全文获取类型
收费全文 | 2262篇 |
免费 | 171篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 7篇 |
化学工业 | 970篇 |
金属工艺 | 21篇 |
机械仪表 | 41篇 |
建筑科学 | 77篇 |
矿业工程 | 5篇 |
能源动力 | 41篇 |
轻工业 | 566篇 |
水利工程 | 15篇 |
石油天然气 | 7篇 |
无线电 | 80篇 |
一般工业技术 | 293篇 |
冶金工业 | 69篇 |
原子能技术 | 6篇 |
自动化技术 | 236篇 |
出版年
2024年 | 5篇 |
2023年 | 30篇 |
2022年 | 208篇 |
2021年 | 306篇 |
2020年 | 84篇 |
2019年 | 70篇 |
2018年 | 88篇 |
2017年 | 84篇 |
2016年 | 99篇 |
2015年 | 75篇 |
2014年 | 95篇 |
2013年 | 158篇 |
2012年 | 137篇 |
2011年 | 163篇 |
2010年 | 109篇 |
2009年 | 117篇 |
2008年 | 92篇 |
2007年 | 92篇 |
2006年 | 76篇 |
2005年 | 62篇 |
2004年 | 54篇 |
2003年 | 42篇 |
2002年 | 29篇 |
2001年 | 22篇 |
2000年 | 14篇 |
1999年 | 6篇 |
1998年 | 18篇 |
1997年 | 13篇 |
1996年 | 15篇 |
1995年 | 13篇 |
1994年 | 5篇 |
1993年 | 8篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1985年 | 2篇 |
1983年 | 2篇 |
1980年 | 1篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1973年 | 4篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1965年 | 1篇 |
1934年 | 1篇 |
1933年 | 1篇 |
1932年 | 2篇 |
排序方式: 共有2434条查询结果,搜索用时 15 毫秒
111.
Carballa M Omil F Lema JM Llompart M García-Jares C Rodríguez I Gómez M Ternes T 《Water research》2004,38(12):2918-2926
Two cosmetic ingredients (galaxolide, tonalide), eight pharmaceuticals (carbamazepine, diazepam, diclofenac, ibuprofen, naproxen, roxithromycin, sulfamethoxazole and iopromide) and three hormones (estrone, 17beta-estradiol and 17alpha-ethinylestradiol) have been surveyed along the different units of a municipal Sewage Treatment Plant (STP) in Galicia, NW Spain. Among all the substances considered, significant concentrations in the influent were only found for the two musks (galaxolide and tonalide), two anti-inflammatories (ibuprofen and naproxen), two natural estrogens (estrone, 17beta-estradiol), one antibiotic (sulfamethoxazole) and the X-ray contrast medium (iopromide), where the other compounds studied were below the limit of quantification. In the primary treatment, only the fragrances (30-50%) and 17beta-estradiol (20%) were partially removed. On the other hand, the aerobic treatment (activated sludges) caused an important reduction in all compounds detected, between 35% and 75%, with the exception of iopromide, which remained in the aqueous phase. The overall removal efficiencies within the STP ranged between 70-90% for the fragrances, 40-65% for the anti-inflammatories, around 65% for 17beta-estradiol and 60% for sulfamethoxazole. However, the concentration of estrone increased along the treatment due to the partial oxidation of 17beta-estradiol in the aeration tank. 相似文献
112.
Almeida G Figueiredo A Rôla M Barros RM Gibbs P Hogg T Teixeira P 《Journal of food protection》2007,70(7):1710-1716
Seventy raw milk cheeses made in different regions of Portugal, both hard and soft varieties, made with cow's, ewe's, or goat's milk or combinations of these, were sampled within their quoted shelf lives for microbiological safety. On the basis of the presence or numbers of Escherichia coli, E. coli O157, Staphylococcus aureus, Salmonella, and Listeria monocytogenes, cheeses were categorized as satisfactory, acceptable, unsatisfactory, or unacceptable and potentially hazardous. Twenty-two of the 70 cheeses were classified as satisfactory or acceptable. Thirty-seven of the cheeses were considered unsatisfactory because of the presence of E. coli, S. aureus, or both, while 11 of the cheeses were graded as unacceptable and potentially hazardous because of the presence of excessive numbers of S. aureus, E. coli, or L. monocytogenes and the presence of Salmonella in three of these. All cheeses graded as unacceptable and potentially hazardous were soft or semisoft cheeses made with ewe's and goat's milk, with the exception of two hard cheeses made with cow's milk. E. coli O157 was not detected in any of the cheeses. According to the present results, it seems that the presence or counts of pathogenic or indicator organisms in raw milk cheeses cannot be related to the processing conditions, milk type, or region of production. 相似文献
113.
