Synthesis and characterization of pyrochlore-type solid solutions Y2−xLaxRu2O7

New pyrochlore-type solid solutions Y_2−xLa_xRu₂O₇ have been synthesized for x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5, and 0.6 as single-phase materials. The lattice parameters for these solid solutions are linear with x and range from 1.0140 nm (x=0.0) to 1.0257 nm (x=0.6). All the samples show semiconducting behavior with an activation energy of about 0.1 eV. They show the spin-glass-like magnetic transition at low temperatures. Its transition temperature T_G decreases from 77 K for Y₂Ru₂O₇ with increasing the La³⁺ content.     

Optical measurement in carbon nanotubes formation by pulsed laser ablation

Carbon nanotubes (CNTs) were produced by laser ablation of a graphite composite target in argon and nitrogen ambient gas. To investigate the effect of nitrogen gas on CNTs formation, the plasma plume was examined using optical emission spectroscopy. The vibrational temperature of C₂ molecules was estimated by fitting of a Swan band spectrum. The temperature in N₂ ambient gas is lower than that in Ar ambient gas. In a nitrogen atmosphere, the spectrum intensity of C₂ Swan band was enhanced and CN violet system was also observed. Soot collected in the reaction tube was observed using FE-SEM and TEM. The soot deposited in the nitrogen gas contained more bundled CNTs than those in Ar ambience.     

Effect of Seed Layer on the Orientation of Zinc Oxide Film on Silicon Substrate

1. IntroductionZinc oxide films have been attracting more and moreattention because of their high diffractive index, low resis-tance, and photoluminescence properties, and are beingused as transparent electrodes, basis material for opti-cal wave guide devices, gas sensors and so on. Manymethods have been developed to prepare ZnO films, suchas chemical vapor deposition[1], reactive evaporation[2],pulsed laser ablation[3], sputtering[4], spray pyrolysis[5]and hydrothermal method[6]. There are a…     

Manipulation of micro solid particles and induced flows in water by laser irradiation

Q-switch for pulsing laser beam and Galvano scanner for rapid scanning laser beam were adapted to manipulatemicro solid particles in a water droplet.The trapping of fine particles at micron-sized diameters by a YAG lasersystem,induced flows,and the induced motion of the particles by laser beam irradiations are discussed.Particlerotations are observed by using anisotropic micro objects,and moreover the rotational rate with clockwise direc-tion is 22 r/min.The fragments of a cover glass were mixed in a water droplet,and their size and shape are un-even.The rotation of that non-spheres without scanning by the Galvano scanner is also observed in water.     

Functional and Structural Insights into Human PPARα/δ/γ Subtype Selectivity of Bezafibrate,Fenofibric Acid,and Pemafibrate

Among the agonists against three peroxisome proliferator-activated receptor (PPAR) subtypes, those against PPARα (fibrates) and PPARγ (glitazones) are currently used to treat dyslipidemia and type 2 diabetes, respectively, whereas PPARδ agonists are expected to be the next-generation metabolic disease drug. In addition, some dual/pan PPAR agonists are currently being investigated via clinical trials as one of the first curative drugs against nonalcoholic fatty liver disease (NAFLD). Because PPARα/δ/γ share considerable amino acid identity and three-dimensional structures, especially in ligand-binding domains (LBDs), clinically approved fibrates, such as bezafibrate, fenofibric acid, and pemafibrate, could also act on PPARδ/γ when used as anti-NAFLD drugs. Therefore, this study examined their PPARα/δ/γ selectivity using three independent assays—a dual luciferase-based GAL4 transactivation assay for COS-7 cells, time-resolved fluorescence resonance energy transfer-based coactivator recruitment assay, and circular dichroism spectroscopy-based thermostability assay. Although the efficacy and efficiency highly varied between agonists, assay types, and PPAR subtypes, the three fibrates, except fenofibric acid that did not affect PPARδ-mediated transactivation and coactivator recruitment, activated all PPAR subtypes in those assays. Furthermore, we aimed to obtain cocrystal structures of PPARδ/γ-LBD and the three fibrates via X-ray diffraction and versatile crystallization methods, which we recently used to obtain 34 structures of PPARα-LBD cocrystallized with 17 ligands, including the fibrates. We herein reveal five novel high-resolution structures of PPARδ/γ–bezafibrate, PPARγ–fenofibric acid, and PPARδ/γ–pemafibrate, thereby providing the molecular basis for their application beyond dyslipidemia treatment.     

The Routineness of Routines: Measuring Rhythms of Media Interaction

The routines of information work are commonplace yet difficult to characterize. Although cognitive models have successfully characterized routine tasks within which there is little variation, a large body of ethnomethodological research has identified the inherent nonroutineness of routines in information work. We argue that work does not fall into discrete classes of routine versus nonroutine; rather, task performance lies on a continuum of routineness, and routineness metrics are important to the understanding of workplace multitasking.

In a study of 10 information workers shadowed for 3 whole working days each, we utilize the construct of working sphere to model projects/tasks as a network of humans and artifacts. Employing a statistical technique called T-pattern analysis, we derive measures of routineness from these real-world data. In terms of routineness, we show that information workers experience archetypes of working spheres. The results indicate that T-patterns of interactions with information and computational media are important indicators of facets of routineness and that these measures are correlated with workers' affective states. Our results are some of the first to demonstrate how regular temporal patterns of media interaction in tasks are related to stress. These results suggest that designs of systems to facilitate so-called routine work should consider the degrees to which a person's working spheres fall along varying facets of routineness.     

Silicon based on-chip antenna using an LC resonator for near-field RF systems

This paper presents the silicon based on-chip antenna using a LC resonator. The proposed antenna consists of a stacked capacitor and a spiral inductor on silicon substrate. The spiral inductor structure without underpass was proposed for improvement the performance of the silicon based-antenna. The resonant frequency of the fabricated antenna was measured as 465 MHz. Its return loss was 23.4 dB at resonant frequency. The antenna has a gain of ?35.75 dBi due to small size and silicon substrate. However, the fabricated antenna has good performance in the near-field.     

Proposal of resilience assessment by focusing on pliability

Resilience is a concept which presents the strength of mind necessary to adopt the difficulties and to recover from negative psychological state. The assessment for resilience has been assessed by using interview and questionnaire which depend on subjectivity of participants. Though the objective assessment for resilience is expected to advance the biofeedback treatment, neither effective method nor instrument have been developed. Then this study focuses on the pliability as one of aspects of resilience and experimentally verifies whether it becomes a novel index for resilience or not.