Composition and thermal analysis of ternary mixtures of avocado fat:palm stearin:cocoa butter (Avo:PS:CB)

Avocado fat is a semi-solid substance with potential functional lipid characteristics. A study was carried out to evaluate the effect of addition of palm stearin and cocoa butter on the solidification behavior of avocado fat to formulate a mixture to become similar to lard. A total of three mixtures were prepared: avocado fat:palm stearin:cocoa butter (88:7:5), avocado fat:palm stearin:cocoa butter (86:7:7), avocado fat:palm stearin:cocoa butter (84:7:9; w/w), and identified by the mass ratio of avocado fat to palm stearin and cocoa butter. The fat mixtures were compared with lard in terms of the fatty acid and triacylglycerol compositions using gas chromatography and high-performance liquid chromatography, thermal properties using differential scanning calorimetry and solid fat content using p-nuclear magnetic resonance. Although there were considerable differences between lard and the fat mixtures with regard to fatty acid and triacylglycerol compositions, some similarities were seen with regard to thermal properties and solid fat content profile. Of all the fat mixtures, avocado fat:palm stearin:cocoa butter (84:7:9) displayed closer similarity to lard with respect to thermal transitions at –3.59°C and its solid fat content profile showed the least difference to that of lard throughout the temperature range measured.     

Phthalates exposure indicators determined by urinary phthalate metabolites in healthy non-obese Czech adults: FANTOM study

It is assumed that human exposure to phthalates may be associated with adverse health effects. The indicators of urinary phthalate metabolite concentrations in healthy adults are limited. In this study, the phthalate metabolites concentrations were detected from 24-h urine collection in non-obese Czech adults (n = 201). Each participant filled in an 80-item questionnaire (FANTOM-SQ 2013) regarding the outdoor and indoor sources of phthalates, the use of personal care products and food intake sources. The concentrations of 15 phthalates metabolites were analysed following enzymatic cleavage of the glucuronide using ultra-high-performance liquid chromatography-electrospray ionisation tandem mass spectrometry (UHPLC-ESI-MS/MS). The indicators of chronic or acute exposure phthalate-containing materials were identified. It is shown that higher fruit consumption was positively and significantly associated with a higher level of total 15 urinary phthalates biomarkers (p < 0.001). Regular meat consumption showed a negative significant association with total 15 phthalates metabolites (p < 0.01). The use of personal care products was significantly and positively correlated with monoethyl phthalate urine concentrations (p < 0.05). The analysis of the dietary behaviour and personal care products use in the Czech non-obese population showed it to be a predictable tool in the level of phthalates exposure when high fruit consumption and personal care products use are linked to higher phthalate metabolite contents in the urine. However, this topic deserves more research.     

Two-phase flow in a proton exchange membrane electrolyzer visualized in situ by simultaneous neutron radiography and optical imaging

In proton exchange membrane (PEM) electrolyzers, oxygen evolution in the anode and flooding due to water cross-over in the cathode yields two distinct two-phase transport conditions which strongly affect the performance. Two-phase transport in an electrolyzer cell is visualized by simultaneous neutron radiography and optical imaging. Optical and neutron data are used in a complementary manner to aid in understanding the two-phase flow behavior. Two different patterns of gas-bubble evolution and departure are identified: periodic growth/removal of small bubbles vs. prolonged blockage by stagnant large bubbles. In addition, the bubble distribution across the active area is not uniform due to combined effects of buoyancy and proximity to the inlet. The effects of operating parameters such as current density, temperature and water flow rate on the two-phase distribution are investigated. Higher water accumulation is detected in the cathode chamber at higher current density, even though the cathode is purged with a high flow rate of N₂.     

Growth of ω inclusions in Ti alloys: An X-ray diffraction study

We investigated the size and crystal structure of nanometer-sized ω inclusions in single crystals of β-Ti alloys by X-ray diffraction pole-figure measurements and reciprocal space mapping. We studied the topotactical relation of the β and ω crystal lattices, and from the positions and shapes of the diffraction maxima of the ω lattice determined the mean size of the ω inclusions and the misfit of the inclusion lattice with respect to the host lattice, as well as their changes during ageing. The lattice of the ω inclusions exhibits a large positive misfit already before ageing and the misfit is subsequently reduced during the ageing process. Using the theories of elasticity and X-ray scattering we simulated diffuse X-ray scattering around the β diffraction maxima and demonstrated that the diffuse scattering is caused mainly by local elastic strains in the β host phase around the ω inclusions.     

