Copolymerization of ethanesultam with 2-methyl-2-oxazoline

Summary This paper describes the so-called No Catalyst Copolymerization between dioxo-1,1-thiazetidine-1,2(Ethanesultam; ESm) and 2-methyl-2-oxazoline. The copolymerization took place without any added initiator to produce copolymers of MeOZO and ESm. The structure of the copolymer was determined by the IR and NMR spectra, elemental analysis, as well as by the result of an alkaline hydrolysis of the copolymer. The reaction scheme of the copolymerization via zwitterion mechanism (Eq 3–5) was proposed.     

Semiconductor Passivation and Insulation Properties for Hydroxyl- and Fluoride-Free ZnO-SiO2-B2O3-Al2O3 Glasses Stabilized by Increased P2O5

F⁻- and OH⁻-free ZnO-B₂O₃-SiO₂-Al₂O₃-P₂O₅ glasses used for semiconductor-device passivation or insulation are investigated with regard to compositional dependencies for thermal expansion, viscosity points, and metal oxide semiconductor (MOS) capacitor properties. The experimental data show that thermal expansion increases, and flow points decrease, when P₂O₅ is substituted for B₂O₃. MOS capacitors passivated by OH⁻- and F⁻-free ZnO-based glasses exhibit normal capacitance-voltage curves.     

Liquid crystalline side-chain polysiloxanes containing mesogenic groups attached by esterification

Summary Liquid crystalline side-chain polysiloxanes were prepared without metal complex catalyst. Mesogenic groups such as cholesteryl, 4-cyano-4-biphenyl and 4-methoxy-4-biphenyl group were introduced into polysiloxane by esterification and from DSC measurements they were compatible with other liquid crystalline polysiloxanes reported previously.     

Transmission of correct gaze direction in video conferencing using screen-embedded cameras

In this paper, we propose a new video conferencing system that presents correct gaze directions of a remote user by switching among images obtained from multiple cameras embedded in a screen according to a local user’s position. Our proposed method reproduces a situation like that in which the remote user is in the same space as the local user. The position of the remote user to be displayed on the screen is determined so that the positional relationship between the users is reproduced. The system selects one of the embedded cameras whose viewing direction towards the remote user is the closest to the local user’s viewing direction to the remote user’s image on the screen. As a result of quantitative evaluation, we confirmed that, in comparison with the case using a single camera, the accuracy of gaze estimation was improved by switching among the cameras according to the position of the local user.

     

退火对Inconel718合金氢脆特性的影响

通过实施不同的退火热处理工艺，调整合金中强化相的析出状态，制备具有不同退火状态的几组拉伸试样。对每组试样在未充氢和充氢后按相同的条件进行拉伸试验对该组试样的脆化作用。通过比较不同组试样的脆化表现通过比较未充氢试样和充氢后试样的强度和塑性，评价氢考察退火状态对Inconel 718氢脆倾向的影响。试验结果表明，随着退火程度的加强，强化相体积分数减少，氢引起的塑性损失下降，即抗氢脆性能改善。该结果说明，强化相γ″和γ′对Inconel 718合金的氢脆有促进作用。因此，根据不同工业应用要求，在符合强度要求的前提下，可以通过热处理改善零件的抗氢脆性能。     

Chromium-nitride in situ composites with a compositional gradient formed by reactive DC plasma spraying

Nitrides of transition metals have good wear- and corrosion-resistant properties because of their high hardness and chemical stability. Chromium-nitride coatings can be deposited by ion plating; however, the thin thickness due to the slow deposition rate must be improved for severe wear-resistant applications. The main objective in this paper is to realize good structural control in the processing of chromiumnitride in situ composite coatings formed at a high deposition rate. They were synthesized by reactive low-pressure plasma spraying using elemental chromium powder as a spray material. The transferred arc between the gun electrode and the substrate was used to accelerate the nitriding reaction. The sprayed coatings consist of chromium, Cr₂N, and CrN, which have a composition gradient from the substrate interface to the surface. The volume fraction of Cr₂N increases with transferred arc current, and nonreacted chromium concurrently decreases, except close to the substrate. The CrN phase, however, only exists as a surface layer of 20 to 30 μm because it is decomposed to Cr₂N above 1420 K. The hardness of the composite coatings depends on the volume fraction of Cr₂N, and it increases to 1300 HV at a Cr₂N volume fraction of 0.98. The seizure stress with lubricant depends on the coating hardness. The maximum seizure stress of 24.9 MPa is obtained at a hardness of 1300 HV. The composite coatings also show a superior wear resistance. Hence, the Cr₂N in situ composite coatings synthesized by reactive plasma spraying with transferred arc are expected to be good candidates for wear-resistant applications.     

Surface nitridation of titanium metal by means of a gas tunnel type plasma jet

The surface nitridation of titanium was carried out at a low pressure in nitrogen atmosphere using a gas tunnel type plasma jet. The titanium nitride (TiN) film, 10 μm thick and 2000 HV, could be formed in 10 s. The structure of the TiN film was investigated by XRD. The Vickers hardness on the surface of the film was measured. The effects of deposition conditions on the properties of TiN films (TiN thickness,Vickers hardness, etc.) were investigated, and the advantage of this deposition method was identified from those results.     

Effects of blasting parameters on removability of residual grit

This article shows the quantitative evaluation of the residual grit on a blasted substrate, and the removability of the residual grit is examined. Carbon steel plates were blasted by white alumina grit with mean diameters of 338 to 1106 μm. The velocity and the number of grit particles were measured during blasting. The residual grit was removed from a substrate surface by the dissolution of the blasted substrate surface. A mixed acid solution was used as the dissolution solution. The residual grit weight was 7 to 17 g/m². The amount of the residual grit and the penetration depth of the embedded grit increased with increasing grit size. The penetration depth was 5 to 9% of the mean diameter of the grit. The residual grit weight and the penetration depth increased with the increase of the momentum of the grit particle. This article was originally published inBuilding on 100 Years of Success, Proceedings of the 2006 International Thermal Spray Conference (Seattle, WA), May 15–18, 2006, B.R. Marple, M.M. Hyland, Y.-Ch. Lau, R.S. Lima, and J. Voyer, Ed., ASM International, Materials Park, OH, 2006.     

激光退火对Inconel 718微观组织和硬度的影响

研究激光退火对Inconel718时效合金的显微组织和硬度的影响.一台2.5kW的CO2激光机被用来照射试样的表面.在激光能作用下,试样表面层被加热后空冷.通过控制激光工艺参数,在表面不发生熔化的前提下,能够使一定厚度表面层内的硬度降低到标准退火合金的水平,而不影响试样内部母材的硬度.显微组织观察显示表面层的基体强化相(γ″和γ‘)在激光照射过程中被固溶,而其它二次相没有变化.γ″和γ‘的固溶被确定是表面层硬度下降的原因.在其它试验条件不变时,确立了退火层生成时由激光散焦距离和扫描速度描述的工艺参数范围.