The present paper reports an anomalous microstructure formed at interfaces between Cu ribbons and Sn-deposited Cu plates by ultrasonic bonding. The interface consists of Cu-to-Cu directly bonded part and Sn-dispersed part. In the latter part, Sn is dispersed in the vicinity of the bond interfaces being retained as Sn. The formation process of the interfacial microstructure is discussed on the basis of detailed experimental analysis and theoretical analysis on the solid-state reaction at Cu/Sn interface. The theoretical analysis reveals three important points of the reaction. (1) The formation of Cu6Sn5 precedes that of Cu3Sn. (2) The incubation time for the formation of Cu6Sn5 changes discontinuously at the η/η′ transition temperature. (3) The incubation time for the formation of η′Cu6Sn5 is longer than that for ηCu6Sn5. 相似文献
A cationic iridium‐catalyzed C‐7 alkylation of N‐substituted indoline derivatives with various alkenes has been developed. A variety of 7‐alkylindolines were obtained in moderate to high yields. This protocol relies on the use of the carbonyl group on the nitrogen atom of indoline as a directing group and it is potentially applicable to the large‐scale synthesis of 7‐alkylindoles.
Reactor pressure vessels comprise bainitic steel structures, and are heterogeneous on the mesoscale. Nanoindentation techniques were used to evaluate the hardness of these structures on the micrometer scale, and to evaluate the heterogeneity in a specimen using the distribution of the hardness. Three A533B model alloys were irradiated by 2.8 MeV Fe2+ ions at 563 K, and the effects of ion fluence, ion flux, and chemical composition on the change in the hardness distribution were examined. Heterogeneity of the hardening is observed in high-copper specimens irradiated up to (2–10) × 1014 ions/cm2, where the average hardness increases the most. In these specimens, the hardness distribution broadens, and demonstrates that the hardening in certain positions (possibly where the initial hardness is high) is greater than in other positions. Variation in initial chemical composition (especially copper and carbon) or sink strength may cause a difference in the curing behavior. 相似文献
Cell wall material was isolated from the residue obtained after the extraction of sweet potato starch by treatment with the α-amylase. The wall material was fractionated by successive extraction with various reagents. The pectic substance was mainly composed of uronic acid (47.1%) residues and contained galactose as the predominant neutral sugar residues. The hemicellulosic fraction was further fractionated by precipitation with iodine in the presence of calcium chloride to give two fractions, a iodine precipitatable-iodine complex (HC-IP) and a supernatant solution (HC-IS). The HC-IS fraction had a higher glucose content (53.4%), whereas the HC-IP fraction had a high content of xylose residues (35.1%). The HC-IP fraction consisted mainly of xylan, as judged by the degradation with purified xylanase. 相似文献
The realization of high-energy-density all-solid-state Li-ion batteries requires materials exhibiting both high Li-ion conductivity and high deformability, as exemplified by Li3MCl6-type chlorides. Herein, we optimized the classical force-field (FF) parameters for 36 Li- and Cl-containing compounds to reproduce the results of high-precision first-principles calculations and performed rapid FF molecular dynamics (MD) calculations to determine their Li-ion conductivities. In addition, shear moduli were evaluated by first-principles calculations and used as a deformability index. Li4Mn3Cl10 was selected based on its Li-ion conductivity, stiffness, and thermodynamic stability. In accordance with the low calculated shear modulus (11.7 GPa), the cold-pressed compact had a high relative density of 98%, which indicated good deformability. The room-temperature conductivity (3.9 mS cm−1) was similar to that (1.6 mS cm−1) obtained by high-precision first-principles MD calculations. The Li-ion conductivity of synthesized Li4Mn3Cl10 (18 µS cm−1) was relatively rather high compared to those of known chloride materials but much lower than the calculated value, which was ascribed to the fact that calculations were performed for the high-temperature phase, whereas synthesis yielded the low-temperature phase. The material screening method greatly increases the speed of material exploration and expands the application possibilities of chloride materials for all-solid-state batteries. 相似文献
Three types of glass/nylon 6 intermediate material forms-film stacking, uncommingled yarn, and commingled yarm-were selected study the correlations between the impregnating property and mechanical properties. The size of the glass fiber block to be filled with matrix and the porosity in glass fiber bundles by spearing out the fiber bundle was different in these materials. Unidirectional glass fiber reinforced thermoplastic composites were fabricated by compression molding. The being test was performed by using the three-point loading system, and the fracture behavior and the degree of impregnation were observed to examine the influence of processing conditions on the bending properties, relative to the form of the intermediate material. Bending strength increased, in accordance with the impregnating property, least in the film stacking form, second most in uncommingled yarn, and most in commingled yarn. The impregnating property was affected by the size of fiber blocks and the porosity in fiber bundles, because bending strength was improved by spreading out the fiber bundles. Commingled yarn is an excellent intermediate materials, which has both the fineness of matrix/fiber mixing and large porosity in fiber bundles. 相似文献
Artificial Life and Robotics - A variety of planning research is being actively conducted in multiple research fields. The focus of these studies is to flexibly utilize both immediate and... 相似文献