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91.
Shuhua Zhang Muhammad Naeem Shah Feng Liu Zhongqiang Zhang Qin Hu Thomas P.Russell Minmin Shi Chang-Zhi Li Hongzheng Chen 《Nano Research》2017,(11):3765-3774
The ternary strategy for incorporating multiple photon-sensitive components into a single junction has emerged as an effective method for optimizing the nanoscale morphology and improving the device performance of organic solar cells (OSCs).In this study,efficient and stable ternary OSCs were achieved by introducing the small-molecule dye (5E,5'E)-5,5'-(4',4″-(1,2-diphenylethene-1,2-diyl)bis(biphenyl-4',4-diyl))bis(methan-1-yl-1-ylidene)bis(3-ethyl-2-thioxothia zolidin-4-one) (BTPERn) into poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b']dithiopheneco-3-fluorothieno[3,4-b]thiophene-2-carboxylate] (PTB7-Th):[6,6]-phenyl C71 butyric acid methyl ester (PC71BM) blend films processed using a 1,8-diiodooctane (DIO)-free solvent.The incorporation of BTPE-Rn enhanced the short-circuit current density and fill factor of the ternary OSCs compared with those of binary OSCs.An investigation of the optical,electronic,and morphological properties of the ternary blends indicated that the third component of BTPE-Rn not only promoted the photon utilization of blends through the energy-transfer process but also improved the electron mobility of the blends owing to the fullerene-rich nanophase optimization.More importantly,this ternary strategy of utilizing a small-molecule dye to replace the photounstable DIO additive enhanced the operational stability of the OSCs. 相似文献
92.
Berg Alexander Caroff Philippe Shahid Naeem Lockrey Mark N. Yuan Xiaoming Borgström Magnus T. Tan Hark Hoe Jagadish Chennupati 《Nano Research》2017,10(2):672-682
Ternary Ⅲ-Ⅴ nanowires (NWs) cover a wide range of wavelengths in the solar spectrum and would greatly benefit from being synthesized as position-controlled arrays for improved vertical yield,reprodudbility,and tunable optical absorption.Here,we report on successful selective-area epitaxy of metal-particle-free vertical InxGa1-xP NW arrays using metal-organic vapor phase epitaxy and detail their optical properties.A systematic growth study establishes the range of suitable growth parameters to obtain uniform NW growth over a large array.The optical properties of the NWs were characterized by room-temperature cathodoluminescence spectroscopy.Tunability of the emission wavelength from 870 nm to approximately 800 nm was achieved.Transmission electron microscopy and energy dispersive X-ray measurements performed on crosssection samples revealed a pure wurtzite crystal structure with very few stacking faults and a slight composition gradient along the NW growth axis. 相似文献
93.
Ball end magnetorheological finishing is a unique process that utilizes a magnetically controlled ball of polishing fluid at the tip of the rotating tool to finish workpiece of different materials and shapes. The aim of this research is to study the effect of polishing fluid volume on finishing spot size and the surface finish associated with it. A magnetostatic simulation is done to find the variation of flux density in the working gap and on the workpiece surface. The maximum limit of the polishing fluid volume is selected on the basis of area of threshold magnetic flux density (minimum value required for finishing) region on the workpiece surface. The surface characteristics and the diameter of the finished spot are analyzed by varying the fluid volume. The surface obtained with high fluid volume is poorly finished and has scratch marks as the excess fluid flows out from the working gap and forms a thick ring at the periphery of the tool tip. Contrary to this, if the fluid volume is too less, then it merely rotates over the workpiece surface without causing any finishing action. An optimum range of fluid volume produces a good quality surface finish with constant finished spot size. 相似文献
94.
Bilayer SiO2 Nanorod Arrays as Omnidirectional and Thermally Stable Antireflective Coating 下载免费PDF全文
Sadaf B. Khan Hui Wu Jianghao Li Limin Chen Zhengjun Zhang 《Advanced Engineering Materials》2018,20(5)
95.
