涂料中可溶性Pb、Cr含量测定结果误差原因分析

研究并详细讨论了涂料样品制备与样品前处理过程中,各个因素对可溶性Pb、Cr含量测定结果的影响。结果表明:漆膜的厚度、粒径、提取液的酸度、温度等因素对结果的测定有较大的影响,应当对这些因素予以控制以提高实验室间结果一致性。     

Study on purification and application of novel precipitant for ceria-based polishing powder

Novel precipitant prepared through carbonation with MgCl2 wastewater generated from rare earth extraction separation process and low-price dolomite as raw materials was studied in this paper. The purification methods of novel precipitant by adding appropriate oxidizing agent were studied. It was found that optimal purification result could be achieved with sodium hypochlorite as iron removal reagent and the iron removal rate could reach up to 90% when the adding amount was 0.1 vol.%. During the preparation, the particle size and distribution of ceria-based polishing powder were affected obviously by the parameters such as concentration, reaction temperature and feeding rate. The results showed that ceria-based polishing powder with D50 =2.5-3.5 μm and the particle size distribution of 0.65-0.75 μm could be prepared when the concentration of CeCl3 was 0.6 mol/L, the reaction temperature was maintained at 50 °C and the feeding speed was controlled at 25 ml/min. Compared with commercial powder, the self-made polishing powder had roughly the same cutting amount, but the surface finish of polished glass was better than that of commercial polishing powder.     

Compressive sensing-based wind speed estimation for low-altitude wind-shear with airborne phased array radar

An important issue in low-altitude wind-shear detection is to estimate the wind speed of wind field. In this paper, a novel method for wind speed estimation with airborne phased array radar is proposed by combining space time adaptive processing and compressive sensing. The proposed method is able to achieve accurate wind speed estimate in the condition of limited number of sampling pulses, as demonstrated by numerical examples.     

Novel poly(3‐hydroxybutyrate) composite films containing bioactive glass nanoparticles for wound healing applications

Bioactive glass is considered an ideal material for haemostasis as it releases Ca²⁺ ions upon hydration, which is required to support thrombosis. In this study the effects of the presence of nanoscaled bioactive glass (n‐BG) in poly(3‐hydroxybutyrate) (P(3HB)) microsphere films on the structural properties, thermal properties and biocompatibility of the films were studied. The n‐BG with a high surface area was also tested for its in vitro haemostatic efficacy and was found to be able to successfully reduce clot detection time. In an effort to study the effect of the roughness induced by the formation of hydroxyapatite on cellular functions such as cell adhesion, cell mobility and cell differentiation, the composite films were immersed in simulated body fluid for periods of 1, 3 and 7 days. From scanning electron microscopy images, the surface of the P(3HB)/n‐BG composite microsphere films appeared fairly uniform and smooth on day 1; however on day 3 and day 7 a rough and uneven surface was observed. The presence of hydroxyapatite on the composite microsphere films on day 3 and day 7 influenced the surface roughness of the films. However, when the P(3HB)/n‐BG composite microsphere films with enhanced surface roughness were tested for biocompatibility, reduced amounts of protein adsorption and cell adhesion were observed. This study thus revealed that there is an optimal surface roughness for the P(3HB) microsphere films for increased cell adhesion, beyond which it could be deleterious for cell adhesion and differentiation. © 2016 Society of Chemical Industry     

Interactions among biomass components during co-pyrolysis in (macro)thermogravimetric analyzers

The interactions of biomass components (hemicellulose, cellulose, and lignin) during co-pyrolysis were investigated in a thermogravimetric analyzer (TGA) as well as a self-designed Macro-TGA with higher heating rate and larger amount of sample. The overlap ratio (OR) was used to evaluate the interaction of biomass components quantitatively. In TGA, the pyrolysis of xylan was not significantly affected by cellulose, whereas the pyrolysis of cellulose was markedly influenced by xylan. The interactions between xylan and lignin were weak with an overlap ratio of 0.9869, whereas co-pyrolysis of cellulose and lignin was strongly inhibited by interactions with the overlap ratio of 0.9737. In Macro-TGA, interactions between components were stronger than that in TGA due to more considerable heat and mass transfer effect.     

一起220kV电容式电流互感器爆炸事故的分析

介绍了爆炸事故的简要经过和设备概况,为分析事故的原因对互感器进行了解体检查,结合解体检查结果,分析互感器设计制造工艺中存在的问题,分析事故原因和事故发展过程,并提出几点建议和预控措施。     

基于RBF神经网络的FeO-MnO渣系ZGMn13堆焊焊条的设计

为设计一种ZGMn13堆焊焊条,提出了一种基于RBF神经网络的FeO-MnO渣系焊条配方优化设计方法.利用试验采集的数据对网络进行训练,以加工硬化后的硬度为优化目标,得到最优的焊条配方.试验结果表明:优化后熔敷金属的动载加工硬化性能和静载加工硬化性能良好.     

夜间通风在不同气候条件下的适用性

近年来,夜间通风作为一种被动式降温手段受到越来越多的关注。为了研究夜间通风在中国不同气候条件下的节能效果,选取北京、上海、广州分别作为寒冷地区、夏热冬冷地区以及夏热冬暖地区的代表城市,使用建筑能耗模拟软件Energyplus建立一个办公建筑模型,分别在使用和未使用夜间通风的情况下计算出3个城市建筑在供冷季各月的供冷能耗和总能耗,通过对比,分析夜间通风的节能效果。研究结果表明,在相同的月份,夜间通风的效果会随着城市纬度的增加而增大,但对于整个供冷季,即便是在低纬度的夏热冬暖地区,夜间通风也具有显著的节能效果。     

Effects of Carbon and Oxygen Impurities on Luminescence Properties of BCNO Phosphor

The BN and BCNO phosphors were prepared at 750°C using different methods and their structure and luminescent properties were investigated. All the prepared samples were turbostratic boron nitride structure. The SEM and high‐resolution TEM images show that the BCNO phosphors are polycrystalline in nature and include some nanocrystals. The carbon and oxygen impurities have great effects on the excitation, emission, and absorption spectra of BN and BCNO phosphors. The first‐principle calculations results indicate that the carbon and oxygen impurities will produce energy levels in the band gap, which can affect the spectra properties of BCNO phosphors. The spectra properties of BN and BCNO phosphors can be well explained by a simplified energy level diagram.