全文获取类型
收费全文 | 909篇 |
免费 | 75篇 |
国内免费 | 5篇 |
专业分类
电工技术 | 3篇 |
综合类 | 3篇 |
化学工业 | 256篇 |
金属工艺 | 12篇 |
机械仪表 | 46篇 |
建筑科学 | 25篇 |
矿业工程 | 2篇 |
能源动力 | 36篇 |
轻工业 | 150篇 |
水利工程 | 12篇 |
石油天然气 | 12篇 |
无线电 | 81篇 |
一般工业技术 | 113篇 |
冶金工业 | 141篇 |
原子能技术 | 7篇 |
自动化技术 | 90篇 |
出版年
2024年 | 2篇 |
2023年 | 12篇 |
2022年 | 40篇 |
2021年 | 58篇 |
2020年 | 40篇 |
2019年 | 45篇 |
2018年 | 47篇 |
2017年 | 50篇 |
2016年 | 40篇 |
2015年 | 28篇 |
2014年 | 43篇 |
2013年 | 57篇 |
2012年 | 46篇 |
2011年 | 67篇 |
2010年 | 47篇 |
2009年 | 28篇 |
2008年 | 26篇 |
2007年 | 23篇 |
2006年 | 23篇 |
2005年 | 23篇 |
2004年 | 20篇 |
2003年 | 10篇 |
2002年 | 20篇 |
2001年 | 10篇 |
2000年 | 11篇 |
1999年 | 12篇 |
1998年 | 36篇 |
1997年 | 26篇 |
1996年 | 19篇 |
1995年 | 13篇 |
1994年 | 6篇 |
1993年 | 8篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 12篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1969年 | 2篇 |
1966年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有989条查询结果,搜索用时 15 毫秒
51.
A prism coupler based plasmonic sensor consisting of a prism, gold (Au) metal film and dielectric sample has been investigated with the use of admittance loci method in wavelength interrogation mode. Prism materials namely fused silica, chalcogenide (2S2G) and silicon have been used to study their effect on surface plasmon sensing in wavelength interrogation mode by admittance loci plots and by corresponding surface plasmon sensing curves. The performance of the plasmonic sensor under wavelength interrogation mode based on the choice of the prism material has been discussed and validated by the dynamic range and sensitivity plots. 相似文献
52.
Hsi-Wu Wong Mina Jun Jay Peck Ian A. Waitz Richard C. Miake-Lye 《Aerosol science and technology》2014,48(9):981-995
The development of a detailed microphysical model that describes the complex multicomponent interactions between organic vapors and soot particles emitted from aircraft gas turbine engines is presented. Our model formulation includes both soot surface activation by organic vapors and organic vapor condensation on the activated part of the soot surfaces. To enable this formulation, approaches to estimate chemical and physical properties of aerosols containing complex mixtures of sulfuric acid, water, and organic molecules were developed. Relevant distributions of a list of organic surrogates at the engine exit plane were used to represent complex organic emissions from aircraft engines. A parametric study was performed using this new formulation to understand the effects of ambient conditions, organic emissions levels, and mass accommodation coefficient values on the evolution of near field volatile particulate matter emissions from aircraft engines at ground level.
Copyright 2014 American Association for Aerosol Research 相似文献
53.
Some hearing, vestibular, and vision disorders are imputable to voltage-gated Ca2+ channels of the sensory cells. These channels convey a large Ca2+ influx despite extracellular Na+ being 70-fold more concentrated than Ca2+; such high selectivity is lost in low Ca2+, and Na+ can permeate. Since the permeation properties and molecular identity of sensory Ca2+ channels are debated, in this paper, we examine the Na+ current flowing through the L- and R-type Ca2+ channels of labyrinth hair cells. Ion currents and cytosolic free Ca2+ concentrations were simultaneously monitored in whole-cell recording synchronous to fast fluorescence imaging. L-type and R-type channels were present with different densities at selected sites. In 10 nM Ca2+, the activation and deactivation time constants of the L-type Na+ current were accelerated and its maximal amplitude increased by 6-fold compared to physiological Ca2+. The deactivation of the R-type Na+ current was not accelerated, and its current amplitude increased by 2.3-fold in low Ca2+; moreover, it was partially blocked by nifedipine in a voltage- and time-dependent manner. In conclusion, L channel gating is affected by the ion species permeating the channel, and its selectivity filter binds Ca2+ more strongly than that of R channel; furthermore, external Ca2+ prevents nifedipine from perturbing the R selectivity filter. 相似文献
54.