Silver Nanoflower Decorated Graphene Oxide Sponges for Highly Sensitive Variable Stiffness Stress Sensors 下载免费PDF全文
Fakhre Alam Khan C. Muhammed Ajmal Seonghyun Bae Sungwon Seo Hyungpil Moon Seunghyun Baik 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(24)
Soft conductive materials should enable large deformation while keeping high electrical conductivity and elasticity. The graphene oxide (GO)‐based sponge is a potential candidate to endow large deformation. However, it typically exhibits low conductivity and elasticity. Here, the highly conductive and elastic sponge composed of GO, flower‐shaped silver nanoparticles (AgNFs), and polyimide (GO‐AgNF‐PI sponge) are demonstrated. The average pore size and porosity are 114 µm and 94.7%, respectively. Ag NFs have thin petals (8–20 nm) protruding out of the surface of a spherical bud (300–350 nm) significantly enhancing the specific surface area (2.83 m2 g?1). The electrical conductivity (0.306 S m?1 at 0% strain) of the GO‐AgNF‐PI sponge is increased by more than an order of magnitude with the addition of Ag NFs. A nearly perfect elasticity is obtained over a wide compressive strain range (0–90%). The strain‐dependent, nonlinear variation of Young's modulus of the sponge provides a unique opportunity as a variable stiffness stress sensor that operates over a wide stress range (0–10 kPa) with a high maximum sensitivity (0.572 kPa?1). It allows grasping of a soft rose and a hard bottle, with the minimal object deformation, when attached on the finger of a robot gripper. 相似文献
96.
Samra Rehman Muhammad Attique Khan Majed Alhaisoni Ammar Armghan Usman Tariq Fayadh Alenezi Ye Jin Kim Byoungchol Chang 《计算机、材料和连续体(英文)》2023,75(1):697-714
Identifying fruit disease manually is time-consuming, expert-required, and expensive; thus, a computer-based automated system is widely required. Fruit diseases affect not only the quality but also the quantity. As a result, it is possible to detect the disease early on and cure the fruits using computer-based techniques. However, computer-based methods face several challenges, including low contrast, a lack of dataset for training a model, and inappropriate feature extraction for final classification. In this paper, we proposed an automated framework for detecting apple fruit leaf diseases using CNN and a hybrid optimization algorithm. Data augmentation is performed initially to balance the selected apple dataset. After that, two pre-trained deep models are fine-tuning and trained using transfer learning. Then, a fusion technique is proposed named Parallel Correlation Threshold (PCT). The fused feature vector is optimized in the next step using a hybrid optimization algorithm. The selected features are finally classified using machine learning algorithms. Four different experiments have been carried out on the augmented Plant Village dataset and yielded the best accuracy of 99.8%. The accuracy of the proposed framework is also compared to that of several neural nets, and it outperforms them all. 相似文献
97.
Sohaib Manzoor Hira Manzoor Saddaf Rubab Muhammad Attique Khan Majed Alhaisoni Abdullah Alqahtani Ye Jin Kim Byoungchol Chang 《计算机、材料和连续体(英文)》2023,75(2):2347-2363
Despite the planned installation and operations of the traditional IEEE 802.11 networks, they still experience degraded performance due to the number of inefficiencies. One of the main reasons is the received signal strength indicator (RSSI) association problem, in which the user remains connected to the access point (AP) unless the RSSI becomes too weak. In this paper, we propose a multi-criterion association (WiMA) scheme based on software defined networking (SDN) in Wi-Fi networks. An association solution based on multi-criterion such as AP load, RSSI, and channel occupancy is proposed to satisfy the quality of service (QoS). SDN having an overall view of the network takes the association and reassociation decisions making the handoffs smooth in throughput performance. To implement WiMA extensive simulations runs are carried out on Mininet-NS3-Wi-Fi network simulator. The performance evaluation shows that the WiMA significantly reduces the average number of retransmissions by 5%–30% and enhances the throughput by 20%–50%, hence maintaining user fairness and accommodating more wireless devices and traffic load in the network, when compared to traditional client-driven (CD) approach and state of the art Wi-Balance approach. 相似文献
98.
