Application of substituted N-arylpyrroles in the corrosion protection of aluminium in hydrochloric acid

The inhibiting action of N-arylpyrroles on aluminium in 0.17 mol dm^–3 hydrochloric acid solution, in the temperature range 20–60 °C, was studied using potentiodynamic and electrochemical impedence spectroscopy techniques. The inhibiting efficiency of both investigated compounds 1-(2-fluorophenyl)-2,5-dimethylpyrrole (compound A) and 1-(2-fluorophenyl)-2,5-dimethylpyrrole-3-carbaldehyde (compound B) slightly increases with increasing temperature of the corrosive solution. Inhibitor adsorption on the elecrode surface decreases the apparent activation energy of the hydrogen evolution reaction. Compound A follows the Temkin adsorption isotherm, while its carbaldehyde derivative follows the Langmuir isotherm. The results of the apparent energy of activation and the standard free energy of adsorption point to stronger chemisorption of the compound A. However, due to additional condensation of molecules with carbaldehyde groups on the electrode surface, the carbaldehyde derivative exhibits even better inhibiting efficiency than compound A. The kinetic corrosion parameters, analysed in terms of the impedance data, show a satisfactory agreement with those obtained by the potentiodynamic method.     

On some interval methods for algebraic,exponential and trigonometric polynomials

New inclusion methods for the simultaneous determination of the zeros of algebraic, exponential and trigonometric polynomials are presented. These methods are realized in real interval arithmetic and do not use any derivatives. Using Weierstrass' correction some modified methods with the increased convergence rate are constructed. Convergence analysis and numerical example are included.     

Josephson junction with an amorphous silicon barrier

A Josephson junction Nb/Si/Nb with a 10 nm thick amorphous silicon barrier is studied. The upper electrode contains a 2 nm thick sublayer of amorphous phase adjacent to the barrier, as revealed by cross-sectional TEM. Thus, the junction can be considered as a S-I-N-S system with the N layer represented by amorphous niobium. Peculiarities in the I–V and Δ(T) dependencies are observed and explained as a consequence of a proximity effect present in the upper electrode.     

An approach to emulating separable graphs

A technique foremulating multicomputer interconnection networks that are based onseparable graphs (graphs having bounded degree and sublinear multicolor recursive bisectors) is presented. Efficient emulations among interconnection networks are necessary for porting programs designed for one network to another.Emulations are formalized asgraph embeddings, where the nodes (processors) of theguest graph (emulated network) are assigned to nodes of thehost graph (emulator), while the edges (communication links) of the guest are routed via paths in the host. The communication slowdown in an emulation depens on thedilation (length of the longest routing path) and thecongestion (number of paths that contend for a host edge) of the embedding. Theexpansion of the embedding (the ratio of the sizes of the host to guest) determines the inefficiency of processor utilization. Cell trees are introduced as interconnection networks whose special communication properties enable them to serve as intermediate devices in these emulations. Nodes in cell trees are organized into equinumerous parts calledcells; the cells are labeled by nodes of a complete binary tree. Communication in cell trees is restricted to two specific and distinct primitives:cell communication is confined within cells, whiletransfer communication occurs between adjacent cells. Rather than solved directly, the emulation problem for the original guest-host pair is decomposed into two independent parts: emulating the guest by the cell tree, and emulating the cell tree by the host.In emulations of separable graphs by cell trees, the node assignment that ensures small dilation is derived from the separator-based decomposition of guest graphs. The congestion-free edge routing is achieved by coordinatingglobal andlocal phases, which are based on two characteristic cell-tree communication primitives.The technique is instantiated by emulating cell trees on specific host graphs. Withshuffle-like hypercube-derivative networks as hosts new constant-expansion emulations are obtained that have both dilation and congestion logarithmic in the size of the multicolor bisector of guest graphs. These emulations are the first such to have optimal (up to constants)congestion; they provide the firstoptimal algorithm for emulating arbitrary separable graphs on shuffle-like networks. The application of the technique tohypercubes as hosts also produces optimal emulations that differ from those previously known by having smaller expansion constants.This research was supported in part by NSF Grants CCR-88-12567 and CCR-90-13184, and by the University of Massachusetts Graduate School Fellowship for the academic year 1991-92. A preliminary version of this paper was presented at the 3rd ACM Symposium on Parallel Algorithms and Architectures, July 22–24, 1991, in Hilton Head, South Carolina, USA.     

