Methylaluminoxane/haloalkane as initiator system for styrene polymerization

Summary Styrene polymerization was initiated by methylaluminoxane in the presence of haloalkane. The propagating species are shown by trapping experiments and electron paramagnetic resonance to be both radicals and cations.     

Structure Development Study of Pb (Zr, Ti)O3 Thin Films by an Optical Method

Lead zirconate titanates (Pb (Zr_xTi_1–x)O₃ or PZT) are well-known materials with useful ferroelectric properties for nonvolatile memory applications. The device applications usually require processes which form the ferroelectric perovskite phase at low temperatures. Understanding the various aspects of structure development of PZT films is the key to develop low-temperature processes. An effective, versatile, and nondestructive optical method was developed for the study of the structure development in PZT films. Also, models for the structure development were proposed and were verified by this optical method. Using this method, the characteristic temperatures at which both pyrochlore phase and perovskite phase are initiated and completed were identified. The pyrochloreperovskite transformation was initiated at lower temperature and completed faster for the films on the titanium-rich side than those on the zirconium-rich side. In addition, the volume fractions of the perovskite phase were obtained as a function of annealing temperature by this optical method.     

High‐Tg Carbazole Derivatives as Blue‐Emitting Hole‐Transporting Materials for Electroluminescent Devices

A series of dicarbazolyl derivatives bridged by various aromatic spacers and decorated with peripheral diarylamines were synthesized using Ullmann and Pd‐catalyzed C–N coupling procedures. These derivatives emit blue light in solution. In general, they possess high glass‐transition temperatures (T_g > 125 °C) which vary with the bridging segment and methyl substitution on the peripheral amine. Double‐layer organic light‐emitting devices were successfully fabricated using these molecules as hole‐transporting and emitting materials. Devices of the configuration ITO/HTL/TPBI/Mg:Ag (ITO: indium tin oxide; HTL: hole‐transporting layer; TPBI: 1,3,5‐tris(N‐phenylbenzimidazol‐2‐yl)benzene) display blue emission from the HTL layer. The EL spectra of these devices appear slightly distorted due to the exciplex formation at the interfaces. However, for the devices of the configuration ITO/HTL/Alq₃/Mg:Ag (Alq₃ = tris(8‐hydroxyquinoline)aluminum) a bright green light from the Alq₃ layer was observed. This clearly demonstrates the facile hole‐transporting property of the materials described here.     

Optical DQPSK Receiver With Enhanced Dispersion Tolerance

We propose and analyze a novel differential quadrature phase-shift-keying (DQPSK) receiver architecture based on optical frequency discriminator filtering and direct detection. Our simulations show that such a receiver provides significantly enhanced tolerance to chromatic dispersion compared with the conventional delay-interferometer-based receiver. Preliminary measurement results demonstrate the novel DQPSK demodulator concept at 20 Gb/s.     

Water bamboo husk reinforced poly(lactic acid) green composites

The water bamboo husk is one of major agricultural wastes in Taiwan. In this study, the powder obtained from the water bamboo husk was added to poly(lactic acid) (PLA) to form novel reinforced biodegradable composites. Morphologies, mechanical properties, and heat resistance of these water bamboo powder reinforced composites were investigated. The results indicate that the char yields were increased as plant powder was incorporated to PLA. In addition, the mechanical properties were also enhanced due to the addition of powders. The increments of storage moduli of PLA were about 50–200%. Moreover, the increments of loss moduli of PLA were about 70–200%. On the other hand, the T_g of PLA was slightly decreased by the addition of powder, and this may improve the brittle characteristics of PLA. Furthermore, this type of reinforced PLA would be more environmental friendly than the artificial additive‐reinforced one. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers     

Five channel WDM soliton pulse generation using sinusoidally drivenelectroabsorption modulators in 16×1 laser/modulator array

Five wavelength multiplexed pulse streams are generated in an integrated 16×1 laser modulator array by sinusoidally driving five of the potential 16 electroabsorption modulators. At a repetition rate of 2.5 GHz, near transform-limited pulses spaced in wavelength over 7.6 nm are observed. Pseudorandom coding of one channel is achieved by applying an electrical RZ data signal to the modulator     

Cyclic hot corrosion of Haynes 230 alloy

Cyclic hot corrosion conducted on Haynes 230 at temperatures of 871 and 1093 C indicated that catastrophic corrosion occurred. The corrosion rate was related to the high content of tungsten and chromium in the alloy. The concept of basic and acid fluxing was applied to explain the dissolution of the protective film of Cr₂O₃ and volatile WO₃ by an Na₂SO₄-rich liquid due to the formation of Na₂CrO₄ and Na₂WO₄. As the basic melts were acidified by continuously consuming oxygen ions, plate-like crystals of Cr₂O₃ were precipitated on the free surface by conversion from Na₂CrO₄. Acid fluxing was achieved by the refractory oxide, WO₃, consuming oxygen ions. The presence of sulphur suppressed the diffusion of chromium outward to form protective Cr₂O₃. Internal chromium-rich sulphide particles were observed. It was suggested that at very lowP _O2, sulphur reacted with chromium to form CrS initially. As oxygen penetrated through the porous layer, the CrS was oxidized internally to Cr₂O₃.     

A dynamic programming approach to sequential pattern recognition

This paper presents the dynamic programming approach to the design of optimal pattern recognition systems when the costs of feature measurements describing the pattern samples are of considerable importance. A multistage or sequential pattern classifier which requires, on the average, a substantially smaller number of feature measurements than that required by an equally reliable nonsequential classifier is defined and constructed through the method of recursive optimization. Two methods of reducing the dimensionality in computation are presented for the cases where the observed feature measurements are 1) statistically independent, and 2) Markov dependent. Both models, in general, provide a ready solution to the optimal sequential classification problem. A generalization in the design of optimal classifiers capable of selecting a best sequence of feature measurements is also discussed. Computer simulated experiments in character recognition are shown to illustrate the feasibility of this approach.     

An empirical study of design-of-experiment data mining for yield-loss diagnosis for semiconductor manufacturing

To maintain competitive advantages, semiconductor industry has strived for continuous technology migrations and quick response to yield excursion. As wafer fabrication has been increasingly complicated in nano technologies, many factors including recipe, process, tool, and chamber with the multicollinearity affect the yield that are hard to detect and interpret. Although design of experiment (DOE) is a cost effective approach to consider multiple factors simultaneously, it is difficult to follow the design to conduct experiments in real settings. Alternatively, data mining has been widely applied to extract potential useful patterns for manufacturing intelligence. However, because hundreds of factors must be considered simultaneously to accurately characterize the yield performance of newly released technology and tools for diagnosis, data mining requires tremendous time for analysis and often generates too many patterns that are hard to be interpreted by domain experts. To address the needs in real settings, this study aims to develop a retrospective DOE data mining that matches potential designs with a huge amount of data automatically collected in semiconductor manufacturing to enable effective and meaningful knowledge extraction from the data. DOE can detect high-order interactions and show how interconnected factors respond to a wide range of values. To validate the proposed approach, an empirical study was conducted in a semiconductor manufacturing company in Taiwan and the results demonstrated its practical viability.