Plasma enhanced chemical vapor deposition of SiO2 films at low temperatures using SiCl4 and O2

Silicon dioxide films have been deposited by Plasma-Enhanced Chemical Vapor Deposition (PECVD) technique using SiCl₄ and O₂ as reactive materials. Infra-red transmittance, Auger electron spectroscopy analysis, ellipsometry, electrical, and chemical etch measurements have been used to characterize these films. It is possible to obtain good quality oxides at a substrate temperature of 200° C using a low flow of reactant gases. High flow of reactant gases results in highly non-homogeneous porous films. The best oxide films obtained show destructive breakdown at electrical fields above 4 MV/cm and a fixed charge density of the order of 2.6 × 10¹¹ charges/cm².     

<Emphasis Type="Italic">μ</Emphasis>DTNSec: a security layer with lightweight certificates for Disruption-Tolerant Networks on microcontrollers

In Delay/Disruption-Tolerant Networks, man-in-the-middle attacks are easy: due to the store-carry-forward principle, an attacker can simply place itself on the route between source and destination to eavesdrop or alter bundles. This weakness is aggravated in networks, where devices are energy-constrained but the attacker is not. To protect against these attacks, we design and implement μDTNSec, a security layer for Delay/Disruption-Tolerant Networks on microcontrollers. Our design establishes a public key infrastructure with lightweight certificates as an extension to the Bundle Protocol. It has been fully implemented as an addition to μDTN on Contiki OS and uses elliptic curve cryptography and hardware-backed symmetric encryption. In this enhanced version of μDTNSec, public key identity bindings are validated by exchanging certificates using neighbor discovery. μDTNSec provides a signature mode for authenticity and a sign-then-encrypt mode for added confidentiality. Our performance evaluation shows that the choice of the curve dominates the influence of the payload size. We also provide energy measurements for all operations to show the feasibility of our security layer on energy-constrained devices. Because a high quality source of randomness is required, we evaluated the random number generators by the AT86RF231 radio, its successor AT86RF233, and one based on the noise of the A/D converter. We found that only AT86RF233 provides the required quality.     

A Time-Domain Digital-Intensive Built-In Tester for Analog Circuits

To solve test challenges in nanometer CMOS technologies, a time-domain digital-intensive built-in tester for analog circuits is proposed. The compact tester allows characterizations of AC response and DC gain for various analog circuits which have a low-pass frequency characteristic. By applying ramp signals to stimulate the circuit under test and measuring slopes and time delays of its responses, the testing can be simple and robust over process-voltage-temperature variations. Also, it is well suited for nanometer technologies because of its digital-intensive implementation. The tester was fabricated in 65 nm standard CMOS process and occupies 0.026 mm².     

Electromagnetic coupling between wires inside a rectangular cavityusing multiple-mode-analogous-transmission-line circuit theory

This paper examines the coupling between two arbitrarily positioned wire segments inside a rectangular enclosure. The enclosure is treated as a superposition of analogous transmission lines which have been short circuited at two positions on the propagation axis. Each analogous transmission line is associated with a particular waveguide mode in the cavity. Previous work has used this analogy to predict the coupling between two monopoles inside a small box using the dominant TE ₁₀ mode. This paper considers the general case of high-frequency coupling between two wire monopoles in a large rectangular cavity, where several higher order modes are active. By taking into account higher order modes, and the mutual coupling between the modes, a simple equivalent circuit is presented which can give a prediction for the coupling between the monopoles. Experimental results for various monopole pair positions are shown, which indicate the success of the multimode theory. The technique requires far less computer resources than traditional methods for solving such a problem (e.g., MoM, TLM or FDTD), with solution times of less than a second on an average PC. In addition, considerable insight into the coupling process can be gained by including or excluding particular waveguide modes. This is not possible with numerical methods     

Liquid Metal Based Island‐Bridge Architectures for All Printed Stretchable Electrochemical Devices

The adoption of epidermal electronics into everyday life requires new design and fabrication paradigms, transitioning away from traditional rigid, bulky electronics towards soft devices that adapt with high intimacy to the human body. Here, a new strategy is reported for fabricating achieving highly stretchable “island‐bridge” (IB) electrochemical devices based on thick‐film printing process involving merging the deterministic IB architecture with stress‐enduring composite silver (Ag) inks based on eutectic gallium‐indium particles (EGaInPs) as dynamic electrical anchors within the inside the percolated network. The fabrication of free‐standing soft Ag‐EGaInPs‐based serpentine “bridges” enables the printed microstructures to maintain mechanical and electrical properties under an extreme (≈800%) strain. Coupling these highly stretchable “bridges” with rigid multifunctional “island” electrodes allows the realization of electrochemical devices that can sustain high mechanical deformation while displaying an extremely attractive and stable electrochemical performance. The advantages and practical utility of the new printed Ag‐liquid metal‐based island‐bridge designs are discussed and illustrated using a wearable biofuel cell. Such new scalable and tunable fabrication strategy will allow to incorporate a wide range of materials into a single device towards a wide range of applications in wearable electronics.     

