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21.
Relaxor perovskite ferroelectric 0.1Bi(Zn1/2Zr1/2)O3-0.9BaTiO3(0.1BZZ-0.9BT) ceramics were successfully prepared, whose powders synthesized by the sol-gel process, with average grain size about 1.29 μm. 1.75 J/cm3 discharge energy density and good dielectric stability were obtained over a wide temperature range from 25°C to 140°C. The pulse discharge capability of 0.1BZZ-0.9BT ceramics was tested under different electric fields. The discharge time was 2.13 μs, which proved its ability to charge and discharge quickly. Complex impedance analysis and thermally stimulated depolarization current tests were applied to investigate the defect types and activation of 0.1BZZ-0.9BT ceramics. The evolution process of composite defects and oxygen vacancies profoundly affects the dielectric temperature stability of 0.1BZZ-0.9BT ceramics’ energy storage property.  相似文献   
22.
In this work, nanofiber scaffolds for surface drug delivery applications were obtained by electrospinning poly(N-vinylcaprolactam) (PNVCL) and its blends with poly(ε-caprolactone) and poly(N-vinylcaprolactam)-b-poly(ε-caprolactone). The process parameters to obtain smooth and beadless PNVCL fibers were optimized. The average fibers diameter was less than 1 μm, and it was determined by scanning electron microscopy analyses. Their affinity toward water was evaluated by measuring the contact angle with water. The ketoprofen release behavior from the fibers was analyzed using independent and model-dependent approaches. The low values of the release exponent (n < 0.5) obtained for 20 and 42 °C, indicating a Fickian diffusion mechanism for all formulations. Dissolution efficiencies (DEs) revealed the effect of polymer composition, methodology used in the electrospinning process, and temperature on the release rate of ketoprofen. PNVCL/poly(N-vinylcaprolactam)-b-poly(ε-caprolactone)-based nanofibers showed greater ability to control the in vitro release of ketoprofen, in view of reduced kinetic constant and DE, making this material promising system for controlling release of hydrophobic drugs. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48472.  相似文献   
23.
The friction and wear of steel pins coated with filled polyamides and loaded against a rotating cylinder of bearing steel were tested under dry, lubricated, and abrasive contaminated conditions. The filler materials were copper/lead and aluminium/tin powders. The test results show a significant reduction in friction with the Cu/Pb filled polyamides (8 wt.% Cu, 12 wt.% Pb, and 80 wt.% PA6). The Al/Sn filled polyamides (3 wt.% Al, 2 wt.% Sn, and 95 wt.% PA6) showed the best wear resistance, accompanied by an increase in the coefficient of friction.  相似文献   
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ABSTRACT

A multistage system comprising an upflow anaerobic sludge blanket (UASB) followed by anoxic unit and then oxic activated sludge (AS) with biofilm is studied in El-Berka WWTP, Egypt. Different organic loading wastewaters of chemical oxygen demand (COD) less than 500 mg/L till 3000 mg/L are tested during the study. The hydraulic retention time (HRT) varies for each loading from 7.5 to 10 to 15 h. The UASB reactor accomplishes the removal efficiency of 50%–70% of influent COD. The overall system performs the removal efficiency of 95% of influent COD and NH4-N. Also, the results are verified by a modified mathematical model.  相似文献   
25.