Studies with purified subcellular organelles from rat liver indicate that nervonic acid (C24:1) is beta-oxidized preferentially in peroxisomes. Lack of effect by etomoxir, inhibitor of mitochondrial beta-oxidation, on beta-oxidation of lignoceric acid (C24:0), a peroxisomal function, and that of nervonic acid (24:1) compared to the inhibition of palmitic acid (16:0) oxidation, a mitochondrial function, supports the conclusion that nervonic acid is oxidized in peroxisomes. Moreover, the oxidation of nervonic and lignoceric acids was deficient in fibroblasts from patients with defects in peroxisomal beta-oxidation [Zellweger syndrome (ZS) and X-linked adrenoleukodystrophy (X-ALD)]. Similar to lignoceric acid, the activation and beta-oxidation of nervonic acid was deficient in peroxisomes isolated from X-ALD fibroblasts. Transfection of X-ALD fibroblasts with human cDNA encoding for ALDP (X-ALD gene product) restored the oxidation of both nervonic and lignoceric acids, demonstrating that the same molecular defect may be responsible for the abnormality in the oxidation of nervonic as well as lignoceric acid. Moreover, immunoprecipitation of activities for acyl-CoA ligase for both lignoceric acid and nervonic acid indicate that saturated and monoenoic very long chain (VLC) fatty acids may be activated by the same enzyme. These results clearly demonstrate that similar to saturated VLC fatty acids (e.g., lignoceric acid), VLC monounsaturated fatty acids (e.g., nervonic acid) are oxidized preferentially in peroxisomes and that this activity is impaired in X-ALD. In view of the fact that the oxidation of unsaturated VLC fatty acids is defective in X-ALD patients, the efficacy of dietary monoene therapy, "Lorenzo's oil," in X-ALD needs to be evaluated. 相似文献
99.
Transient liquid phase diffusion bonding and associated recrystallization phenomenon when joining ODS ferritic superalloys 总被引:1,自引:0,他引:1
Oxide dispersion strengthened (ODS) ferritic superalloys attribute their excellent intermediate and high temperature creep resistant properties to the distribution of an inert oxide, Y2O3 within highly directional and elongated grains. Careful selection of joining techniques is, therefore, of utmost importance so that the parent metal microstructure is not disrupted and is continuous across the bond line. Transient liquid phase (TLP) bonding is a suitable technique which has been used to join the ferritic superalloys MA957, MA956 and PM2000 using an amorphous foil based on an Fe-B-Si composition. To further minimize disruption to the parent alloy microstructure at the bond line, thin sputter coats based on the Fe-B-Si composition have also been used successfully for TLP bonding. Results have shown a boron-induced secondary recrystallized zone at the bond line in MA957 which acts as a barrier to further grain growth across the bond line on subsequent zone annealing. Differential scanning calorimetry shows that this recrystallization is triggered at 200 °C below the usual recrystallization temperature during heat treatment and occurs only when the metal filler melts and there is a free flux of boron into the base metal. Texture measurements show that the boron-induced recrystallization is of the same nature as the recrystallization produced by heat treatment but possesses a stronger directional 110 fibre texture. In contrast, grain growth across the bond line could be achieved in TLP bonds produced in MA956. However, a similar heat treatment for PM2000 produced simultaneous but independent secondary recrystallization both at the joint and in the bulk alloy. This difference in behaviour between these two similar alloys is attributed to differences in their thermomechanical processing. 相似文献
100.
We demonstrate a microfluidic continuous-flow protein separation process in which silica-coated superparamagnetic nanoparticles
interact preferentially with hemoglobin in a mixture with bovine serum albumin, and the resulting hemoglobin-nanoparticle
aggregates are recovered online using magnetophoresis. We present detailed modeling and analysis of this process yielding
quantitative estimates of the recovery of both proteins, validated by experiments. While several previous studies utilize
an average particle size in modeling magnetophoretic particle trajectories or process design, in this study we emphasize the
importance of accounting for particle size distributions in calculating particle recovery, and therefore in estimating separation
efficiency. We combine experimentally measured size distributions of protein-nanoparticle aggregates with simulations of particle
trajectories and provide a simple analytical method to calculate the efficiency of separation at various flow speeds, which
fully accounts for heterogeneity in particle sizes. Our method can potentially be used for affinity based biomolecular separations
at both analytical and preparative scales by exploiting well-established techniques to functionalize nanoparticle surfaces
with selective ligands. Further, the modeling methodology presented here may be applied to provide better estimates of particle
recovery in a broad range of magnetophoretic separation processes involving heterogeneity in particle sizes. 相似文献