Daniel Alberto Sánchez Gabriela Marta Tonetto María Luján Ferreira 《Journal of the American Oil Chemists' Society》2014,91(2):261-270
New avenues to add value to glycerol are currently being explored. One of them is the synthesis of structured lipids through glycerol esterification. In this work we have analyzed the recovery and purification of dicaprin obtained by esterification of glycerol with capric acid (C) in heptane, mediated by Lipozyme RM IM. This is an intermediate step to obtain lipids MLM. In the first stage, the diglyceride synthesis MGM (being G a central HC–OH) was carried out. When M = C, the diglyceride is CGC. Recovery of the diglyceride CGC is required to carry out the esterification of the sn-2 position with palmitic acid (P), thus obtaining the triglyceride CPC. Different solvents were evaluated using Ecofac 1.0 (a molecular design software solvent) through a theoretical approach to explore the best solvents for the acylglycerides separation. Then, the performance of the selected solvents to separate dicaprin from mono and tricaprin was experimentally studied in a liquid–liquid extraction process. Previously, the remaining fatty acid had been neutralized. With liquid–liquid extraction in three simple steps, using ethanol/water, 94 % of the dicaprin obtained by enzymatic esterification was recovered with a purity of 89 % (wt%). It was also possible to obtain dicaprin with a purity of 97 % but with a yield of 56 %. 相似文献
114.
M. Wesołowska-Trojanowska M. Tomczyńska-Mleko K. Terpiłowski M. Kawecka-Radomska S. Mleko 《Journal of Inorganic and Organometallic Polymers and Materials》2016,26(3):555-562
The aim of the research was to obtain biopolymers based on wheat gluten, whey protein concentrate (WPC) and montmorillonite (MON). Ternary biopolymers were formed as heat-induced gels and they were hardened by water evaporation. Adding 7 % of MON and 5 % WPC to gluten caused ca. four times higher values of storage modulus. Increased moduli values with adding MON and WPC to gluten were probably caused by reinforcing effect of MON, which decreased mobility of gluten chains and possible interactions between gluten and whey proteins by disulphide interchange. Increase in gluten protein concentration and addition of WPC and MON caused increase in viscosity measured by dissipation of ultrasound vibrations. Evaporation of water from the gels formed very hard material with high puncture force values. Obtained gels were very plastic and it was easy to form any type of shapes. They could be used to produce biodegradable pottery (e.g. flowerpots) with the mechanical properties similar to non-degradable clay products. 相似文献
115.
Marta Kopaska Edyta Barna Joanna Bajda Barbara Kuduk Anna agowska Agnieszka Bana-Zbczyk 《International journal of molecular sciences》2022,23(8)
Introduction and purpose of the study: SARS-CoV-2 virus does not only affect the respiratory system. It may cause damage to many organ systems with long-term effects. The latest scientific reports inform that this virus leaves a long-term trace in the nervous, circulatory, respiratory, urinary and reproductive systems. It manifests itself in disturbances in the functioning of the organs of these systems, causing serious health problems. The aim of the study was to review the latest research into the long-term effects of COVID-19 and determine how common these symptoms are and who is most at risk. Based on a literature review using the electronic scientific databases of PubMed and Web of Science on the long-term effects of SARS-CoV-2 infection, 88 studies were included in the analysis. The information contained in the analyzed literature shows that the SARS-CoV-2 virus can cause multi-organ damage, causing a number of long-term negative health complications. Conclusions: There is evidence that the virus can cause long-term complications lasting more than six months. They mainly concern disturbances in the functioning of the nervous, circulatory and respiratory systems. However, these studies are small or short-lasting, and many are speculative. 相似文献
116.
Antonio Sánchez‐Díaz Marta Izquierdo Salvatore Filippone Nazario Martin Emilio Palomares 《Advanced functional materials》2010,20(16):2695-2700
Organic solar cells made using a blend of DPM12 and P3HT are studied. The results show that higher Voc can be obtained when using DPM12 in comparison to the usual mono‐substituted PCBM electron acceptor. Moreover, better device performances are also registered when the cells are irradiated with sun‐simulated light of 10–50 mW cm?2 intensity. Electrochemical and time‐resolved spectroscopic measurements are compared for both devices and a 100‐mV shift in the density of states (DOS) is observed for DPM12/P3HT devices with respect to PCBM/P3HT solar cells and slow polaron‐recombination dynamics are found for the DPM12/P3HT devices. These observations can be directly correlated with the observed increase in Voc, which is in contrast with previous results that correlated the higher Voc with different ideality factors obtained using dark‐diode measurements. The origin for the shift in the DOS can be correlated to the crystallinity of the blend that is influenced by the properties of the included fullerene. 相似文献
117.
