Analysis of a coal-derived liquid using highpressure liquid chromatography and synchronous fluorescence spectrometry

Synchronous fluorescence spectra of model polycondensed aromatic hydrocarbon molecules were recorded and used to identify the number of condensed rings in the aromatic molecules. A coal-derived liquid from Yubarishinko coal was initially separated into fractions having different number of condensed aromatic rings, and each fraction was further divided into narrow fractions having different numbers of carbon atoms. These fractions were studied using synchronous fluorescence spectroscopy. Results indicate the potential usefulness of synchronous fluorescence spectroscopy as a method of analysis of complex mixtures as coal-derived liquids despite the limitation of the method that some molecules give only weak peaks. Several components in some fractions were identified by a combination of synchronous fluorescence spectra and conventional excitation and emission fluorescence spectra.     

Flow structure of steam–water mixed spray

In this study, the flow structure of a steam–water mixed spray is studied both numerically and experimentally. The velocity and pressure profiles of single-phase flow are calculated using numerical methods. On the basis of the calculated flow fields, the droplet behavior is predicted by a one-way interaction model. This numerical analysis reveals that the droplets are accelerated even after they are sprayed from the nozzle. Experimentally, the mixed spray is observed using an ultra-high-speed video camera, and the velocity field is measured by using the oarticle image velocimetry (PIV) technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, the mixing process of steam and water and the atomization process of a liquid film are observed using a transparent nozzle. High-speed photography observations reveal that the flow inside the nozzle is annular flow and that most of the liquid film is atomized at the nozzle throat and nozzle outlet. Finally, the optimum mixing method for steam and water is determined.     

Plasma-tolerant structure for organic light-emitting diodes with aluminum cathodes fabricated by DC magnetron sputtering: Using a Li-doped electron transport layer

We fabricate aluminum cathodes that are almost free from plasma damage by DC magnetron sputtering for organic light-emitting diodes (OLEDs). While sputtering is widely known to have numerous advantages over conventional evaporation for mass production of devices, it can cause serious damage to organic layers. In this report, we fabricate devices that are free from plasma damage by introducing a 1%-Li-doped electron transport layer (ETL). The difference of external electroluminescence quantum efficiency between OLEDs with the structure ITO/α-NPD/ETL/Al (where ITO is indium tin oxide and α-NPD is N,N′-di(1-naphthyl)-N,N′-diphenylbenzidine) with Al cathodes deposited by conventional evaporation or sputtering is 0.1%, and their driving voltage is identical. We find that the Li-doped ETL should be thicker than 40 nm. Analysis of the depth profile of the ETL by time-of-flight secondary ion mass spectrometry indicates that considerable damage from sputtering extended to a depth of approximately 30 nm, suggesting that high-energy particles penetrated about 30 nm into the ETL.     

STABILITY TEST OF SRC II DISTILLATES BY ESR

ABSTRACT

The stability of distillates derived from the SRC II coal liquefaction process has been investigated by means of electron spin resonance (e.s.r.). The samples were prepared by storing at room temperature for 8 days in air or in vacuo. The lighter fraction of distillate deteriorated more easily via oxidation than the heavier fraction.     

Defect Detection from Visual Abnormalities in Manufacturing Process Using IDDQ

Abnormal I _DDQ (Quiescent V _DD supply current) indicates the existence of physical damage in a circuit. Using this phenomenon, a CAD-based fault diagnosis technology has been developed to enhance the manufacturing yield of logic LSI. This method to detect the fatal defect fragments in several abnormalities identified with wafer inspection apparatus includes a way to separate various leakage faults, and to define the diagnosis area encircling the abnormal portions. The proposed technique progressively narrows the faulty area by using logic simulation to extract the logic states of the diagnosis area, and by locating test vectors related to abnormal I _DDQ. The fundamental diagnosis way employs the comparative operation of each circuit element to determine whether the same logic state with abnormal I _DDQ exists in normal logic state or not.     

IN-situ monitoring of hydrogen transfer in carbonization reaction by well resolved high-temperature 1H NMR

By means of a well resolved high-temperature ¹H NMR technique, the carbonization process of acenaphthylene as well as the hydrogen transfer from some model compounds and decant oil to anthracene and/or acenaphthylene have been studied. The hydrogen transfer reaction was found to take place in the liquid phase at temperatures above 630 K for the decant oil/anthracene system.     

T1ρ study of pitch softening

Proton rotating frame spin-lattice relaxation time (T_1ρ) measurements have been made in 10 samples of pitch from room temperature to 673 K to obtain information about the mechanisms of pitch softening. The T_1ρ minimum of pitch was found to occur at approximately the same temperature as the softening point. This result suggests that the softening phenomenon of pitch can be detected at the molecular level by T_1ρ measurements. Laboratory frame spin-lattice relaxation time (T₁) measurements were also made on pitches to obtain information about the molecular motion of pitch in the high frequency ranges.