Mina Han Ikue Abe Jihun Oh Jaehoon Jung Young Ji Son Jaegeun Noh Mitsuo Hara Takahiro Seki 《International journal of molecular sciences》2022,23(2)
Fluorescent molecular assembly systems provide an exciting platform for creating stimuli-responsive nano- and microstructured materials with optical, electronic, and sensing functions. To understand the relationship between (i) the plausible molecular structures preferentially adopted depending on the solvent polarity (such as N,N-dimethylformamide [DMF], tetrahydrofuran [THF], and toluene), (ii) the resulting spectroscopic features, and (iii) self-assembled nano-, micro-, and macrostructures, we chose a sterically crowded triangular azo dye (3Bu) composed of a polar molecular core and three peripheral biphenyl wings. The chromophore changed the solution color from yellow to pink-red depending on the solvent polarity. In a yellow DMF solution, a considerable amount of the twisted azo form could be kept stable with the help of favorable intermolecular interactions with the solvent molecules. By varying the concentration of the DMF solution, the morphology of self-assembled structures was transformed from nanoparticles to micrometer-sized one-dimensional (1D) structures such as sticks and fibers. In a pink-red toluene solution, the periphery of the central ring became more planar. The resulting significant amount of the keto-hydrazone tautomer grew into micro- and millimeter-sized 1D structures. Interestingly, when THF-H2O (1:1) mixtures were stored at a low temperature, elongated fibers were stacked sideways and eventually developed into anisotropic two-dimensional (2D) sheets. Notably, subsequent exposure of visible-light-irradiated sphere samples to solvent vapor resulted in reversible fluorescence off↔on switching accompanied by morphological restoration. These findings suggest that rational selection of organic dyes, solvents, and light is important for developing reusable fluorescent materials. 相似文献
55.
Davide Ciardiello Brigida Anna Maiorano Paola Parente Maria Grazia Rodriquenz Tiziana Pia Latiano Cinzia Chiarazzo Valerio Pazienza Luigi Pio Guerrera Brunella Amoruso Nicola Normanno Giulia Martini Fortunato Ciardiello Erika Martinelli Evaristo Maiello 《International journal of molecular sciences》2022,23(2)
Biliary tract cancers (BTC) represent a heterogeneous and aggressive group of tumors with dismal prognosis. For a long time, BTC has been considered an orphan disease with very limited therapeutic options. In recent years a better understanding of the complex molecular landscape of biology is rapidly changing the therapeutic armamentarium. However, while 40–50% of patients there are molecular drivers susceptible to target therapy, for the remaining population new therapeutic options represent an unsatisfied clinical need. The role of immunotherapy in the continuum of treatment of patients with BTC is still debated. Despite initial signs of antitumor-activity, single-agent immune checkpoint inhibitors (ICIs) demonstrated limited efficacy in an unselected population. Therefore, identifying the best partner to combine ICIs and predictive biomarkers represents a key challenge to optimize the efficacy of immunotherapy. This review provides a critical analysis of completed trials, with an eye on future perspectives and possible biomarkers of response. 相似文献
56.
封堵性是油基钻井液的一个重要评价指标,提高油基钻井液的封堵性有助于井壁稳定,促进快速安全钻井.本文通过使用砂芯漏斗来模拟页岩的微裂缝,建立了一种新的评价油基钻井液封堵性能的方法,利用该方法对自制的纳米材料CQ-NZC在钻井液封堵性及其与氧化沥青封堵剂的复合作用开展了实验研究.结果表明,CQ-NZC在与沥青类封堵剂复配使用时,能够更好地降低滤失量、提高封堵性能.通过微观形态分析发现,CQ-NZC与沥青类封堵剂可以在一定程度上聚结,形成堵孔粒子,提升了钻井液体系的封堵性能. 相似文献
57.
