Development of headspace-gas chromatography-flame ionization detection procedure to determine volatile fatty acids in zoo organic waste leachates

In order to determine volatile fatty acids (short chain monocarboxylic acids with 2 to 6 carbon atoms in a molecule) in leachates formed in organic waste piles a procedure based on static headspace (HS) coupled with gas chromatography (GC) have been proposed and optimized. The conditions of HS extraction and sample introduction into a gas chromatograph as well as of chromatographic separation were considered. Using flame ionization detection LODs were of the order of 0.02-0.37 mg/L. The analyzed leachate collecting on and close to a zoo organic waste pile contained VFAs (Volatile Fatty Acids) at a concentration ranging from 5.5 mg/L to 0.88 g/L and from below LOD to 10.1 mg/L for pool water at some distance from the pile, respectively.     

Real-time monocular image-based path detection

In this work, we present a new real-time image-based monocular path detection method. It does not require camera calibration and works on semi-structured outdoor paths. The core of the method is based on segmenting images and classifying each super-pixel to infer a contour of navigable space. This method allows a mobile robot equipped with a monocular camera to follow different naturally delimited paths. The contour shape can be used to calculate the forward and steering speed of the robot. To achieve real-time computation necessary for on-board execution in mobile robots, the image segmentation is implemented on a low-power embedded GPU. The validity of our approach has been verified with an image dataset of various outdoor paths as well as with a real mobile robot.     

Modeling dynamic recovery strategy for composite web services execution

During the execution of Composite Web Services (CWS), a component Web Service (WS) can fail and can be repaired with strategies such WS retry, substitution, compensation, roll-back, replication, or checkpointing. Each strategy behaves differently on different scenarios, impacting the CWS Q o S. We propose a non intrusive dynamic fault tolerant model that analyses several levels of information: environment state, execution state, and Q o S criteria, to dynamically decide the best recovery strategy when a failure occurs. We present an experimental study to evaluate the model and determine the impact on Q o S parameters of different recovery strategies; and evaluate the intrusiveness of our strategy during the normal execution of CWSs.     

Building a Usable and Accessible Semantic Web Interaction Platform

Semantic Web applications take off is being slower than expected, at least with respect to “real-world” applications and users. One of the main reasons for this lack of adoption is that most Semantic Web user interfaces are still immature from the usability and accessibility points of view. This is due to the novelty of these technologies, but this also motivates the exploration of alternative interaction paradigms, different from the “traditional” Web or Desktop applications ones. Our proposal is realized in the Rhizomer platform, which explores the possibilities of the object–action interaction paradigm at the Web scale. This paradigm is well suited for heterogeneous resource spaces such as those common in the Semantic Web. Resources, described by metadata, correspond to the objects in the paradigm. Semantic web services, which are dynamically associated to these objects, correspond to the actions. The platform is being put into practice in the context of a research project in order to build an open application for media distribution based on Semantic Web technologies. Moreover, its usability and accessibility have been evaluated in this real setting and compared to similar systems.     

The semantic web as a newspaper media convergence facilitator

Newspapers are evolving and this causes great changes in how newspapers reach their consumers, but also in how newspapers work internally. Advanced computerised support is needed in order to cope with the new needs, which require that machines are aware of a greater part of the underlying semantics. Ontologies and Semantic Web technologies are clear candidates for web-wide semantics. However, newspapers have made great investments in their current news management systems and their wish is to undertake a smooth transition. Our proposal is to build an ontological framework based on existing journalism and multimedia standards. These standards are based on XML technologies. Therefore, we have developed a generic XML Schema to OWL mapping, complemented with an XML to RDF one. Together, they allow reusing existing metadata that, once in a semantic space, facilitates data integration, news management and retrieval. The resulting ontological framework is being applied in the Diari Segre Media Group¹, which produces press, radio and television content.     

Low-Temperature Fabrication of Oxide Composites for Solid-Oxide Fuel Cells

Composites of yttria-stabilized zirconia (YSZ) with Sr-doped LaCrO₃ (LSC) and Sr-doped LaMnO₃ (LSM) were prepared by impregnation of a porous YSZ matrix with aqueous solutions of the appropriate metal salts, followed by sintering to various temperatures. XRD measurements showed that perovskite phases formed after sintering at 1073 K, a temperature well below that at which solid-state reactions with YSZ occur. The conductivities of the LSC–YSZ and LSM–YSZ composites prepared in this way were maximized at a sintering temperature of 1373 K for LSC–YSZ and 1523 K for LSM–YSZ, although reasonable conductivities were achieved at much lower temperatures. The conductivities of the two composites increased much more rapidly with the content of the conductive oxide than has been found with conventional composites formed by mixing and sintering the oxide powders. The implications for using this approach to develop novel electrodes for SOFC applications are discussed.     

