Production of rapidly solidified Al/SiC composites

Rapidly solidified metal matrix composites have been produced on a laboratory scale either by (1) melt spinning a composite after introduction of the ceramic phase and extrusion of the flakes obtained, or (2) blending melt-spun powder (basic alloy) with the ceramic phase and subsequent extrusion. AlMg(Si) alloys were used as matrix material while SiC particles with diameters of 3 or 20 m were used as the ceramic phase. For the composites prepared by route 1 it was found that the basic alloy was reinforced by the addition of 3 m particles whereas for the 20m particles reinforcement was observed only for very ductile matrices. The bond between SiC particles and matrix was good. A diffusion and wetting bond was formed. For the composites prepared by route 2 it was found that reinforcement did not occur and that the bond between particles and matrix was weak. Debonding of the particles took place in the case of tensile fracture. The advantage of a rapidly solidified matrix for these composites is that relatively high ductilities are combined with good reinforcement effects. Prior contact of the ceramic phase and the aluminium melt is needed for a good bond between SiC and the matrix material. It is concluded that route 1 should be preferred for the production of rapidly solidified aluminium matrix composites.     

Electrical properties of monoazacrown ether-substituted phthalocyanines

D.c. conductivities of polycrystalline monoazacrown ether-substituted phthalocyanines (M=2H, Ni, Zn, Pb, Cu) and diphthalocyanine (M=Lu) are measured as Au-MPc-Au sandwiches to be of the order 10^–10–10^–12 S m^–1. Chemical doping with oxidants (e.g. NOBF₄) and enhancing the stacking of planar phthalocyanine moieties through the formation of alkali metal adducts with sodium and potassium ions leads to increase in conductivity of the order 10¹–10². The low conductivity and the diamagneticity of the bis(phthalocyaninato)-lutetium can be ascribed to the lack of radical nature in LuH(Pc)₂. For the a.c. conductivities, lead and lutetium complexes form a group with higher conductivities and the rest show lower conductivity. The conduction activation energies calculated from Arrhenius plots exhibit the lowest value (0.40 eV) for the lutetium compound.Part of this work was presented at NATO-ASI on Semiconductor Materials and Processing Technologies, Erice, Sicily, 1–13 July 1991.     

Variation in light scattering and water-holding capacity along the porcine Longissimus dorsi muscle

The meat quality of M. longissimus muscle was evaluated in 851 pigs by using the Fibre Optic Probe (FOP) at three sites in the muscle and in both halves of the carcass. A systematic difference between sites was found, with the lowest light scattering (indicating the best meat quality) in the mid-part of the muscle and higher light scattering in the anterior and posterior parts. A non-systematic variation was also observed, with the opposite pattern in some animals, even though it was not frequent. A negative influence of the shackling was found, yielding higher FOP values in the shackled half.

Drip loss measurements in the Longissimus muscle, taken from another 100 pig carcasses, were evaluated using three methods. Drip loss, too, showed a considerable variation along the Longissimus muscle, with minimum losses around the last rib. Repeatability estimates, calculated from two non-consecutive pieces of the Longissimus dorsi muscle from each carcass, varied from 0·4 when keeping samples vacuum packed for 2 days, to 0·5 when the samples were either kept in plain plastic bags for 2 days or in a meat container with a squared inset for 1 or 2 days.     

Resistant starch formation during baking -effect of baking time and temperature and variations in the recipe

Summary The dietary fibre content in white wheat bread, measured with an enzymatic, gravimetric method, was almost 20% higher than in the corresponding flour. The increment was largely explained by the formation of resistant starch, i.e. starch available to amyloglucosidase only after solubilization with 2m-KOH. The resistant starch was formed in the oven or upon cooling of the finished bread. The water content in the dough seemed to influence the extent of the resistant starch formation, whereas changes in the fat content had no effect. The results indicate that the resistant starch might be hard retrograded starch, possibly amylose.

