Optimal Management of Solid Waste in Smart Cities using Internet of Things

Wireless Personal Communications - Smart cities are benefiting from Internet of Things (IoT) in optimizing their services. Smart waste management systems can provide substantial savings in time,...     

Visible-light-active silver- , vanadium-codoped TiO<Subscript>2</Subscript> with improved photocatalytic activity

Optimized doped TiO₂ is necessary for efficient visible light harvesting and widening the applications spectrum of TiO₂-based materials. Titanium dioxide doped with silver and/or vanadium has been synthesized by one-pot hydrothermal method without post-calcination. Codoping induced visible light absorption while maintaining the photoactive anatase phase along with good crystallinity. Synthesized products are in nanometer range and possess high specific surface area. Having nearly spherical morphology, the particles are distributed and the particle size estimated from TEM observation is in accordance with the XRD results. Spectroscopic investigations reveal that the doped atoms successfully entered the TiO₂ lattice modifying the band structure. The narrowed band gap allows visible light photons for absorption, and the codoped samples displayed enhanced visible light absorption among the synthesized samples. Photodegradation performance evaluated under visible light irradiations showed that silver- , vanadium-codoped TiO₂ have the best visible light photocatalytic activity attributed to stable configuration, high visible light absorption, coupling between silver and vanadium and their optimal doping concentration.     

A first 1,2,4-triazole Pb Complex: Thermal, spectroscopic and structural studies, [Pb2(trz)2(CH3COO)(NO2)]n

A 3D Pb^II coordination polymer containing 1,2,4-triazole (trz) and two different anions, [Pb₂(trz)₂(CH₃COO)(NO₂)]_n has been synthesized and characterized by elemental analysis, IR-, ¹H NMR-, ¹³C NMR spectroscopy and studied by thermal as well as X-ray crystallography. The single-crystal X-ray data shows two types of Pb²⁺-ions with coordination numbers of seven, Pb(1) and Pb(2) with hemidirected and holodirected geometries, respectively.     

Voltammetric determination of ascorbic acid and dopamine in the same sample at the surface of a carbon paste electrode modified with polypyrrole/ferrocyanide films

Functionalized polypyrrole film were prepared by incorporation of [Fe(CN)₆]⁴⁻ as a doping anion, during the electropolymerization of pyrrole onto a carbon paste electrode in an aqueous solution by potentiostatic method. The electrochemical behavior of dopamine (DA) and ascorbic acid (AA) in one solution was studied at the surface of bare and modified carbon paste electrodes using cyclic voltammetry (CV), linear sweep voltammetry (LSV) and differntial pulse voltammetry (DPV) methods. The well separated anodic peaks for oxidation of DA and AA were observed at the surface of the modified carbon paste electrode under optimum condition (pH 6.00), which can be used for determination of these species simultaneously in mixture by LSV and DPV methods. The linear analytical curves were obtained in the ranges of 0.10-1.00 mM and 0.10-0.95 mM for ascorbic acid and 0.10-1.20 mM and 0.20-0.95 mM for dopamine concentrations using LSV and DPV methods, respectively. The detection limits (2σ) were determined as 3.38 × 10⁻⁵ M and 1.34 × 10⁻⁵ M of ascorbic acid and 3.86 × 10⁻⁵ M and 1.51 × 10⁻⁵ M of dopamine by CV and DPV methods.     

Preparation of polypyrrole/ferrocyanide films modified carbon paste electrode and its application on the electrocatalytic determination of ascorbic acid

Functionalized polypyrrole film were prepared by incorporation of (Fe(CN)₆)⁴⁻ as doping anion, during the electropolymerization of pyrrole onto a carbon paste electrode (CPE) in aqueous solution by using potentiostatic method. The electrochemical behavior of the (Fe(CN)₆)³⁻/(Fe(CN)₆)⁴⁻ redox couple in polypyrrole was studied by cyclic voltammetry and double step potential chronoamperometry methods. In this study, an obvious surface redox reaction was observed and dependence of this reaction on the solution pH was illustrated. The electrocatalytic ability of polypyrrole/ferrocyanide films modified carbon paste electrode (Ppy/FCNMCPEs) was demonstrated by oxidation of ascorbic acid. It has been found that under optimum condition (pH 7.00), the oxidation of ascorbic acid at the surface of such electrode occurs at a potential about 540 mV less positive than unmodified carbon paste electrode. The kinetic parameters such as electron transfer coefficient, α and catalytic reaction rate constant, k_h′, were also determined by using various electrochemical approaches.The catalytic oxidation peak current showed a linear dependent on the ascorbic acid concentration and a linear calibration curve was obtained in the range of 4.5×10⁻⁴ to 9.62×10⁻³ M of ascorbic acid with a correlation coefficient of 0.9999. The detection limit (2σ) was determined as 5.82×10⁻⁵ M.     

A secure migration process for mobile agents

This article describes a decentralized secure migration process of mobile agents between Mobile‐C agencies. Mobile‐C is an IEEE Foundation for Intelligent Physical Agents (FIPA) standard compliant multi‐agent platform for supporting C/C++ mobile and stationary agents. Mobile‐C is specially designed for mechatronic and factory automation systems where malicious agents may cause physical damage to machinery and personnel. As a mobile agent migrates from one agency to another in an open network, the security concern of mobile agent systems should not be neglected. Security breaches can be minimized considerably if an agency only accepts mobile agents from agencies known and trusted by the system administrator. In Mobile‐C, a strong authentication process is used by sender and receiver agencies to authenticate each other before agent migration. The security framework also aims to guarantee the integrity and confidentiality of the mobile agent while it is in transit. This assures that all agents within an agency framework were introduced to that framework under the supervision and permission of a trusted administrator. The Mobile‐C Security protocol is inspired from the Secure Shell (SSH) protocol, which avoids a single point of failure since it does not rely on a singular remote third party for the security process. In this protocol, both agencies must authenticate each other using public key authentication, before a secure migration process. After successful authentication, an encrypted mobile agent is transferred and its integrity is verified by the receiver agency. This article describes the Mobile‐C secure migration process and presents a comparison study with the SSH protocol. The performance analysis of the secure migration process is performed by comparing the turnaround time of mobile agent with and without security options in a homogeneous environment. Copyright © 2010 John Wiley & Sons, Ltd.     

Synchronization of general chaotic systems using neural controllers with application to secure communication

The main contribution of this paper is to propose a nonlinear robust controller to synchronize general chaotic systems, such that the controller does not need the information of the chaotic system’s model. Following this purpose, in this paper, two methods are proposed to synchronize general forms of chaotic systems with application in secure communication. The first method uses radial basis function neural network (RBFNN) as a controller. All the parameters of the RBFNN are derived and optimized via particle swarm optimization (PSO) algorithm and genetic algorithm (GA). In order to increase the robustness of the controller, in the second method, an integral term is added to the RBF neural network gives an integral RBFNN (IRBFNN). The coefficients of the integral term and the parameters of IRBFNN are also derived and optimized via PSO and GA. The proposed methods are applied to the famous Lorenz chaotic system for secure communication. The performance and control effort of the proposed methods are compared with the recently proposed PID controller optimized via GA. Simulation results show the superiority of the proposed methods in comparison to the recent one in improving synchronization while using smaller control effort.