Characterization of the human iris spectral reflectance with a multispectral imaging system

We present a multispectral system developed and optimized for measurement of the spectral reflectance and the color of the human iris. We tested several sets of filters as acquisition channels, analyzed different reconstruction algorithms, and used different samples as training sets. The results obtained show that a conventional three-channel color camera (RGB) was enough to reconstruct the analyzed reflectances with high accuracy, obtaining averaged color differences of around 2-3 CIEDE2000 units and root mean square errors of around 0.01. The device developed was used to characterize 100 real irises corresponding to 50 subjects, 68 prostheses used in clinical practice, and 17 cosmetic colored contact lenses.     

Consequence analysis to determine damage to buildings from vapour cloud explosions using characteristic curves

The objective of this paper is to propose a methodology to estimate the consequences to buildings from the pressure wave caused by unconfined vapour cloud explosions (VCEs). This methodology is based on the use of characteristic overpressure-impulse-distance curves, shown in a previous paper [F. Diaz Alonso, E. Gonzalez Ferradas, J.F. Sanchez Perez, A. Mi?ana Aznar, J. Ruiz Gimeno, J. Martinez Alonso, Characteristic overpressure-impulse-distance curves for vapour cloud, explosions using the TNO Multi-Energy model, J. Hazard. Mater. A137 (2006) 734-741]. They allow the overpressure and impulse at each distance from the explosion to be determined. Since they can be combined with damage criteria (such as those shown by the PROBIT equations), they can be used to perform consequence analysis as the damage is shown in the same diagram as the overpressure, impulse and distance. Since damages suffered by buildings usually affect people inside, it is important to take them into account when performing consequence analysis. This is done in this paper, where diagrams and equations are presented to determine minor damage to buildings (broken windows, displacement of doors and window frames, tile displacement, etc.), major structural damage (cracks in walls, collapse of some walls) and collapse (the damage is so extensive that the building is partially or totally demolished). This paper completes the consequence analysis to humans outdoors shown by F.D. Alonso et al. [F. Diaz Alonso, E. Gonzalez Ferradas, T. Jimenez Sanchez, A. Mi?ana Aznar, J. Ruiz Gimeno, J. Martinez Alonso, Consequence analysis to determine the damage to humans from vapour cloud explosions using characteristic curves, J. Hazard. Mater., in press].     

Determination of the solid-water distribution coefficient (Kd) for pharmaceuticals, estrogens and musk fragrances in digested sludge

This work determined the solid-water distribution coefficient (K(d)) and the organic carbon normalized distribution coefficient (K(oc)) of several pharmaceuticals (carbamazepine, ibuprofen, naproxen, diclofenac, iopromide, sulfamethoxazole and roxithromycin), three estrogens (estrone, 17beta-estradiol and 17alpha-ethinylestradiol) and two musk fragrances (HHCB and AHTN) in digested sludge. These sorption coefficients can be used to evaluate the fate of these substances during sludge treatment, thus avoiding the expensive and time-consuming analysis in the sludge phase. For determining the K(d) and K(oc) values of the target compounds in digested sludge, their concentrations were measured in the aqueous and solid phase of the effluent of an anaerobic digestion pilot plant run at several operational conditions. The results obtained were compared with the values modelled by using simple K(ow) approaches. The resulting log K(d) values ranged between 3.5 and 4.4 for the two musk fragrances (log K(oc) of 4.5-6.0), between 2.1 and 2.9 for estrogens (log K(oc) of 2.9-4.2) and between 0.8 and 1.9 for the remaining pharmaceuticals (log K(oc) of 1.8-3.5). These values are in the same range as those reported in the literature for primary and secondary sludge and no significant influence of the anaerobic digestion operational conditions was observed. For most compounds, the modelled K(oc) were close or within the lower range of the experimentally determined K(oc). Major deviations of the modelled K(oc) values were found for iopromide, sulfamethoxazole and roxithromycin, which were 1-3 orders of magnitude lower than the measured values.