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Bildung von resistenter Stärke während des Backens in Abhängigkeit von Backzeit, Backtemperatur und Rezeptvariationen

Zusammenfassung Die Menge an Ballaststoffen, die nach einer enzymatisch-gravimetrischen Methode bestimmt wurde, war in weißem Weizenbrot fast 20% höher als in dem entsprechendem Mehl. Die Erhöhung konnte zum großen Teil auf die Bildung von resistenter Stärke zurückgeführt werden, d. h. auf eine Stärkefraktion, die nur nach Auflösung mit 2m-KOH für Amyloglucosidase zugänglich ist. Die resistente Stärke wird während des Backens oder während der Abkühlung des Brotes gebildet, und die Menge scheint vom Wassergehalt des Teiges, aber nicht vom Fettgehalt abhängig zu sein. Die Resultate dieser Untersuchung weisen darauf hin, daß die resistente Stärke retrogradierte Stärke, möglicherweise Amylose, ist.

     

Effect of Carbon Content on Variant Pairing in Bainitic Low Alloy Steel

Metallurgical and Materials Transactions A - Variant pairing in bainite was evaluated in four different commercial low alloy steels with medium to high carbon content. The steels investigated were...     

印刷线路板电镀废水综合治理

简述线路板电镀废水中氰、铜氨、油墨废水治理方法和混合废水综合治理工艺流程及原理。     

Depolymerization of Turkish lignites. I. Effect of substituted phenols

A lignite (C, 67.4 wt%) was depolymerized with phenol, p-nitrophenol and o-chlorophenol using sulphuric acid as catalyst. The solubility of the lignite was enhanced by these treatments, with phenol being the most reactive reagent whereas p-nitrophenol was the least reactive. The distribution of nitro- and chloro-groups in the solubilized products was investigated by infrared spectrometry and it was found that these groups were redistributed among the pyridine- and methanol-soluble materials. It is suggested that benzene-soluble material is produced by self-depolymerization of coal or by degradation of pyridine- and methanol-soluble material.     

Lead recovery from aqueous environment by using porous carbon of citrus fruits waste: equilibrium,kinetics and thermodynamic studies

ABSTRACT

The mixture of citrus fruits (orange, grapefruit, mandarin, and lemon) wastes was utilized to obtain high surface area activated carbon (AC) by H₃PO₄ activation. The production conditions were optimized and the optimum conditions were determined. The optimal-activated carbon (CFWAC) was characterized by various physicochemical techniques. CFWAC was also used as a sorbent for Pb (II) ions from water. Batch experiments were performed to explore the adsorption capacity and mechanism. The Langmuir isotherm and pseudo-second-order kinetic model showed good fitness to the experimental data. The maximum Pb (II) adsorption capacity of CFWAC was found to be 163.93 mg/g.     

Molecular motion of small molecules in cellulose gels studied by NMR

Measurements of relaxation times, T₁ and T₂, and self-diffusion coefficients, D, for small molecules, viz., H₂O, dioxane and t-butanol, in the gel system cellulose/H₂O are reported and compared with those for H₂O in a polyacrylamide gel of the same polymer content. The temperature dependence of T₁ and D can for all the penetrants be represented by Arrhenius type relations which merely are parallel shifts by the same amount, towards smaller values, of those obtained without polymer. The T₂ values for H₂O in both gels pass through a shallow minimum over the considered temperature interval (14°?44°C). Furthermore, relaxation times T₁ of D₂O in the gel system cellulose/D₂O are reported; in a plot of ln T₁ vs. 1/T, a plateau region is observed at higher temperatures.     

碳四烷烃催化裂解制低碳烯烃的研究进展

论述了碳四烷烃催化裂解制低碳烯烃的催化剂体系、影响因素及催化裂解方式。该催化剂体系包括硅铝酸盐及锆硫酸盐,氧化铝与碱金属或碱土金属的混合物,负载型催化剂等3种类型。其中分子筛(晶体硅铝酸盐)及其改性催化剂是研究开发的主要方向。除操作条件外,稀释剂、引发和抑制剂和裂解反应方式对催化裂解反应均有影响。催化裂解反应机理与催化剂的种类和反应条件相关。对于酸性分子筛催化剂有2种比较公认的机理:正碳离子机理,自由基与正碳离子机理两种形式。研究表明碳四烷烃,特别是正丁烷催化裂解制低碳烯烃具有良好的低碳烯烃收率,收率可达50%以上。