Reactive energy measurement using frequency controlled analog-to-pulse-rate converter

Contents This paper analyzes a problem of phase shifting and deseribes a novel method for electronic reactive energy measurement. The proposed measurement structure, composed of an integrator as a phase shifting circuit and a frequency controlled analog-to-pulse-rate converter, provides for the measurement completely in accordance with IEC definition of reactive energy, which is performed with simple but high performance metering device.

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Die Blindverbrauchsmessung anhand eines netzsynchronisierten Analog-Frequenz-Wandlers

Übersicht In diesem Artikel wird das Problem der Phasenverschiebung analysiert und eine neue Meßmethode für elektronische Blindverbrauschsmessung aufgezeigt. Die vorgeschlagene Strucktur, bestehend aus einem Integrator als Phasenschieber und netzkontrolliertem Analog-Frequenz-Wandler, ermöglicht die Verwirklichung eines einfachen aber präzisen Elektrizitätszählers zur Messung der Blindenergie, dessen Arbeitsprinzip mit den IEC Empfehlungen vollkommen übereinstimmt.

     

Computer program for the construction of the level scheme on the basis of energy balance of gamma transitions

A computerised method is presented for the construction of the level scheme on the basis of measured energies of the gamma transitions without any previous knowledge of the observed isotope. The method and the steps of the algorithm are discussed. The calculated results are compared with the published schemes for the given isotopes.     

Scientometric analysis of the research activities of chemists from the “Rugjer Bošković” Institute (Yugoslavia), 1976–1985

The research activity of chemists from the Rugjer Bokovi Institute (RBI, Zagreb, Yugoslavia) was analyzed for the period 1976–1985, covering 2018 research years of scientific work, and 1149 SCI registered papers (0.57 publications per research year). At the average, one paper was published by 3.05 scientists. The papers were published in 235 different journals, most frequently is the nationalCroatica Chemica Acta (171 papers). The publications were divided into two groups: for the periods 1976–1980 and 1981–1985, and for each paper citations were collected in the respective time period. An average publication had 2.58 citations. Chemical papers from the second period had 2.73 citations per paper, which is 85% of the expected value, and this was considerably more than for Yugoslav papers (66%) in general. The papers were classified according to the subfields used in theJournal Citation Reports, and the results compared with the data published bySchubert, Glänzel andBraun. The distribution of citations was also analyzed.     

Phase transformation and densification during pressureless sintering of Si3N4 with MgO and Y3Al5O12 additives

The - transformation of Si₃N₄ during liquid-phase sintering appears to be controlled by the growth of the -Si₃N₄ grains in the direction perpendicular to thec-axis in the case of MgO additive. The diffusion through the liquid is the rate-controlling step in the case of the Y₄Al₅O₁₂ additive. The density of the sintered body at the solid skeleton stage was influenced by the change in the - transformation rate and/or by a change of the transformation mechanism. The indirect proportionality between the -phase content in the starting powder and the density at the solid skeleton stage was found. The microstructure of the sintered body is influenced by both the -phase content in the starting powder and the chemical composition of the additive. Fine, uniform microstructure with a high aspect ratio of -grains is obtained, when the -phase content in the starting powder is as small as possible and when the - transformation is controlled by grain growth.     

Challenges and opportunities of multimodal data in human learning: The computer science students' perspective

Multimodal data have the potential to explore emerging learning practices that extend human cognitive capacities. A critical issue stretching in many multimodal learning analytics (MLA) systems and studies is the current focus aimed at supporting researchers to model learner behaviours, rather than directly supporting learners. Moreover, many MLA systems are designed and deployed without learners' involvement. We argue that in order to create MLA interfaces that directly support learning, we need to gain an expanded understanding of how multimodal data can support learners' authentic needs. We present a qualitative study in which 40 computer science students were tracked in an authentic learning activity using wearable and static sensors. Our findings outline learners' curated representations about multimodal data and the non-technical challenges in using these data in their learning practice. The paper discusses 10 dimensions that can serve as guidelines for researchers and designers to create effective and ethically aware student-facing MLA innovations.