Biogenic synthesis and thermo‐magnetic study of highly porous carbon nanotubes

Nanomaterials synthesis using natural sources is the technology to up come with advanced materials through extracts of plant, microorganisms, poultry waste etc. In this study, the authors report the synthesis of porous carbon nanotubes using high‐temperature decomposition technique facilitated by cobalt salt using chicken fats, a poultry waste as a precursor. Since chicken fats contain fatty acids which can decompose into short hydrocarbon chains and cobalt can act as the catalyst. The formation of carbon nanotubes was confirmed by Raman spectra, peaks at 1580 and 1350.46 cm⁻¹ confirmed the graphite mode G‐band and structural imperfections defect mode D‐band, respectively. Transmission electron microscopy showed the formation of tube‐like structures. Nitrogen adsorption–desorption studies showed the high‐surface area of 418.1 m² g⁻¹ with an estimated pore diameter of 8.1 nm. Thermogravimetry analysis–derivative thermogravimetric analysis–differential thermal analysis showed the instant weight loss at 517°C attributed to the rapid combustion of nanotubes. A vibrating‐sample magnetometer showed the paramagnetic nature of the so‐formed carbon nanotubes formed.Inspec keywords: transmission electron microscopy, infrared spectra, nanomagnetics, pyrolysis, decomposition, adsorption, desorption, carbon nanotubes, differential thermal analysis, thermal analysis, nanofabrication, Raman spectra, X‐ray diffraction, scanning electron microscopy, paramagnetic materialsOther keywords: biogenic synthesis, highly porous carbon nanotubes, microorganisms, high‐temperature decomposition technique, cobalt salt, chicken fats, fatty acids, short hydrocarbon chains, Raman spectra, graphite mode G‐band, structural imperfections defect mode D‐band, transmission electron microscopy, paramagnetic nature, thermo‐magnetic properties, poultry waste, nitrogen adsorption‐desorption studies, thermogravimetry analysis, differential thermal analysis, carbon nanotubes, temperature 517.0 degC, C     

Physicochemical,thermal and pasting properties of starch separated from γ-irradiated and stored potatoes

The morphological, thermal and pasting properties of starch separated from potatoes of three varieties (Kufri Chandramukhi, Kufri Jyoti and Kufri Chipsona-2), treated either with CIPC (isopropyl N-(3 chlorophenyl) carbamate) or γ-irradiation (Co⁶⁰, 0.1 and 0.5 kGy) and subsequently stored at 8, 12 and 16 °C for 90 days, were studied. Scanning electron microscopy (SEM) showed the presence of oval and irregular shaped starch granules with a diameter range of 15–16 μm. Mean granule size of starch separated from potatoes stored at 12 °C ranged from 18–25 μm and irradiation treatment resulted in an increase in the proportion of small size granules. The irradiation of potatoes with 0.5 kGy resulted in starch with significantly lower peak-, trough- and breakdown-viscosity as compared to starch from potatoes treated with either CIPC or 0.1 kGy irradiation. The irradiation of potatoes with 0.5 kGy caused a significant increase in setback and pasting temperature. Pasting temperature of starch was observed to vary with the storage temperature. Starch separated from potatoes stored at higher temperature showed lower pasting temperature and vice versa. The starch from potatoes stored at 8 °C showed higher peak-, trough- and breakdown-viscosity and lower setback. Peak viscosity increased and swelling volume decreased with increase in storage temperature. FTIR spectra showed that the starch from irradiated potatoes displayed a significant decrease in the intensity of the C–H stretch region between 2800 and 3000 cm⁻¹, which was observed to be irradiation dose-dependent, and higher with 0.5 than 0.1 kGy. However, a slight broadening of O–H stretch (3000–3600 cm⁻¹) in starches from irradiated potatoes was observed. The spectral changes caused by γ-irradiation were apparent in the O–H stretch (3000–3600 cm⁻¹), C–H stretch (2800–3000 cm⁻¹) and bending mode of water (1600–1800 cm⁻¹).     

