羧甲基淀粉的应用与合成

综述了羧甲基淀粉的发展、合成方法、合成过程中的影响因素以及应用现状。羧甲基淀粉的合成主要分三种类型 :干法、半干法、湿法。综合了反应过程中的影响因素 ,例如醚化剂和催化剂的影响 ,反应时间和温度的关系 ,溶剂、设备对反应的影响 ,以及在食品、医药、钻井、纺织、日化工业中的应用前景     

BP网络算法在平面运动测量误差补偿中的应用

在航天对接试验平台开发项目中,针对平面运动物体非接触高精度测量的难点,提出一种针对物体三自由度平面运动的创新性测量方法.利用激光测距传感器的并联组合,实现对物体位置和姿态的非接触式测量.以传感器测量值为输入样本,运用BP神经网络算法建立误差模型,通过调整权值因子使建立的网络模型能够拟合出测量误差,从而修正测量的数学模型.基于BP神经网络的误差补偿方法对平面运动物体测量误差的补偿具有明显的效果,能够满足位姿测量的精度要求.     

天然藻类对废水中 COD 的去除效率研究

目前废水中COD的处理问题是我国乃至世界各国普遍关注的问题,找到一种操作简单、成本低且效果好的处理方法是解决问题的关键所在。利用天然藻类中绿藻、硅藻处理不同类型废水,以COD作为检测指标。结果表明,绿藻对废水中COD的去除率最高。同时探讨了不同初始浓度的COD、不同种类废水中COD的去除效率。     

宁夏黄河段水库泥沙淤积对大坝防渗与结构安全影响研究

以宁夏黄河段某水库为例,在对其泥沙淤积原因进行总结分析的基础上,对其淤积情况下大坝渗流分析、结构分析及抗震安全分析进行了有限元计算。研究表明:(1)泥沙淤积情况下大坝渗漏量减小,大坝稳定性增强,抗震安全系数增大;(2)泥沙淤积导致水库有效库容减小,水库建筑物无法正常工作,水库下游生活用水和农业用水无法满足,应采取必要的清淤措施。     

WSN 中基于粒子滤波的目标跟踪研究

针对无线传感器网络中仅有角度测量的目标跟踪问题,详细分析其定位过程,提出一种基于改进粒子滤波算法的新解决方案.方案采用高斯混合模型(GMM)代替单一模型近似概率密度分布,融入粒子滤波算法,提议分布采用SRUKF-PF算法更新粒子.算法中增加改进措施以提高滤波性能如:残差重采样算法用于重采样、K-means算法用于构建预估起始点、EM算法用于拟合GMM近似等.仿真结果验证了方案的有效性.     

Somatic mutation favors the evolution of diploidy

Explanation of diploidy have focused on advantages gained from masking deleterious mutations that are inherited. Recent theory has shown that these explanations are flawed. Indeed, we still lack any satisfactory explanation of diploidy in species that are asexual or that recombine only rarely. Here I consider a possibility first suggested by Efroimson in 1932, by Muller in 1964 and by Crow and Kimura in 1965: diploidy may provide protection against somatic, not inherited, mutations. I both compare the mean fitness of haploid and diploid populations that are asexual and investigate the invasion of "diploidy" alleles in sexual populations. When deleterious mutations are partially recessive and somatic mutation is sufficiently common, somatic mutation provides a clear advantage to diploidy in both asexual and sexual species.     

Tandem mass spectrometry and nuclear magnetic resonance spectroscopy studies of Candida bombicola sophorolipids and product formed on hydrolysis by cutinase

Natural mixtures of sophorolipids produced by the yeast Candida bombicola have been analyzed by fast atom bombardment (FAB)-MS and collision-induced dissociation (CID)-MS. Some pure components have been analysed by two-dimensional NMR spectroscopy. The presence of acidic, lactonic, and O-acetylated forms and the position of double bonds in the fatty acid part of these glycolipids can be easily inferred from positive and negative ion FAB-mass spectra. Details about position of O-acetylation can be obtained from CID mass spectra of [M+H]+ and [M-H]- ions and from the NMR spectra. Differences in CID fragmentation between protonated and sodiated molecular ions are discussed in detail. Enzymatic hydrolysis of 6',6"-di-O-acetyl sophorolipid lactone by cutinase from Fusarium solani results specifically in the removal of the 6'-O-acetyl group, whereas the 6"-O-acetyl and lactone group are resistant. This specificity is explained from a three-dimensional model of the sophorolipid generated on the basis of the short 1H,1H distances as inferred from the NMR (ROESY) spectra.     

一种新型含硅拒水剂的合成与应用

以甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)、γ-甲基丙烯酰氧丙基三(三甲基硅氧烷)硅烷(TRIS)等为主要原料,采用半连续乳液聚合法,合成了具有核壳结构乳胶粒子的阳离子型含硅拒水剂。通过纳米粒度-Zeta电位分析仪、接触角(CA)、红外光谱(FT-IR)、透射电镜(TEM)及热重分析(TG)等手段研究了粒子的核壳形貌结构和固化后树脂的热稳定性等性能,然后考察了不同硅含量和不同浓度拒水剂对织物拒水性的影响。结果表明,有机硅单体参与了聚合,所合成乳胶粒具有明显的核壳结构,平均粒径为100nm。当硅含量最低为2%(占壳单体的质量分数)、有效浓度为2%,整理后的织物对水的接触角可达到135.5°。