Deformation of Rodlike Elements of Composite Materials Subjected to Uniform Compression

On the basis of generalization of the results of investigation of the operation of rodlike elements of composite materials, we make a conclusion that the influence of various factors on the deformability of these elements is studied incompletely. The comparison of the stress-strain states for different models of concrete and reinforced-concrete elements makes it possible to describe the effect of longitudinal reinforcement (coefficient of reinforcement, strength and deformation characteristics) on the critical level of strains in the cross section. According to the results of our investigations, we give recommendations concerning the evaluation of the critical value of the coefficient of reinforcement above which one may observe the effect of reinforcement on the deformability of the analyzed sections. It is shown that the compression strength of the brittle base of the composite with inhomogeneous structure decreases as a result of the fracture processes. It is also demonstrated that the existing procedure used for the evaluation of the indicated decrease in strength requires significant improvement. The problem of evaluation of the ultimate value of the coefficient of reinforcement is also analyzed.     

Synthesis, Characterization, and Formation Process of Na-X Zeolite from Coal Fly Ash

Using the SiO₂ and Al₂O₃ components of the amorphous phase in coal fly ash (Fa), Fa was converted to Na-X zeolites in NaOH-NaAlO₂ solutions by stirring at 35°C for 72 hr and then aging at 85°C for a given period. The molar ratio SiO₂/Al₂O₃ of the starting materials was controlled from 2.0 to 13.2. The resulting materials were characterized by various means. Increasing the SiO₂/Al₂O₃ ratio of the starting material increased the degree of crystallinity of faujasite, exhibiting a maximum at SiO₂/Al₂O₃ = 8.0. The faujasite formed was identified as Na-X zeolite with Si/Al = 1.20. The amorphous phase in Fa was dissolved during the stirring to form a precursor of zeolite, such as amorphous aluminosilicate. The Na-X zeolite was formed by aging for 24 hr, and the degree of crystallinity of this material was increased with the increasing aging period. The cation exchange capacity and specific surface area were increased with the increasing degree of crystallinity of the Na-X zeolites.     

Comparison of Solutions of the Problems of Elasticity Theory for Different Near-Boundary Elements

We consider three types of near-boundary elements: curvilinear quadrangles and families of arcs and points, and their application to a two-dimensional problem of the static theory of elasticity with boundary conditions in displacements. The comparison of the theoretical and numerical aspects of the obtained solutions is performed. It is shown that the accuracy of evaluation of the components of the vector of displacements increases in the following cases: in the case of complete quantization of the near-boundary region (but not in the case of its partial quantization or quantization with overlapping), in the case where the numbers of arcs and points increase, and in the case of simultaneous application of different types of near-boundary elements (specifically, quadrangles and families of arcs).     

Synthesis and Structure of Complexes of Np(V) Perchlorate and Np(V) Chloride with Urea

The crystal structure of [NpO₂{OC(NH₂)₂}₅]ClO₄·H₂O and [NpO₂Cl{OC(NH₂)₂}₄] was studied by X-ray diffraction. The electronic absorption spectra of these complexes were recorded. The coordination polyhedron of Np in both complexes is a distorted pentagonal bipyramid. There is no cation-cation interaction of neptunyl cations in these complexes.     

Microscopic and Macroscopic Growth Rates of Fatigue Cracks in Steels and Alloys under the Influence of Crack Closure

On the basis of the experimental data, we show that the difference between the macroscopic and microscopic fatigue crack growth rates in the second section of the kinetic diagram of fatigue fracture is caused by the effect of crack closure within the limits of its existence. We establish the relationships between the macroscopic and microscopic fatigue crack growth rates and the structure of the material in the second section of the diagram for various values of the load ratio with regard for the effect of crack closure and propose a procedure of examination of the fracture processes in structural materials based on the analysis of microscopic and macroscopic fatigue crack growth rates.     

Volatile Compounds of Raw Beef from 5 Local Spanish Cattle Breeds Stored Under Modified Atmosphere

Volatile compounds of raw beef from Asturiana de los Valles, Morucha, Parda Alpina, Pirenaica, and Retinta cattle breeds were studied. Steaks were packaged under 60% O₂, 30% CO₂, and 10% N₂, and 53 volatile compounds were tentatively identified by purge‐and‐trap extraction and gas chromatography with mass spectrometry after 0, 5, 10, and 15 d of chill storage. The degradation of beef quality with increasing storage time was evidenced by the increase in 2,3,3‐trimethylpentane, 2,2,5‐trimethylhexane, 3‐octene, 3‐methyl‐2‐heptene, 2‐octene, and 2‐propanone and by the decrease in dimethyl sulfide. Consequently, some of the volatile compounds, which are believed to be formed by thermal degradation of meat, might be formed during chill storage, and the rate of formation of some was dependent on the specific compound.     

Stability analysis of continuous-time periodic systems via theharmonic analysis

Asymptotic stability of finite-dimensional linear continuous-time periodic (FDLCP) systems is studied by harmonic analysis. It is first shown that stability can be examined with what we call the harmonic Lyapunov equation. Another necessary and sufficient stability criterion is developed via this generalized Lyapunov equation, which reduces the stability test into that of an approximate FDLCP model whose transition matrix can be determined explicitly. By extending the Gerschgorin theorem to linear operators on the linear space l₂, yet another disc-group criterion is derived, which is only sufficient. Stability of the lossy Mathieu equation is analyzed as a numerical example to illustrate the results     

Equal-channel angular extrusion of beryllium

The equal-channel angular extrusion (ECAE) technique has been applied to a powder metallurgy (P/M) source Be alloy. Extrusions have been successfully completed on Ni-canned billets of Be at approximately 425°C. No cracking was observed in the billets, and significant grain refinement was achieved. In this article, microstructural features and dislocation structures are discussed for a singlepass extrusion, including evidence of <c> and <c+a> dislocations. Significant crystallographic texture developed during ECAE, which is discussed in terms of this unique deformation processing technique and the underlying physical processes which sustain the deformation. S.R. AGNEW, formerly with the Oak Ridge National Laboratory, Oak Ridge, TN 37831-6115 This article is based on a presentation made in the symposium entitled “Defect Properties and Mechanical Behavior of HCP Metals and Alloys” at the TMS Annual Meeting, February 11–15, 2001, in New Orleans, Louisiana, under the auspices of the following ASM committees: Materials Science Critical Technology Sector, Structural Materials Division, Electronic, Magnetic & Photonic Materials Division, Chemistry & Physics of Materials Committee, Joint Nuclear Materials Committee, and Titanium Committee.     

Terahertz/optical mixing in symmetric semiconductor quantum wells embedded in optical microcavities

A quantum well (QW) in the simultaneous presence of a terahertz field polarized in the growth direction and an incident optical field near an excitonic resonance results in substantial frequency mixing between the terahertz and optical fields. In particular, a response at new frequencies given by the input optical frequency plus or minus multiples of the terahertz frequency occurs-the terahertz sidebands. In a symmetric QW, the dominant contribution to terahertz-sideband formation is the high-frequency modulation of the overlap integral of the relevant conduction- and valence-subband envelope functions that determine the strength of the interband dipole moment. terahertz-sideband generation is shown to be strongly enhanced in a high quality-factor optical microcavity. Numerical values of the reflected intensity into the first terahertz sideband normalized with respect to the reflected intensity at the fundamental as large as /spl sim/10% are estimated. This suggests that terahertz-sideband generation in semiconductor microcavities is a promising option worthy of exploration for wavelength conversion for wavelength-division multiplexing applications.