width to zero leg width. There are two contributions to the specific essential work of fracture: one is due to the localised plastic shearing work in a zone contiguous with the torn edges (w _e1 ) and the other is the final out-of-plane tearing work (w _e2 ).

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Résumé En utilisant le Trousers Test, on présente une analyse simple d'équilibre énergétique dans le cas du déchirement de feuilles métalliques ductiles. On montre qu'il est possible d'estimer le travail spécifique de rupture en déchirement w _e en extrapolant la relation linéaire qui lie la force de déchirement par unité d'épaisseur et la largeur de l'échantillon caractéristique entre une valeur 0 et une valeur donnée. Deux éléments contribuent au travail spécifique essentiel de rupture, l'un est dû au travail de cisaillement plastique local dans une zone contigue aux bords de l'arrachement (w _e1 ) et l'autre est le travail de déchirement final hors du plan de la feuille (w _e2 ).

     

Structure and function of maladaptive cognitions in Pathological Internet Use among Chinese adolescents

This study empirically investigated the structure and function of maladaptive cognitions related to Pathological Internet Use (PIU) among Chinese adolescents. To explore the structure of maladaptive cognitions, this study validated a Chinese Adolescents’ Maladaptive Cognitions Scale (CAMCS) with two samples of adolescents (n1 = 293 and n2 = 609). The results of the exploratory factor analysis and confirmatory factor analysis revealed that CAMCS included three distinct factors, namely, “social comfort,” “distraction,” and “self-realization.” To examine the function of maladaptive cognitions, this study tested an updated cognitive-behavioral model in the third sample of 1059 adolescents. The results of structural equation model analyses verified both the direct effect of maladaptive cognitions on PIU and their mediating role in the relationships between distal factors (social anxiety and stressful life events) and PIU among Chinese adolescents. Theoretical and practical implications of these findings were discussed.     

The essential work of plane stress ductile fracture of a strain-aged steel

The paper reports the results of an experimental investigation on the essential work of fracture of a strain-aged low carbon (0.1% C) temper-rolled 16-gauge sheet steel which has been subjected to pre-strain levels of 2 to 12% and ageing temperatures of 80 and 100C. Deep edge-notched tension specimens were used to determine the specific essential work by extrapolating the straight-line relationship between the specific work of fracture (W _f) and ligament length (I) to zero ligament length. The strain-aged steels at 80 and 100 give approximately the same specific essential fracture work of 0.18 to 0.20 J mm^–2 which is independent of the amount of prestrain. Advancing crack opening displacements (C.O.D.) have also been analysed, which give 0.60 to 0.63 mm for the strain-aged steels. For comparison, the prestrained but unaged steels have a higher essential work of fracture of 0.275 J mm^–2 and a larger C.O.D. of 0.73 mm. It is concluded, therefore, that the causes of strain-ageing embrittlement are primarily due to the reduction of both the essential work of fracture and the advancing C.O.D. at the crack tip end region.     

交联型水性聚氨酯树脂的合成研究

用聚乙二醇和甲苯二异氰酸酯等进行预聚反应制备交联型水性聚氨酯树脂。系统地研究了nNCO／nOH(聚乙二醇)值对膜力学性能及玻璃化转变温度的影响，并考察了nNCO/nOH(总)值及交联剂三羟甲基丙烷的用量对乳液稳定性的影响。     

On the environmental fracture of polymethylmethacrylate

Crack propagation of PMMA in some liquid environments is described for various testing conditions, such as fixed load, fixed displacement and monotonically increasing displacement. Fracture mechanics concepts have been used successfully in analysing the results. When continuous stable cracking is achieved, values of fracture toughness (R) for PMMA under these loading conditions are obtained as a function of crack velocity () using the method of Gurney and Hunt [11]. For crack velocities greater than 10^–2 mm sec^–1, the fracture toughness values in the environments are increased when compared with the corresponding air results. Unique relationships betweenR and have been shown to exist for cracking in ethanol and carbon tetrachloride.     

Mode III fracture of a magnetoelectroelastic layer: exact solution and discussion of the crack face electromagnetic boundary conditions

This paper develops a closed-form solution for anti-plane mechanical and in plane electric and magnetic fields in a magnetoelectroelastic layer of finite thickness. Explicit expressions for the stresses, electric fields, and magnetic fields, together with their intensity factors are obtained for the extreme cases for impermeable and permeable cracks. Solutions for some special cases, such as a magnetoelectroelastic layer with infinite thickness, are also obtained. Applicability of the crack face electromagnetic boundary conditions is discussed. It is found that the crack profile is important in obtaining the correct electromagnetic fields and their intensity factors. The stress intensity factor, however, does not depend on the crack face electromagnetic boundary condition assumptions.     

Micro- and nano-scale deformation behavior of nylon 66-based binary and ternary nanocomposites

The primary aim of this paper is to provide an insight on the effect of the location of organoclay on the micro- and nano-scale deformation processes in melt-compounded nylon 66/organoclay/SEBS-g-MA ternary nanocomposites prepared by different blending sequences. In addition, the deformation processes of the ternary nanocomposites were compared to the binary nanocomposites (nylon 66/organoclay and nylon 66/SEBS-g-MA) and neat nylon 66. The incorporation of SEBS-g-MA particles toughened nylon 66 markedly; but the flexural modulus and strength were both reduced. Conversely, the use of organoclay increased the modulus but decreased the fracture toughness of nylon 66. Nylon 66/SEBS-g-MA/organoclay ternary nanocomposites exhibited balanced elastic stiffness and toughness. Stress-whitening studies of the fracture surfaces in terms of gray level were also performed and an attempt was made to correlate the optical reflectivity characteristics with fracture toughness. It was concluded that the capability of SEBS-g-MA particles to cavitate was decreased by the presence of organoclay in the SEBS-g-MA phase, resulting in reduced toughening efficiency. The best micro-structure for toughness and other mechanical properties is thus to maximize the amount of exfoliated organoclay in the nylon 66 matrix rather than to have it embedded in the finely dispersed SEBS-g-MA particles.     

Advances in Vapor Pressure Modeling for Electronic Packaging

Two advanced techniques have been developed for modeling vapor pressure within the plastic IC packages during solder reflow. The first involves the extension of the "wetness" technique to delamination along multimaterial interface and during dynamic solder reflow. Despite its simplicity, this technique is capable of offering reliable and accurate prediction for packages with high flexural rigidity. For packages with low flexural rigidity, the new "decoupling" technique that integrates thermodynamics, moisture diffusion, and structural analysis into a unified procedure has been shown to be more useful. The rigorous technique has been validated on both leadframe-based as well as laminate-based packages. With high accuracy and computational efficiency, these dynamic modeling tools will be valuable for optimization of package construction, materials, and solder reflow profile against popcorn cracking for both SnPb and Pb-free solders     

温压用铁粉松装密度的优化粒级匹配试验研究

为提高温压用铁粉的流动性和松装密度，对典型粉末的粒度分布、流动性和松装密度进行了试验研究。结果表明，随温度的升高单一粒径粉体的流动性和松装密度均变差，而多粒级匹配粉末在120℃内基本保持不变，且粉体粒度分布对粉末的流动性和松装密度影响较大。通过正交试验优化了粉末的粒级匹配，获得了高松装密度的H1粉末，其流动性与国外粉W1相当，而松装密度比国外粉W1和国内粉N1分别提高了5．03％和8．99％。