Reduction of dietary sodium intake by lowering amount of sodium in foods is a global industry target. Quantitative information on current consumer knowledge of sodium reduction trends in Korea is unknown. The objective of this study was to quantify the consumer knowledge and awareness of sodium and salt reduction in foods and to characterize consumer interest in health labeling on the food package. Additionally, comparison of consumer knowledge status between Korea and United States was followed. Consumers (n = 289) participated in an internet survey designed to gauge consumer knowledge and attitudes toward dietary sodium, the sodium content in representative food products (n = 27), and their interest toward specific health claims, including sodium labeling. Questions regarding demographics as well as consumption characteristics were asked. Sodium knowledge index and saltiness belief index were calculated based on the number of correct responses regarding the salt level and sodium content in given food products. Kano analysis was conducted to determine the role of nutrition labels in consumer satisfaction with products. Current consumer knowledge on the sodium content in food products was high, and consumers were adept at matching the sodium content with the salty taste intensity of food products. Consumers’ knowledge of the relationship between diets high in sodium and an increased risk of developing previously reported sodium‐related diseases, such as hypertension, coronary heart disease, kidney disease, and stomach cancer, were also high. Information on the nutrition panel that influences the consumer satisfaction (trans‐fat, sodium, ingredient list, and country of origin) as well as adjective‐nutrition claim pairs that appeal positively to purchase intent of the product were identified. 相似文献
58.
The effect of linear styrene–butadiene polymer structure on the temperature–viscosity behavior of model polymer-base oil solutions is investigated using molecular dynamics simulations. Simulations of alternating, random, and block styrene–butadiene polymers in a dodecane solvent are used to calculate viscosity at 40 and 100 °C, reference temperatures for characterizing their function as viscosity modifiers. Mechanisms underlying this function are explored by quantifying the radius of gyration and intramolecular interactions of the polymers at the same reference temperatures. The block styrene–butadiene configuration exhibits the least change in viscosity with temperature, characteristic of a good viscosity modifier or viscosity index improver, and the behavior is correlated to the ability of this structure to form smaller coils with more intramolecular interactions at lower temperatures and then expand as temperature is increased. The results indicate that there is a correlation between styrene–butadiene polymer structure, additive function, and the mechanisms underlying that function. 相似文献
59.
Effect of process variables on product yield distribution in thermal catalytic cracking of naphtha to light olefins over Fe/HZSM-5 总被引:1,自引:0,他引:1
Mina Alyani Jafar Towfighi Seyed Mojtaba Sadrameli 《Korean Journal of Chemical Engineering》2011,28(6):1351-1358
The effect of temperature, WHSV and Fe loading over HZSM-5 catalyst in thermal-catalytic cracking (TCC) of naphtha for the
production of light olefins has been studied. The response surface defined by three most significant parameters is obtained
from Box-Behnken design method and the optimal parameter set is found. The results show that ethylene increases with temperature,
while propylene shows an optimum at 650 °C. Moderate WHSV is favorable for maximum production of light olefins. Addition of
Fe to HZSM-5 has a favorable effect on the production of light olefins up to 6% of loading. Excess amount of loading decreases
the conversion of naphtha, which leads to a drop in light olefin yields. The yield of light olefins (ethylene and propylene)
at 670 °C, 44 hr−1 and 6 wt% Fe has been increased to 5.43 wt% compared to the unmodified HZSM-5 and reaches to 42.47 wt%. 相似文献
60.
Hajimahmoodi Mannan Khanavi Mahnaz Sadeghpour Omid Ardekani Mohammad Reza Shams Mazde Fatemeh Zamani Khoddami Mina Sadat Afzalifard Sheida Ranjbar Ali Mohammad 《Food Analytical Methods》2016,9(12):3451-3459
Food Analytical Methods - Vinegar as a nutraceutical substance is classified to various types related to the different substances applied in production process. Therefore, identity of the source... 相似文献