Evaluation of specimen preparation techniques for micro-PIXE localisation of elements in hyperaccumulating plants

Hybanthus floribundus subsp. floribundus, a rare Australian Ni-hyperaccumulating shrub and Pityrogramma calomelanos var. austroamericana, an Australian naturalized As-hyperaccumulating fern are promising species for use in phytoremediation of contaminated sites. Micro-proton-induced X-ray emission (μ-PIXE) spectroscopy was used to map the elemental distribution of the accumulated metal(loid)s, Ca and K in leaf or pinnule tissues of the two plant species. Samples were prepared by two contrasting specimen preparation techniques: freeze-substitution in tetrahydrofuran (THF) and freeze-drying. The specimens were analysed to compare the suitability of each technique in preserving (i) the spatial elemental distribution and (ii) the tissue structure of the specimens. Further, the μ-PIXE results were compared with concentration of elements in the bulk tissue obtained by ICP-AES analysis.In H. floribundus subsp. floribundus, μ-PIXE analysis revealed Ni, Ca and K concentrations in freeze-dried leaf tissues were at par with bulk tissue concentrations. Elemental distribution maps illustrated that Ni was preferentially localised in the adaxial epidermal tissues (1% DW) and least concentration was found in spongy mesophyll tissues (0.53% DW). Conversely, elemental distribution maps of THF freeze-substituted tissues indicated significantly lower Ni, Ca and K concentrations than freeze-dried specimens and bulk tissue concentrations. Moreover, Ni concentrations were uniform across the whole specimen and no localisation was observed.In P. calomelanos var. austroamericana freeze-dried pinnule tissues, μ-PIXE revealed statistically similar As, Ca and K concentrations as compared to bulk tissue concentrations. Elemental distribution maps showed that As localisation was relatively uniform across the whole specimen. Once again, THF freeze-substituted tissues revealed a significant loss of As compared to freeze-dried specimens and the concentrations obtained by bulk tissue analysis.The results demonstrate that freeze-drying is a suitable sample preparation technique to study elemental distribution of ions in H. floribundus and P. calomelanos plant tissues using μ-PIXE spectroscopy. Furthermore, cellular structure was preserved in samples prepared using this technique.     

Effect of manganese and cobalt doping on conductivity of ZnO based varistors: a study by complex plane modulus

Effect of manganese and cobalt doping (0.50 mole%) on electrical properties of ZnO based varistors has been studied using complex plane modulus analysis. It is found that total resistivity of Mn doped sample is more as compared to that of Co doped sample. This has been ascribed to existence of Mn in variable valence states viz. Mn²⁺, Mn³⁺ and Mn⁴⁺ which promotes hopping conduction leading to increase in the conductivity as compared to Co doped sample, in which Co exists predominantly in +3 state with traces of Co²⁺ or Co⁺⁴ states. This accounts for its less conductivity. Mechanism of conduction is the same for grains and grainboundaries.     

Well Loss Estimation: Variable Pumping Replacing Step Drawdown Test

An optimization method is presented for simultaneous estimation of aquifer parameters and well loss parameters utilizing all the drawdowns observed during a variable rate pumping or multiple step pumping test. The proposed method does not require any graphical analysis. It is shown that a variable rate pumping test is a better substitute for the conventional step drawdown test to estimate well loss parameters. It suggests that the pumping rate may be changed frequently without waiting for a near steady state to be reached (or a selected duration, say 60 min) in each step of a conventional step drawdown test. This can result in a substantial saving of time and money involved in conducting a step drawdown test with a view to estimate well loss parameters. This gives a greater number of distinct discharges, which improves the estimates of the well loss parameters. Application of the method is demonstrated on published data sets, the results of which show that the parameters estimated using the new method are more reliable as compared to those obtained using prior methods.     

Theory of optical nutation in direct-gap semiconductors due toultrashort resonant laser irradiation

An analytical investigation of optical nutation in direct-gap semiconductors such as GaAs, InSb, and Hg_1-xCd_xTe based on the time-dependent perturbation technique is discussed. The crystals are considered to be irradiated by short pulsed moderate power near-resonant lasers producing significant density of optically-induced free electron-hole pairs. Incoherent dephasing mechanisms have been introduced phenomenologically into the coherent radiation-semiconductor interaction model. The theory, on application to the case of a specific crystal such as Hg_1-xCd_xTe with x=0.18 irradiated by a pulsed 10.6 μm CO₂ laser, manifests distinctly the occurrence of ringing behavior in the transmitted intensity, transient dispersion, and absorption even in the absence of any theoretical averaging or the consideration of the effective density of states     

Temperature behavior and compensation of light-emitting diode

This letter offers a fresh insight into the behavior of light-emitting diode (LED) over temperature. Theoretically and by measurement, it has been shown that equi-intensity curves in the diodes current-voltage plane are nearly a straight line over a very wide range of temperatures. Based on this property, bias voltage and resistance value of a bias circuit have been realized and practical measurement shows the peak-to-peak light intensity variation decreases from 99 % (in case of fixed current bias) to 6 % over the temperature range of -20 C to +80 C for the LED IN6092. This circuit uses no separate temperature sensor or compensating mechanism, but responds directly to the junction temperature of the diodes. This prevents any error caused by temperature gradient, or by self-heating due to power dissipation in the diode.