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61.
David Eskenazi Patrick Kreit Jean‐Paul Pirard Nathalie Job Philippe Compère 《American Institute of Chemical Engineers》2018,64(3):1049-1058
A continuous process for producing porous carbon xerogel beads has been developed. It consists in injecting a pre‐cured aqueous solution of resorcinol and formaldehyde on top of a column filled with hot oleic acid. The latter is pumped on the top of the column and fed at the bottom, generating an upward flow that can be adjusted to match the terminal velocity of the settling beads. Thus, the bead residence time in the column can be adjusted to match the gelation time, allowing the beads to solidify before reaching the bottom of the vessel. The obtained beads are subsequently dried and pyrolyzed. The developed experimental setup proved the continuous synthesis of porous carbon beads is possible. Nevertheless, the shaping process caused various texture changes of the porous carbon, which mainly yields macropores instead of micro and mesopores. This process also leads to the build‐up of a denser skin around the beads. © 2018 American Institute of Chemical Engineers AIChE J, 64: 1049–1058, 2018 相似文献
62.
Dr. Morgan Le Naour Dr. Veronique Leclerc Dr. Amaury Farce Dr. Daniel‐Henri Caignard Dr. Nathalie Hennuyer Prof. Bart Staels Dr. Valérie Audinot‐Bouchez Dr. Jean‐Albert Boutin Dr. Michel Lonchampt Dr. Catherine Dacquet Prof. Alain Ktorza Prof. Pascal Berthelot Dr. Nicolas Lebegue 《ChemMedChem》2012,7(12):2179-2193
Compounds that simultaneously activate peroxisome proliferator‐activated receptor (PPAR) subtypes α and γ have the potential to effectively treat dyslipidemia and type 2 diabetes (T2D) in a single pharmaceutically active molecule. The frequently observed side effects of selective PPARγ agonists, such as edema and weight gain, were expected to be overcome by using additive PPARα activity, leading to dual PPARα/γ agonists with balanced activity for both subtypes. Herein we report the discovery, synthesis, and optimization of a new series of α‐ethoxyphenylpropionic acid bearing 5‐ or 6‐substituted indoles. The incorporation of oxime ethers on the carbonyl portion of the benzoyl group can bring the PPARα/γ potency ratio equal to or slightly greater than one, as is the case for compounds 20 c and 21 a . Compound 20 c shows high efficacy in an ob/ob mouse model of T2D and dyslipidemia, similar to that of rosiglitazone and tesaglitazar, but with a significant increase in body weight gain. In contrast, compound 21 a , less potent as a dual PPARα/γ activator than 20 c , showed an interesting pharmacological profile, as it elicits a decrease in body weight relative to reference compounds. 相似文献
63.
Abir Abdelkefi Pierrick Malécot Nathalie Boudeau Noamen Guermazi Nader Haddar 《The International Journal of Advanced Manufacturing Technology》2017,93(5-8):1725-1735
It is generally known that the contact between tube and die, in the case of tube hydroforming process, leads to the appearance of friction effects. In this context, there are many different models for representing friction and many different tests to evaluate it. In the present paper, the pin-on-disk test has been used and the theoretical model of Orban-2007 has been chosen and developed to evaluate friction coefficient. The main goal is to prove the capacity of theoretical model to present the friction conditions in comparison with the pin-on-disk test. From the Orban model, values of 0.05 and 0.25 of friction coefficient have been found under lubricated and dry tests, respectively. On the other hand, by the classical pin-on-disk test, other values were experimentally obtained as friction coefficient at the copper/steel interface. In the case of pure expansion hydroforming, based on an internal pressure loading only, a “corner filling” test has been run for tube hydroforming. Both dry and lubricated contacts have been considered. Various configurations and shapes have been studied such as the rectangular, trapezoidal, and trapezoid-sectional dies. Finite element simulations with 3D shell and 3D solid models have been performed with different values of friction coefficients. From the main results, it was found that the critical thinning occurs in the transition zone for the square and rectangular section die and in the sharp angle for the trapezoidal and trapezoid-sectional die. The comparison between numerical data and experimental results shows a good agreement. Moreover, the thickness distribution along the cross section is relatively consistent with those measured for the 3D shell model; however, the 3D solid models do not provide a realistic representation of the thickness distribution in the shaped tube. Finally, the results obtained from the theoretical model were more efficient than the results obtained from the pin-on-disk test. 相似文献
64.
Pascal Williams Claude Lévy-Clément Ana Albu-Yaron Nathalie Brun Christian Colliex 《Journal of Porous Materials》2000,7(1-3):159-163
First results of an Electron Energy Loss Spectroscopy in the Near Field (NFEELS) mode of n+ porous silicon are described here. Sequences of EELS spectra in the low loss energy range (0–30 eV) were recorded, using a scanning transmission electron microscope, as the e-beam was scanned across a nano-hole surrounded by Si platelets. This technique is shown to be very sensitive to spectral and spatial changes in the electromagnetic field distribution outside the surface of nanoparticles, governed by their local nature and shape. 相似文献
65.
