Temperature dependence of kinetics and diffusion coefficients for ferrocene/ferricenium in ammonium-imide ionic liquids

The electrochemical behavior of ferrocene (Fc) and ferricenium (Fc⁺) was investigated by cyclic voltammetry with convolutional and semi-differential electroanalyses in the temperature range 298-373 K in the hydrophobic room temperature ionic liquid systems consisting of bis(trifluoromethanesulfone)imide anion with quaternary ammonium cation. The experimental results indicated that the redox reaction of Fc/Fc⁺ was reversible in this ionic liquid and the charge-transfer rate constant (k⁰) has been obtained. Mass transport towards the electrode is a simple diffusion process and the diffusion coefficient (D) for Fc/Fc⁺ has been also calculated. These results indicated that the k⁰ and D increased with increasing temperature in ionic liquids. The validity of the Arrhenius law was verified by investigating the temperature dependences of k⁰ and D.     

Hydrogenation of Nitrobenzene with Supported Transition Metal Catalysts in Supercritical Carbon Dioxide

Transition metal catalysts such as Pd, Pt, Ru, and Rh supported on carbon, silica and alumina have been examined for the hydrogenation of nitrobenzene (NB) in supercritical carbon dioxide (scCO₂) and in ethanol. The order of hydrogenation activity is Pt>Pd>Ru, Rh in scCO₂ and in ethanol. The effectiveness of the support is C>Al₂O₃, SiO₂ for either Pt or Pd in scCO₂. For all the catalysts, higher selectivity to aniline has been obtained in scCO₂ compared with ethanol. Hydrogenation of nitrobenzene catalyzed with Pd/C and Pt/C catalysts was successfully conducted in scCO₂ with a 100% yield to aniline at a lower reaction temperature of 35 °C. The product aniline (organic phase) can be easily separated from the side‐product water (aqueous phase), solvent (scCO₂), and catalyst (solid) by a simple phase separation process. The hydrogenation of NB is a structure‐sensitive reaction in ethanol as well as in scCO₂ except for a few Pt/C catalysts in which the degree of metal dispersion is small (<0.08).     

Cutting plane methods for Lagrangian relaxation‐based unit commitment algorithm

In this paper, we study cutting plane methods for a Lagrangian relaxation‐based unit commitment algorithm. In the algorithm, nondifferentiable optimization methods can be applied to optimize the dual function, and a subgradient method which needs parameter tuning and has some drawbacks such as computational inefficiency and oscillating behavior is commonly used. The cutting plane method and the central cutting plane method are applied to the algorithm and implemented using reoptimization techniques. A numerical example shows that both methods are accelerated by the reoptimization techniques and have good convergence without parameter tuning. © 2002 Wiley Periodicals, Inc. Electr Eng Jpn, 141(3): 17–29, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10066     

Group 3 error-free facsimile terminal for analog cellular networks

A Group 3 error-free facsimile terminal for use in an analog cellular network has been developed. This facsimile terminal is provided with the International Telecommunication Union (ITU-T, formerly CCITT) T.30 recommendation protocol and an adaptive error control scheme (AECS) for Group 3 communication and error-free communication. The AECS monitors the channel conditions and selects the optimum error correction code. The ITU-T V.27ter is used as the modulation method and the transmission rate is 4800 bps. This system is compatible with the modified Huffman (MH), modified READ (MR), and modified modified READ (MMR) image data compression codes. The average communication time of this facsimile terminal is 40 s per page while moving through the analog cellular network     

Dual voltage converter with improved power factor and enabling voltage control

In this paper, a novel version of the dual voltage converter is presented with improved voltage regulation and enabling a wide range of voltage control by using self-turn-off devices (power transistors) instead of diodes. Further, this system operates with unity displacement factor. We have obtained the analytical expressions of this circuit. The results are, however, quite complex. We could calculate values of the voltage and current waveforms by using a computer. The calculated values are essentially in agreement with the experimental values. Experimentally, an ideal load characteristic with null voltage regulation was obtained by the conduction angle control for power transistors. Further, a wide range of voltage from 220 V to 39 V was obtained. A disadvantage for this system is the requirement for snubber circuits with a larger value of capacitor in order to suppress the surge voltages at turn-off periods.     

Self-regenerating bone implant: ectopic osteoinduction following intramuscular implantation of a combination of rhBMP-2, atelopeptide type I collagen and porous hydroxyapatite

A combination of recombinant human bone morphogenetic protein-2 (rhBMP-2), atelopeptide Type I collagen (CL) as a carrier and porous hydroxyapatite (pHAP) was implanted in a calf muscle pouch of the rat. Three rhBMP-2-implanted groups (2, 10 and 50 micrograms; each n = 5) and the control group (n = 5), in which only CL and pHAP were implanted, were established. Three weeks later, the implants were examined.     

Vinyl polymerization by metal complexes. XVI. Photopolymerization of vinyl monomers by metal-amine systems

The photopolymerization of vinyl monomers was studied by the system of metal-amine complex and carbon tetrachloride. Addition of amines to the initiating system generally accelerates the polymerization. The acceleration by various sorts of amines in different solvents was examined. It was confirmed that the photopolymerization in question is of free radical character. The polymerization mechanism was discussed.     

Development of a hybrid catalytic combustor for a 1300°C class gas turbine

The hybrid catalytic combustor concept proposed by the authors has an advantage concerned with catalyst durability, because the catalyst is maintained below 1000°C even for application to 1300°C class gas turbines. A full-scale hybrid catalytic combustor has been designed for a 200 MW (1300°C) class gas turbine. The catalyst bed was 450 mm in diameter and consisted of a Pd/ alumina washcoat on a cordierite monolith. In experiments, the combustor has demonstrated the capability of meeting the NO_x emission level of SCR (selected catalytic reduction) during atmospheric pressure testing. To predict the catalyst performance at an elevated pressure, the characteristics of the catalyst were studied using a small scale reactor test, and a material property test using a DTA/TGA-Q.MASS system. The catalyst showed a higher activity in the oxidized state (PdO) than in the metallic state (Pd). This activity difference was governed by the equilibrium of the oxygen release from PdO in bulk. It was considered that oxidation rate of the metallic Pd in bulk was not so high and this caused self-oscillation for the Pd catalyst around the temperature of the oxygen release equilibrium. Even below the temperature of the oxygen release equilibrium, both surface and bulk (lattice) oxygen of the PdO was consumed by the methane oxidation reaction, and resulted in a lack of surface oxygen on the catalyst. This caused a reversible decrease in the catalyst activity during combustion testing, and indicated that the oxygen dissociation step was a rate limiting step in the catalytic combustion.     

Residual stress relief and local embrittlement in a A533B reactor pressure vessel weldment

A suitable testing technique is developed for evaluating the effect of weld residual stress on fracture toughness in the HAZ region of a reactor pressure vessel steel (SA533 Grade B, Class 1) and for investigating its susceptibility to reheat and underclad cracking or local embrittlement in the coarse-grained HAZs during post weld heat treatment. Use of a fracture mechanics approach leads to an interpretation of the effect of weld residual stress, tempering due to PWHT and notch acuity on the HAZ fracture toughness. This is applied to the estimation of COD transition temperature in the actual component of the reactor pressure vessel in terms of a summation of the various changes in the COD transition temperature associated with several factors such as weld residual stress, tempering, notch acuity and environment. Detailed comments are given on the determination of an allowable crack size in an actual component.