Polymer electrolyte membranes from fluorinated polyisoprene-block-sulfonated polystyrene: Structural evolution with hydration and heating

Small-angle neutron scattering (SANS) and ultra-small-angle X-ray scattering (USAXS) have been used to study the structural changes in fluorinated polyisoprene/sulfonated polystyrene (FISS) diblock copolymers as they evolved from the dry state to the water swollen state. A dilation of the nanometer-scale hydrophilic domains has been observed as hydration increased, with greater dilation occurring in the more highly sulfonated samples or upon hydration at higher temperatures. Furthermore, a decrease in the order in these phase separated structures is observed upon swelling. The glass transition temperatures of the fluorinated blocks have been observed to decrease upon hydration of these materials, and at the highest hydration levels, differential scanning calorimetry (DSC) has shown the presence of tightly bound water. A precipitous drop in the mechanical integrity of the 50% sulfonated materials is also observed upon exceeding the glass transition temperature (T_g), as measured by dynamic mechanical analysis (DMA).     

Synthesis and chain flexibility of poly(cyclohexylethyl methacrylate)

The synthesis and characterization of fractions of poly(cyclohexylethyl methacrylate) (PCHEM) are reported. A combination of low-angle laser light scattering and intrinsic viscosity experiments was employed to estimate the characteristic ratio (C_∞) of this polymer. The value of 10.7 obtained for PCHEM is similar to the value of 11.3 found previously for poly(phenylethyl methacrylate) but is smaller than values measured for poly(cyclohexyl methacrylate) and poly(cyclohexylmethyl methacrylate) (C_∞ = 11.6 and 11.9, respectively). Received: 28 October 1996/Revised: 16 December 1996/Accepted: 19 December 1996     

Heuristic Optimization Model for the Optimal Layout and Pipe Design of Sewer Systems

The design of urban stormwater systems and sanitary sewer systems consists of solving two problems: generating a layout of the system and the pipe design which includes the crown elevations, slopes and commercial pipe sizes. A heuristic model for determining the optimal (minimum cost) layout and pipe design of a storm sewer network is presented. The hierarchical procedure combines a sewer layout model formulated as a mixed-integer nonlinear programming (MINLP) problem which is solved using the General Algebraic Modeling System (GAMS) and a simulated annealing optimization procedure for the pipe design of a generated layout was developed in Excel. The GAMS and simulated annealing models are interfaced through linkage of Excel and GAMS. The pipe design model is based upon the simulated annealing method to optimize the crown elevations and diameter of pipe segments in a storm sewer network using layouts generated using GAMS. A sample scenario demonstrates that using these methods may allow for significant costs saving while simultaneously reducing the time typically required to design and compare multiple storm sewer networks.     

Optimization Models for Layout and Pipe Design for Storm Sewer Systems

Optimization models are developed for simultaneously determining the pipe layout and the pipe design for storm sewer systems. The pipe design process includes computation of commercial diameters, slopes, and crown elevations for the storm sewer pipes. The optimization models aim to minimize the total costs of the layout and the pipe design for most of system elements. The optimization models are formulated as a 0–1 Integer Nonlinear Programming problem and solved using the General Algebraic Modeling System without the use of heuristic models which were characteristic of all previous models for the simultaneous determine of the pipe layout and pipe design of sewer networks. The models are based upon two different optimization approaches: (1) considers one or more commercial diameters of pipe connecting two manholes and (2) considers only one commercial diameter in a pipe connecting two manholes. The commercial diameters, pipe slopes, crown elevations, and total costs of the storm sewer system were compared for the two approaches using an example that illustrates the savings in cost by allowing multiple pipe sizes. The two new optimization modeling approaches developed herein can simultaneously determine the minimum cost pipe design (commercial diameters, slopes, and crown elevations) and pipe layout of storm sewer systems and satisfy all design constraints.

     

Spatial genetic structure and recruitment dynamics of burbot (Lota lota) in Eastern Lake Michigan and Michigan tributaries

Burbot (Lota lota) are the only freshwater member of the Cod like (Lotidae) family that have a circumpolar distribution and occupy the widest geographic distribution of all Laurentian Great Lakes fish species. Information regarding burbot spatial genetic structure and recruitment dynamics is critical for the development of effective management strategies. Although burbot are a species of conservation concern throughout their range, little demographic or behavioral information exists. We estimated levels of genetic diversity within, and the degree of spatial population structure between samples collected from Lake Michigan and tributaries of the Manistee River, MI. Measures of genetic diversity across 10 microsatellite loci were moderately high. Disparities between adult groups sampled in Lake Michigan and the Manistee River were notable for observed heterozygosity (0.662 vs 0.488) and allelic richness (11.7 vs 6.6). Significant levels of inter-population variance in microsatellite allele frequencies (F_ST 0.154 to 0.208) were detected between Lake Michigan and the Manistee River samples. Results indicate reproductive isolation between what plausibly may be riverine and lacustrine spawning life history types. Pedigree analyses for three cohorts sampled in the Manistee River revealed that a sizeable number of adults contributed reproductively to multiple cohorts, indicating spawning philopatry. While data were collected from restricted areas in lacustrine and river habitats, analyses revealing microgeographic genetic structuring, potentially attributed to life history polymorphisms, have significant implications for burbot management in the Great Lakes.     

Sewer System Design Using Simulated Annealing in Excel

An optimization procedure has been developed for branching storm and sanitary sewer systems with a pre-determined layout for determining the minimum total cost. The model was developed within Microsoft Excel using simulated annealing as the optimization procedure. The total cost of the storm sewer system that was obtained with this optimal design procedure was compared to the total cost of the system as obtained from the conventional straight slope design procedure. Applying the simulated annealing optimizer to the design of the branching storm sewer network resulted in a cost savings of over $77,100 or about 7 % (a reduction from $1,117,700 to $1,040,600). These significant savings were realized by simply going an extra step and implementing an optimization technique during the design phase. Use of Excel should enhance the availability and the usage of such an optimization model for the design of storm and sanitary sewer systems by consulting engineers and various agencies.     

Technical and Environmental Sustainability Assessment of Water Distribution Systems

An environmental and technical sustainability assessment methodology is developed for both centralized and dual water distribution systems (WDSs) with and without fire flow scenarios. Technical sustainability of potable and reclaimed water networks is measured by a sustainability index (SI) assessment using reliability, resiliency, and vulnerability performance criteria. The U.S. Environmental Protection Agency EPANET software is used to simulate hydraulic (i.e. nodal pressure) and water quality (i.e. water age) analysis in a WDS. Total fresh water use and total energy intensity are considered as environmental sustainability criteria. The procedure considers two separate alternatives for meeting fire flows: (1) adding pumping to a system or (2) adding a non-potable WDS. The reclaimed system is designed using linear programming (LP) optimization. For each alternative, multi-criteria decision analysis (MCDA) is used to combine technical and environmental sustainability criteria for an urban WDS.     

New Methodology for Optimal Operation of Soil Aquifer Treatment Systems

A new methodology is presented in thisarticle for computing the optimal operation of soilaquifer treatment systems. The mathematical problemis stated as a discrete-time optimal control problemto maximize infiltration subject to various physicaland operation constraints. The methodology is basedupon solving the discrete-time optimal control problemusing a successive approximation linear quadraticregulator interfaced with a simulator. Theunsaturated flow model HYDRUS is modified to simulatethe water content distribution, the infiltrationprocess, and the draining process. A penalty functionmethod is used to treat the bound constraints on thewater content and the cycle time. Sample problems aregiven to illustrate the capability of the model tosolve the optimal operation of soil aquifer treatment systems.