The corrosion inhibition of Cu-Ni alloys was investigated in aqueous chloride solutions using amino acids as environmentally safe materials. The corrosion rate was calculated in absence and presence of the corrosion inhibitor using polarization and impedance techniques. The inhibition efficiency of the different amino acids was also calculated.The experimental results have shown that a simple amino acid like glycine can be used as efficient corrosion inhibitor for the Cu-Ni alloys in neutral chloride solutions. An inhibition efficiency of about 85% could be achieved at very low concentrations of the amino acid (0.1 mM). For low Ni content alloy (Cu-5Ni), 2.0 mM cysteine shows a remarkable high (∼96%) corrosion inhibition efficiency. The experimental impedance data were fitted to theoretical data according to a proposed equivalent circuit model for the electrode/electrolyte interface, and the mechanism of the corrosion inhibition process was suggested. Different adsorption isotherms were tested and the corrosion inhibition process was found to depend on the adsorption of the amino acid molecules and/or the deposition of corrosion products on the alloy surface. The adsorption free energy of cysteine on Cu-5Ni (−37.81 kJ mol−1) reveals a strong physical adsorption of the inhibitor on the alloy surface.  相似文献   
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Poly(glycerol sebacate) (PGS) is a biodegradable polymer increasingly used in a variety of biomedical applications. This polyester is prepared by polycondensation of glycerol and sebacic acid. PGS exhibits biocompatibility and biodegradability, both highly relevant properties in biomedical applications. PGS also involves cost effective production with the possibility of up scaling to industrial production. In addition, the mechanical properties and degradation kinetics of PGS can be tailored to match the requirements of intended applications by controlling curing time, curing temperature, reactants concentration and the degree of acrylation in acrylated PGS. Because of the flexible and elastomeric nature of PGS, its biomedical applications have mainly targeted soft tissue replacement and the engineering of soft tissues, such as cardiac muscle, blood, nerve, cartilage and retina. However, applications of PGS are being expanded to include drug delivery, tissue adhesive and hard tissue (i.e., bone) regeneration. The design and fabrication of PGS based devices for applications that mimic native physiological conditions are also being pursued. Novel designs range from accordion-like honeycomb structures for cardiac patches, gecko-like surfaces for tissue adhesives to PGS (nano) fibers for extra cellular matrix (ECM) like constructs; new design avenues are being investigated to meet the ever growing demand for replacement tissues and organs. In less than a decade PGS has become a material of great scrutiny and interest by the biomedical research community. In this review we consolidate the valuable existing knowledge in the fields of synthesis, properties and biomedical applications of PGS and PGS-related biomaterials and devices.  相似文献   
29.
The design-build delivery method is increasingly used in the United States due to numerous advantages it can offer a project. An important issue associated with design-build delivery is the procurement method used to select the design-build team. It is a critical decision that involves several key project team members, including the owner, designer, and contractor organizations, and requires the owner to carefully choose the design-build procurement method that will be used to select the team that will deliver the project. This research quantitatively analyzed the correlation between the design-build procurement method and the performance of the design-build project with regard to cost, time, and quality metrics. The procurement methods studied were sole source, qualifications-based, best value, and low bid selection. Data were collected through surveys from 76 design-build projects in the United States. Based on the patterns and relationships identified from these data, a better understanding of the procurement process and how it influences project performance is achieved. The impact of project-specific factors and guidelines are presented to assist owners in selecting the design-build team procurement method that responds to their project goals.  相似文献   
30.
Emerging technologies such as edge computing, Internet of Things (IoT), 5G networks, big data, Artificial Intelligence (AI), and Unmanned Aerial Vehicles (UAVs) empower, Industry 4.0, with a progressive production methodology that shows attention to the interaction between machine and human beings. In the literature, various authors have focused on resolving security problems in UAV communication to provide safety for vital applications. The current research article presents a Circle Search Optimization with Deep Learning Enabled Secure UAV Classification (CSODL-SUAVC) model for Industry 4.0 environment. The suggested CSODL-SUAVC methodology is aimed at accomplishing two core objectives such as secure communication via image steganography and image classification. Primarily, the proposed CSODL-SUAVC method involves the following methods such as Multi-Level Discrete Wavelet Transformation (ML-DWT), CSO-related Optimal Pixel Selection (CSO-OPS), and signcryption-based encryption. The proposed model deploys the CSO-OPS technique to select the optimal pixel points in cover images. The secret images, encrypted by signcryption technique, are embedded into cover images. Besides, the image classification process includes three components namely, Super-Resolution using Convolution Neural Network (SRCNN), Adam optimizer, and softmax classifier. The integration of the CSO-OPS algorithm and Adam optimizer helps in achieving the maximum performance upon UAV communication. The proposed CSODL-SUAVC model was experimentally validated using benchmark datasets and the outcomes were evaluated under distinct aspects. The simulation outcomes established the supreme better performance of the CSODL-SUAVC model over recent approaches.  相似文献   
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