High temperature rate coefficient for the reaction of O(P) with H2 obtained by the resonance absorption of O and H atoms

The reaction of O(³P) with H₂ has been studied behind reflected shock waves in the temperature range of 1713–3532K at total pressures of about 1.4–2.0 bar by Atomic Resonance Absorption Spectroscopy using mixtures of N₂O and H₂ highly diluted in Ar. The O atoms were generated by the fast thermal decomposition of N₂O and the reaction with H₂ was followed by monitoring the time dependent O and H atom concentrations in the postshock reaction zone. For the experimental conditions chosen, the measured O and H atom concentrations were primarily sensitive to the well-known N₂O dissociation and to the studied reaction and hence its rate coefficient could be deduced. The measured rate coefficient data are fitted by the least-squares method to obtain the following three parameter expression: K₄=3.72×10⁶(T/K)^2.17exp(−4080K/T)cm³ mol⁻¹8⁻, which is in excellent agreement with the recent ab initio calculations for the rate coefficient of this reaction in the overlapping temperature range. The present result is also compared to the experimental results reported by earlier investigators.     

A study on defect controlled morphology of Organic/Inorganic composite nanofibers with different heat flow rates

One dimensional nanofibers of organic and inorganic materials have been used in filters, optoelectronic devices, sensors etc. It is difficult to obtain ultra fine fibers of inorganic materials having lengths in the order of millimeter as they tend to break during formation due to thermal and other mechanical stresses. In this study, we have investigated the mechanism to prevent the defect formation and the breaking ZnO nanofibers by using optimized heat flow rates. ZnO nanofibers were obtained by heat treating the PVA composites fibers formed by electrospinning. The morphology and structural characteristic of prepared samples were investigated by Scanning electron microscopy and X-ray diffraction. It was found that the morphology of the composite and annealed nanofibers could be influenced by the concentration of the polymer content and heat flow rate during thermal treatment respectively. A lower concentration favors the formation of defects along the fiber and the number of defects reduces when the concentration is increased. The reasons for the formation of defects and their reduction, and the observed structural changes of ZnO nanofibers during heat treatment are also discussed.     

Flexible polymer microtubes and microchannels via electrospinning

Here we report an approach to fabricate flexible polymer self standing films embedded with continuous aligned microtubes/microchannels via electrospinning. The scheme is to wash the electrospun fibers selectively to form either microtubes/microchannels. Optical microscope (OM) and Scanning electron microscope images are evident for the well aligned microtubes and microchannels respectively with a diameter of ~ 8 μm and a length of ~ 4 cm. Meniscus of tetrahydrofuran in the microtubes can be observed explicitly in the OM images. Mutually perpendicular microtubes are also fabricated on a polymer film. Angular distribution of aligned microstructures indicates the standard deviation is not more than 1°. These tubes/channels can be potential for tissue engineering as they could provide a directional template for the growth when a biodegradable polymer such as Poly(vinylalcohol) is used.     

Vibrational excitations in molecular layers probed by ballistic electron microscopy

We demonstrate the information on molecular vibrational modes via the second derivative (d(2)I(B)/dV(2)) of the ballistic electron emission spectroscopy (BEES) current. The proposed method does not create huge fields as in the case of conventional derivative spectroscopy and maintains a zero bias across the device. BEES studies carried out on three different types of large polycyclic aromatic hydrocarbon (PAH) molecular layers show that the d(2)I(B)/dV(2) spectra consist of uniformly spaced peaks corresponding to vibronic excitations. The peak spacing is found to be identical for molecules within the same PAH family though the BEES onset voltage varies for different molecules. In addition, injection into a particular orbital appears to correspond to a specific vibrational mode as the manifestation of the symmetry principle.     

Experimental investigation of forced convection and desiccant integrated solar dryer

An indirect forced convection and desiccant integrated solar dryer is designed and fabricated to investigate its performance under the hot and humid climatic conditions of Chennai, India. The system consists of a flat plate solar air collector, drying chamber and a desiccant unit. The desiccant unit is designed to hold 75 kg of CaCl₂-based solid desiccant consisting of 60% bentonite, 10% calcium chloride, 20% vermiculite and 10% cement. Drying experiments have been performed for green peas at different air flow rate. The equilibrium moisture content M_e is reached in 14 h at an air flow rate of 0.03 kg/m² s. The system pickup efficiency, specific moisture extraction rate, dimensionless mass loss, mass shrinkage ratio and drying rate are discussed in this paper.     

Wideband reflecting frequency-selective surface polarizer for X-band applications

This paper proposed the design of a broadband linear-to-circular reflecting polarizer for X-band applications. The polarizer is designed with three-arm dipole-shaped unit cells with a full ground plane to get wideband performance. The incident linear polarized wave is converted to a right-handed circularly polarized wave upon reflection from the polarizer. The footprint of the unit cell is 9 × 9 mm, which is printed on a FR-4 substrate. Fabricated prototype is measured for its performances like polarization conversion ratio (PCR), fractional bandwidth, and aperture efficiency. The PCR is about 97%, and the fractional bandwidth is 64% with the aperture efficiency of more than 80%. Polarizer performance is analyzed in transverse electric and transverse magnetic modes, and they are stable up to 40° of various incident angles. The polarizer exhibits the 3-dB axial ratio bandwidth from 8 to 12 GHz, which is suitable for satellite applications.     

Robust named entity detection from optical character recognition output

In this paper, we focus on information extraction from optical character recognition (OCR) output. Since the content from OCR inherently has many errors, we present robust algorithms for information extraction from OCR lattices instead of merely looking them up in the top-choice (1-best) OCR output. Specifically, we address the challenge of named entity detection in noisy OCR output and show that searching for named entities in the recognition lattice significantly improves detection accuracy over 1-best search. While lattice-based named entity (NE) detection improves NE recall from OCR output, there are two problems with this approach: (1) the number of false alarms can be prohibitive for certain applications and (2) lattice-based search is computationally more expensive than 1-best NE lookup. To mitigate the above challenges, we present techniques for reducing false alarms using confidence measures and for reducing the amount of computation involved in performing the NE search. Furthermore, to demonstrate that our techniques are applicable across multiple domains and languages, we experiment with optical character recognition systems for videotext in English and scanned handwritten text in Arabic.     

Seismic response of multi-storey buildings including foundation interaction and P-Δ effects

This paper presents a method of seismic analysis of multi-storey buildings when both soil-structure interaction and P-Δ effects have been taken into account. The additional overturning moment at each storey due to P-Δ effects is replaced by two fictitious horizontal forces acting in opposite directions at the upper and lower ends of each storey. Then, the governing equation for each floor is developed in which these fictitious horizontal forces are incorporated along with seismic inertia forces. Considering the footing as a rigid disc resting on the surface of an elastic half-space, two equations expressing the equilibrium of the building as a whole in translation and rotation complete the set of equations in terms of floor displacements and two rigid body base displacements. Recognizing that the superstructure alone admits classical normal modes, floor governing equations are uncoupled and substituted into the remaining equations, which results in two coupled integro-differential equations in terms of two rigid body displacements. These two equations can be solved using numerical procedures. The method is applied to two unbraced steel buildings and numerical results are presented for different foundation soil conditions. The influence due to P-Δ effects and soil-structure interactions on the responses of these buildings is discussed.