Gerardo F. Barbero Ali Liazid Marta Ferreiro-González Miguel Palma Carmelo G. Barroso 《International Journal of Food Properties》2016,19(5):984-992
A new chromatographic method for the separation of major capsaicinoids in peppers has been developed. Nordihydrocapsaicin, capsaicin, dihydrocapsaicin, homocapsaicin, and homodihydrocapsaicin have been separated by reversed-phase ultra-performance liquid chromatography. A gradient method has been developed using two solvents: 0.1% acetic acid in water and 0.1% acetic acid in methanol. The developed method allows the full separation of capsaicinoids in less than 3 min, with high reproducibility (relative standard deviation < 4.3%) and repeatability (relative standard deviation < 3.6%). Robustness regarding the total amount of methanol in the sample was determined. Comparison with previous reversed-phase high-performance liquid chromatography methods using both monolithic and conventional columns was also studied. Finally, the method was applied in the determination of major capsaicinoids in 16 hot pepper samples produced in Spain. 相似文献
118.
In recent years, a peculiar homelessness policy that goes under the name of ‘Housing First’ has become increasingly popular all over the world. Epitomising a quintessential case of policy-mobility, Housing First can today be considered an heterogeneous assemblage of experiences and approaches that sometimes have little in common with each other. Introducing and commenting upon this heterogeneity, the paper critically analyses why and how Housing First has become a planetary success and what are the issues at stake with its widespread implementation. If recent scholarship published in this journal has granted us a fine understanding of Housing First’s functioning in the US, this paper offers something currently absent from the debate: a nuanced and critical understanding of the ambiguities related to the international success of this policy, with specific references to the challenges associated to its translation in the Italian case. 相似文献
119.
N‐Oligo(3‐hydroxybutyrate)‐functionalized polypyrroles: towards bio‐erodible conducting copolymers
下载免费PDF全文
![点击此处可从《Polymer International》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Anna Domagala Wojciech Domagala Przemyslaw Ledwon Marta Musiol Henryk Janeczek Agnieszka Stolarczyk Piotr Kurcok Grazyna Adamus Mieczyslaw Lapkowski 《Polymer International》2016,65(12):1395-1404
New copolymer materials have been prepared by chemical grafting of oligomeric 3‐hydroxybutyric acid (OHB) onto polypyrrole (PPy) derivatives. The influence of grafting density and molecular weight of OHB brushes on the physicochemical properties of prepared copolymers was investigated. PPy substrates were prepared by FeCl3‐driven oxidative homopolymerization of N‐(2‐carboxyethyl)pyrrole or its copolymerization with pyrrole. The grafting method employed involved controlled anionic polymerization of β‐butyrolactone on pyrrole‐tethered potassium carboxylate active sites. Obtained PPy‐g‐OHB copolymers of varying grafting density and pendant polyester chain length were characterized and the observed structure–property relationships discussed. The impact of real time exposure to phosphate‐buffered saline environment was investigated and the residue products were characterized. Cross‐correlation of spectroscopic, thermal, electrical and elemental analysis data afforded comprehensive evaluation of the structure of prepared materials and their behaviour in hydrolytic medium. Erosion and degradation pathways have been identified, indicating ways to consciously tailor the physicochemical properties of these new biomimetic materials. © 2016 Society of Chemical Industry 相似文献
120.
Agustín Jiménez Avello Basil Mohammed Al‐Hadithi Marta Ines Gonzalez Garcia Jose Maria Lopez Rubio 《风能》2014,17(1):57-74
In this paper, a new algorithm, difference equation matrix model (DEMM), in the framework of model predictive control (MPC) is introduced. Instead of the standard dynamic matrix control (DMC), which is based upon step response method that has been used in most research works, we propose a new approach based upon a DEMM for model prediction. It has shown that DEMM has proven to be less computational and thus faster than the original DMC for real time applications. Thus, the drawbacks of DMC for online identification or adaptive design could be avoided. The control of wind turbines is carried out in order to decrease the cost of wind energy by increasing the efficiency, and thus the energy capture, or by reducing structural loading and increasing the lifetimes of the components and turbine structures. Modeling of wind turbine has been carried out. Effect of noise and disturbance on the system has been also studied. The results obtained show that the proposed DEMM minimizes the effect of the disturbance and produces an accurate and smooth control. Significant improvements in the regulation of rotor speed at high wind speeds are obtained from the proposed DEMM, where control set points are obtained ahead of the disturbance, saving the turbine of the negative effects of them and thus increasing its lifetime. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献