Radio frequency electromagnetic fields in large conducting enclosures: effects of apertures and human bodies on propagation and field-statistics

Radio frequency propagation in an electrically large resonant chamber (a screened room) was simulated by two models: a statistical combination of multiple resonant modes and a computational electromagnetic simulation [the transmission line matrix (TLM) method]. The purpose of this work was to investigate the effects of passengers and windows on electromagnetic fields (EMF) in aircraft and other vehicles. Comparison of the multimode models with measurements made in a screened room showed that as the electromagnetic losses increased, the transmission between two internal antennas was reduced, and there were fewer turning points in its frequency response. The autocorrelation of this frequency response provided a useful estimate of the composite Q-factor of the resonances and showed that the Q of the chamber was reduced from a value of the order of 10 000 when emptied to 1000 when windows were added and when filled with people to 100. The TLM simulation provided further useful information about the statistical variation of electric field strength with position.     

Optimization of stirrer designs in a reverberation chamber

This paper describes an investigation into the key factors which contribute to an effective mode stirrer. The work concentrates on the lower frequency range, since all stirrers have poorer performance at low frequencies. The stirrer's shapes and sizes have been investigated, together with an optimization of the finer details in the stirrer's shape. The modeling of the mode stirred chamber has been performed using the transmission-line matrix (TLM) method. Software has been developed which, for each position of the rotating stirrer, builds the shape of the stirrer using thin, perfectly conducting boundaries. Results indicate that the design of the stirrer's basic shape has a small but significant impact on its performance. A genetic algorithm has been used to optimize certain parameters in the shape of the stirrer, and a fitness factor based on a free space model of the stirrer has been used. The free space model runs 1500 times faster than the model in the chamber. The optimization is shown to improve the stirrer's performance in three different sizes of chamber. Computer modeling has been verified by measurements performed in the chamber at the University of York.     

Anti‐Oxygen Leaking LiCoO2

LiCoO₂ is a prime example of widely used cathodes that suffer from the structural/thermal instability issues that lead to the release of their lattice oxygen under nonequilibrium conditions and safety concerns in Li‐ion batteries. Here, it is shown that an atomically thin layer of reduced graphene oxide can suppress oxygen release from Li_xCoO₂ particles and improve their structural stability. Electrochemical cycling, differential electrochemical mass spectroscopy, differential scanning calorimetry, and in situ heating transmission electron microscopy are performed to characterize the effectiveness of the graphene‐coating on the abusive tolerance of Li_xCoO₂. Electrochemical cycling mass spectroscopy results suggest that oxygen release is hindered at high cutoff voltage cycling when the cathode is coated with reduced graphene oxide. Thermal analysis, in situ heating transmission electron microscopy, and electron energy loss spectroscopy results show that the reduction of Co species from the graphene‐coated samples is delayed when compared with bare cathodes. Finally, density functional theory and ab initio molecular dynamics calculations show that the rGO layers could suppress O₂ formation more effectively due to the strong C? O_cathode bond formation at the interface of rGO/LCO where low coordination oxygens exist. This investigation uncovers a reliable approach for hindering the oxygen release reaction and improving the thermal stability of battery cathodes.     

Studies on the adsorption of RuN3 dye on sheet-like nanostructured porous ZnO films

The interface between the ZnO and dye directly impacts the dye-sensitized solar cell (DSSC) performance. Nanostructured porous ZnO film was developed by a simple chemical solution process. Scanning electron microscope (SEM) images demonstrated the uniform ZnO films with sheet-like nanostructure. Adsorption studies indicated that the maximum adsorption capacity of RuN₃ dye on the surface of ZnO films was approximately 0.016 mmol RuN₃/g ZnO films. Adsorption studies were conducted at 25 and 40 °C. The results showed that the dye adsorption was significantly influenced by temperatures. Moreover, the problem of the dye aggregation on the ZnO surface was reduced at higher adsorption temperatures. The adsorption chemistry was studied with Raman spectroscopy.