François Malherbe Jean‐Pierre Besse Steven R. Wade Warren J. Smith 《Catalysis Letters》2000,67(2-4):73-79
The catalytic activity of a series of mixed oxides obtained by the thermal decomposition of hydrotalcite‐like precursors was
assessed for the alkoxylation of n-butanol with ethylene oxide. The calcination products of a decavanadate intercalated magnesium–aluminium layered double hydroxide
were shown to possess extremely high activity for the alkoxylation reaction achieving up to 100% conversion in batch reaction.
In all cases, the catalysts exhibit a much higher selectivity towards the monoglycol adduct than that obtained with the industrial
catalyst.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
66.
Serge Laplante Nathalie Souchet Piotr Bryl 《European Journal of Lipid Science and Technology》2009,111(2):135-141
Among the fat fish species available from Eastern Quebec (Canada), whole Atlantic mackerel (Scomber scombrus) and herring (Clupea harengus) represent abundant fishery resources which are currently under‐utilized. They have relatively high contents of oil and coenzyme Q10 (CoQ10) in their tissues, which could be valuable for nutraceutical applications. Therefore, two low‐temperature extraction processes were compared for the recovery of oil and CoQ10 from these resources, such as enzymatic hydrolysis using Protamex? and supercritical CO2 (SCO2) using fish lyophilizates. The results revealed that highest yields of oil and CoQ10 were obtained using the enzymatic hydrolysis process with mackerel. Whatever the process used, CoQ10 concentrations were higher in herring oil, due mainly to a more selective extraction of CoQ10 over that of the oil. The highest CoQ10 recovery rates (extraction efficiencies) were obtained using the enzymatic hydrolysis process with both types of fish, but also the SCO2 process with herring under some conditions. For mackerel, the lower CoQ10 recovery rates obtained from the SCO2 process were explained by its more important matrix effect. An economic assessment of both processes revealed that the enzymatic hydrolysis extraction process would be the most promising for up‐scaling the recovery of oil and CoQ10 from these resources. 相似文献
67.
Nathalie Dupuy Oswin Galtier Yveline Le Drau Christian Pinatel Jacky Kister Jacques Artaud 《European Journal of Lipid Science and Technology》2010,112(4):463-475
Chemometric treatment of near‐infrared (NIR) and mid‐infrared (MIR) combined spectra was used firstly to predict oil and water contents in fresh olive fruit samples (n = 223) and secondly to classify these samples into five principal French cultivar origins (Aglandau, Cailletier, Olivière, Salonenque, and Tanche). The study was carried out during four crop years (2005/2006 to 2008/2009) to take into account the seasonal variations. The comparison of the results obtained in the combined range (REP = 2.6% for the water content and 3.5% for the oil content) provides an obvious advantage compared to the NIR and MIR techniques used separately. Fresh olive fruit cultivars were satisfactorily classified with the partial least squares‐discriminant analysis (PLS‐DA) method in the combined range. After use of the K‐means clustering on the PLS‐DA scores, all the samples were well classified into their five groups of origin. The use of infrared combined spectra allows a considerable improvement in estimating olive fruit quality (oil and water contents, varietal origins). 相似文献
68.
Marie Nathalie Contou-Carrere 《Chemical engineering science》2008,63(15):4012-4025
This paper focuses on non-isothermal plug flow reactors with fast and slow reactions. These processes are modeled by first order hyperbolic partial differential equations with large and small parameters, which results in stiffness and multi-scale behavior. Through a combination of the method of characteristics and singular perturbation techniques, a model reduction method is developed for obtaining a non-stiff representation of the dominant dynamics of these systems. The application of the method and the advantages of using the reduced models for model-based control are illustrated through a case study. 相似文献
69.
70.
Dr. Thomas Le Bihan Dr. Cathryn H. S. Driver Dr. Thomas Ebenhan Dr. Nathalie Le Bris Dr. Jan Rijn Zeevaart Prof. Dr. Raphaël Tripier 《ChemMedChem》2021,16(5):809-821
An improved glucose-chelator-albumin bioconjugate (GluCAB) derivative, GluCAB-2Mal, has been synthesized and studied for in vivo 64Cu-PET/CT imaging in breast cancer mice models together with its first-generation analogue GluCAB-1Mal. The radioligand works on the principle of tumor targeting through the enhanced permeability and retention (EPR) effect with a supportive role played by glucose metabolism. [64Cu]Cu-GluCAB-2Mal (99 % RCP) exhibited high serum stability with immediate binding to serum proteins. In vivo experiments for comparison between tumor targeting of [64Cu]Cu-GluCAB-2Mal and previous-generation [64Cu]Cu-GluCAB-1Mal encompassed microPET/CT imaging and biodistribution analysis in an allograft E0771 breast cancer mouse model. Tumor uptake of [64Cu]Cu-GluCAB-2Mal was clearly evident with twice as much accumulation as compared to its predecessor and a tumor/muscle ratio of up to 5 after 24 h. Further comparison indicated a decrease in liver accumulation for [64Cu]Cu-Glu-CAB-2Mal. 相似文献