Supercritical liquefaction of common reed (Phragmites australis) with alkali catalysts

Milled Phragmites australis was liquefied in organic solvents with and without catalyst in a cylindrical reactor at temperatures of 533, 553, and 573 K under supercritical conditions. The liquefied compounds were extracted with diethyl ether and benzene using an extraction procedure. The product yields without catalyst in supercritical methanol, ethanol, and acetone were found to be 55.4%, 64.4%, and 73.5% at 573 K respectively. The highest conversion to liquid products was obtained in supercritical acetone with 10% sodium hydroxide as catalyst at the same temperature in the catalytic runs. Main chemical compounds present in the liquid products obtained in ethanol without catalyst and acetone with sodium hydroxide catalyst at 573 K were analyzed and characterized by gas chromatography–mass spectrometry (GC-MS).     

Smoothing With Split Linear Fits

We introduce a family of smoothing algorithms that can produce discontinuous output. Unlike most commonly used smoothers, that tend to blur discontinuities in the data, this smoother can be used for smoothing with edge detection. We cite examples of other approaches to (two-dimensional) smoothing with edge detection in image processing, and apply our one-dimensional smoother to sea surface temperature data where the discontinuities arise from changes in ocean currents.     

Web-based environmental simulation: bridging the gap between scientific modeling and decision-making

Data availability in environmental sciences is growing rapidly. Conventional monitoring systems are collecting data at increasing spatial and temporal resolutions; satellites provide a constant stream of global observations, and citizen scientist generate local data with electronic gadgets and cheap devices. There is a need to process this stream of heterogeneous data into useful information, both for science and for decision-making. Advances in networking and computer technologies increasingly enable accessing, combining, processing, and visualizing these data. This Feature reflects upon the role of environmental models in this process. We consider models as the primary tool for data processing, pattern identification, and scenario analysis. As such, they are an essential element of science-based decision-making. The new technologies analyzed here have the potential to turn the typical top-down flow of information from scientists to users into a much more direct, interactive approach. This may accelerate the dissemination of environmental information to a larger community of users. It may also facilitate harvesting feedback, and evaluating simulations and predictions from different perspectives. However, the evolution poses challenges, not only to model development but also to the communication of model results and their assumptions, shortcomings, and errors.     

Extraction of Bioactive Compounds from Milled Grape Canes (Vitis vinifera) Using a Pressurized Low-Polarity Water Extractor

Trans-resveratrol and trans-ε-viniferin were extracted from milled grape canes using pressurized low-polarity water. The effects of temperature were significant for both compounds (p ≤ 0.05): extraction at 160 °C resulted in a 40% loss of trans-resveratrol compared to 95 °C while reduction of trans-ε-viniferin at both temperatures remained at 30%. Increasing ethanol concentration from 0% to 25% increased the extraction of total phenolics and trans-ε-viniferin by 44% and 489%, respectively. Solvent flow rate also influenced trans-ε-viniferin extraction. Antioxidant activity showed a strong correlation with total phenolic content of the extracts, and the two target phenolic compounds. Except for the modifier concentration, the extraction parameters studied were not statistically significant with respect to the antioxidant activity of extracts (p > 0.05). Effective diffusivities of trans-resveratrol multiplied from 3.3 × 10⁻¹¹ to 10.4 × 10⁻¹¹ m²/s by three times with increasing temperature. The modified Gompertz equation satisfactorily explained the extraction of the stilbenes investigated.     

Intercomparisons of Mobility Size Spectrometers and Condensation Particle Counters in the Frame of the Spanish Atmospheric Observational Aerosol Network

Red Española de DMAs Ambientales (REDMAAS), the Spanish network of environmental differential mobility analyzers (DMAs), currently comprises six research groups involved in the measurement of atmospheric aerosol size distributions by means of DMAs. The aim of this network is to guarantee the good quality and comparability of the routine measurements carried out at each location and in diverse environments across Spain. In order to achieve this objective, one of its main activities is the annual intercomparison of mobility size spectrometers used within the network (five units of scanning mobility particle sizers [SMPS] and one ultrafine particle monitor [UFPM]). Here we report the 2main results obtained during the 2010–2012 campaigns, including a study on particle deposition in dryers used in ambient air sampling systems. In general, all instruments showed good performance with deviations in accepted tolerance. The intercomparisons have been proved to be a useful exercise to detect instrument problems, such as incorrect calibrations. DMA calibration checks were performed with polystyrene latex reference particles. Deviations of less than 1% were observed during the first year, which increased 4.7% during the last campaign. Some differences among the responses of different condensation particle counter (CPC) models were encountered, being mainly connected to the intrinsic characteristics of each counter. The comparison of UFPM with CPCs has given good results. The SMPS intercomparisons, especially for particles above 20 nm, have been within +/?15% tolerance. Regarding particle deposition in dryers used in sampling systems, particle penetration was lower than predicted by the recommended model. This result was probably due to the fact that not all the possible mechanisms were considered in the model.

Copyright 2015 American Association for Aerosol Research     

Individual Particle Morphology and Acidity

The morphological characterization of particles during the Pittsburgh Air Quality Study (PAQS) suggests that particle shape and physical state depends on their acidity. The aerosol shape parameters measured by Computer-Controlled Scanning Electron Microscopy (CCSEM) are statistically different in periods when atmospheric particles are neutral and when they are acidic. High concentrations of particles smaller than 500 nm with high sulfur content and liquid appearance or signs of a previous liquid state before partial or total recrystallization are present on filters collected in days with high aerosol acidity. By contrast, in winter and summer periods in which the aerosol was neutral, the shape parameter values are similar and suggest that the particles have been dried out. These direct observations support the hypothesis that during summer acidic periods in the Eastern United States the particles may contain some water even at low relative humidity both in the atmosphere and on filters.     

Effects of Optimized Operating Parameters on Combustion Characteristics and NO_x Emissions of a Burner based on Orthogonal Analysis

To optimize the structure of the burner,improve the combustion performance,and reduce the emission of NO_x,a self-circulating low NO_x combustion technology was used to design a new type of flue gas self-circulating low NO_x burner.Based on previous research on the numerical model of combustion and the composition of mixed gas on combustion and NO_x emissions,the effect of various factors on the ejection coefficient of the flue gas self-circulating structure was analyzed using the orthogonal test method,and the burner operating parameters,such as preheating temperature and excess air coefficient,were deeply studied through the three-dimensional finite element numerical model in this paper.The results show that the diameter ratio of the nozzle and the length of the cylindrical section of the flue gas self-circulating structure have great influence on its ejection and mixing ability.The optimal ejection coefficient was 0.4829.Overall,the amount of NO_x emissions greatly increased from 6.23×10~(-6) (volume fraction) at the preheating temperature 973 K to 3.5×10~(-3) at preheating temperature 1573 K.When the excess air coefficient decreased from 1.2 to 1,the maximum combustion temperature decreased from 2036.3 K to 1954.22 K,and the NO_x emissions decreased from 352.29×10~(-6) to 159.73×10~(-6).