The O<Subscript>2</Subscript> + NH<Subscript>3</Subscript> Reaction Over Rh(110): Steady State Kinetics and Oscillatory Behavior

Abstract  

The kinetics of ammonia oxidation with oxygen over a Rh(110) surface were studied in the pressure range 10⁻⁵–10⁻⁴ mbar. Nitrogen was found to be the preferred product at low partial pressures ratios \textp_{\texto 2} :\textp_{\textNH 3} {\text{p}}_{{{\text{o}}_{ 2} }} :{\text{p}}_{{{\text{NH}}_{ 3} }} , while the NO pathway was favored with oxygen rich gas mixtures and at high temperature. The reactive sticking coefficient of O₂ reaches up to 0.05 under steady state conditions. Pronounced hysteresis effects in the reaction rates were found in T-cycling experiments. Sustained oscillations in the reaction rates occurred under isothermal conditions at T = 620 K at a total pressure of 4 × 10⁻⁵ mbar.     

Characterization of antibacterial polyethersulfone membranes using the respiration activity monitoring system (RAMOS)

Membranes with antibacterial properties were developed using surface modification of polyethersulfone ultrafiltration membranes. Three different modification strategies using polyelectrolyte layer-by-layer (LbL) technique are described. The first strategy relying on the intrinsic antibacterial properties of poly(diallyldimethylammonium chloride) (PDADMAC) and poly(ethylenimine) (PEI) exhibits only little antibacterial effects. The other two strategies contain silver in both ionic (Ag⁺) and metallic (Ag⁰) form. Ag⁺ embedded into negatively charged poly(sodium 4-styrene sulfonate) (PSS) layers totally inhibits bacterial growth. Ag⁰ nanoparticles were introduced to the membrane surface by LbL deposition of chitosan- and poly(methacrylic acid) - sodium salt (PMA)-capped silver nanoparticles and subsequent UV or heat treatment. Antibacterial properties of the modified membranes were quantified by a new method based on the Respiration Activity Monitoring System (RAMOS), whereby the oxygen transfer rates (OTR) of E. coli K12 cultures on the membranes were monitored online. As opposed to colony forming counting method RAMOS yields more quantitative and reliable data on the antibacterial effect of membrane modification. Ag-imprinted polyelectrolyte film composed of chitosan (Ag⁰)/PMA(Ag⁰)/chitosan(Ag⁰) was found to be the most promising among the tested membranes. Further investigation revealed that the concentration and equal distribution of silver in the membrane surface plays an important role in bacterial growth inhibition.     

Fatty acid and amino acid composition of three local Malaysian Channa spp. fish

The objective of this current study was to analyze the biochemical compositions of three Malaysian Channa spp. fish. The proximate analysis revealed that the protein content of Channa lucius, Channa micropeltes and Channa striatus was 19.9%, 22.1%, 23.0% (% of dry weight), respectively. The total lipid content was generally high, ranging from 5.7% to 11.9% and crude ash ranged from 1.0% to 1.8%. The major amino acids were glutamic acid, aspartic acid and lysine, ranging from 9.7% to 21.7%, and the most abundant fatty acid in Channa spp. was C16:0, ranging from 25.6% to 30.4%. The other major fatty acids detected were C22:6, C18:1 and C18:0. The level of arachidonic acid (C20:4) was unusually high in C. striatus (19.02%). The levels of DHA in these fish would also explain the use of Channa spp., especially C. striatus, which has been used for centuries for reducing pain, inflammation and promote wound healing in Malaysia.     

Analysis of Heuristic Graph Partitioning Methods for the Assignment of Packet Control Units in GERAN

Over the last few years, graph partitioning has been recognized as a suitable technique for optimizing cellular network structure. For example, in a recent paper, the authors proposed a classical graph partitioning algorithm to optimize the assignment of cells to Packet Control Units (PCUs) in GSM-EDGE Radio Access Network. Based on this approach, the quality of packet data services in a live environment was increased by reducing the number of cell re-selections between different PCUs. To learn more about the potential of graph partitioning in cellular networks, in this paper, a more sophisticated, yet computationally efficient, partitioning algorithm is proposed for the same problem. The new method combines multi-level refinement and adaptive multi-start techniques with algorithms to ensure the connectivity between cells under the same PCU. Performance assessment is based on an extensive set of graphs constructed with data taken from a live network. During the tests, the new method is compared with classical graph partitioning approaches. Results show that the proposed method outperforms classical approaches in terms of solution quality at the expense of a slight increase in computing time, while providing solutions that are easier to check by the network operator.