全文获取类型
收费全文 | 2949篇 |
免费 | 178篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 86篇 |
综合类 | 4篇 |
化学工业 | 707篇 |
金属工艺 | 61篇 |
机械仪表 | 98篇 |
建筑科学 | 102篇 |
矿业工程 | 8篇 |
能源动力 | 118篇 |
轻工业 | 492篇 |
水利工程 | 16篇 |
石油天然气 | 14篇 |
无线电 | 178篇 |
一般工业技术 | 769篇 |
冶金工业 | 26篇 |
原子能技术 | 9篇 |
自动化技术 | 440篇 |
出版年
2023年 | 23篇 |
2022年 | 15篇 |
2021年 | 61篇 |
2020年 | 57篇 |
2019年 | 67篇 |
2018年 | 114篇 |
2017年 | 110篇 |
2016年 | 140篇 |
2015年 | 100篇 |
2014年 | 148篇 |
2013年 | 327篇 |
2012年 | 207篇 |
2011年 | 216篇 |
2010年 | 179篇 |
2009年 | 127篇 |
2008年 | 135篇 |
2007年 | 117篇 |
2006年 | 94篇 |
2005年 | 52篇 |
2004年 | 31篇 |
2003年 | 48篇 |
2002年 | 38篇 |
2001年 | 31篇 |
2000年 | 36篇 |
1999年 | 30篇 |
1998年 | 21篇 |
1997年 | 15篇 |
1996年 | 26篇 |
1995年 | 20篇 |
1994年 | 29篇 |
1993年 | 23篇 |
1992年 | 23篇 |
1991年 | 20篇 |
1990年 | 20篇 |
1989年 | 18篇 |
1988年 | 13篇 |
1985年 | 32篇 |
1984年 | 34篇 |
1983年 | 28篇 |
1982年 | 24篇 |
1981年 | 36篇 |
1980年 | 32篇 |
1979年 | 25篇 |
1978年 | 24篇 |
1977年 | 18篇 |
1976年 | 20篇 |
1975年 | 14篇 |
1974年 | 13篇 |
1973年 | 14篇 |
1972年 | 15篇 |
排序方式: 共有3128条查询结果,搜索用时 15 毫秒
71.
Igor Jerković Marina Rajić Zvonimir Marijanović Mate Bilić Stela Jokić 《分离科学与技术》2016,51(18):2925-2931
Supercritical (SC) CO2 extraction of dried Immortelle flowers was performed at different process parameters. The optimal extraction conditions related to the yield were determined by response surface methodology (yield 4.09% at 20 MPa and 52°C). The extracts were analyzed by GC-MS and tremetone derivatives dominated: bitalin A, 12-acetoxytremetone, gnaphaliol, 1-[2-(2-methyl-2,3-dihydroxypropyl)-2,3-dihydro-1-benzofuran-5-yl]ethanone, isobutyl bitalin A, and 1-[2-(acetylprop-1-en-2-yl)-3-hydroxy-2,3-dihydro-1-benzofuran-5-yl]ethanone. Striking differences were found among the essential oil and SC-CO2 extracts composition. The major oil compounds were γ-curcumene, α-pinene, β-selinene, α-selinene, and limonene. Mono- and sesquiterpene were found among minor constituents of the extracts. Neryl acetate was present in the extracts and essential oil. 相似文献
72.
Ana Rešček Zlata Hrnjak-Murgić Nino Dimitrov Kata Galić 《Polymer-Plastics Technology and Engineering》2016,55(14):1450-1459
Polyethylene (PE) was modified and prepared as double-layer polyethylene/polycaprolactone (PE/PCL) film. Magnetite and casein were added to the PCL-coating film to improve barrier properties and prevent destruction of basic structure of primary polymer PE. Significant improvements were observed with regards to mechanical (tensile strength, elongation at break) and thermal properties, while barrier (O2 permeability) properties were slightly improved. Overall migration values into acetic acid were lower (from 1 to 4.6 mg/dm2) than the upper limit set by the legislation. Specific migration of iron in PE/PCL-Fe samples is also below (µg/L) specific migration limit value set by the legislation (mg/kg). 相似文献
73.
Dr. Robert Kuhnert Dr. Lydia Kuhnert Dr. Menyhárt-B. Sárosi Sven George Dr. Dijana Draca Dr. Svetlana Paskas Dr. Bettina Hofmann Prof. Dr. Dieter Steinhilber Prof. Dr. Walther Honscha Prof. Dr. Sanja Mijatović Prof. Dr. Danijela Maksimović-Ivanić Prof. Dr. Evamarie Hey-Hawkins 《ChemMedChem》2022,17(1):e202100588
12-Lipoxygenase is crucial for tumour angiogenesis. 5,6,7-Trihydroxy-2-phenyl-4H-1-benzopyran-4-one (baicalein) is a suitable inhibitor for this enzyme but is rapidly metabolised in vivo. Thus, an improvement of the metabolic stability is necessary to enhance the therapeutic efficiency. An emerging approach to enhance metabolic stability of carbon-based pharmaceuticals is the use of metabolically stable, non-toxic boron clusters, such as dicarba-closo-dodecaborane(12)s (carboranes) as phenyl mimetics. Therefore, the unsubstituted phenyl ring of baicalein was replaced by meta-carborane, resulting in borcalein, the carborane analogue of baicalein. This substitution resulted in a decreased inhibitory activity toward 12-lipoxygenase, but led to increased toxicity in melanoma (A375, B16, B16F10) and colon cancer cell lines (SW480, HCT116, CT26CL25) with decreased tumour selectivity in comparison to baicalein. Surprisingly, borcalein displays a different mechanism of cytotoxicity with increased intracellular production of reactive oxygen species (ROS), reactive nitrogen species (RNS) and nitric oxide (NO). 相似文献
74.
75.
Milan Stakić Dejan Cvetinović Predrag Škobalj Vuk Spasojević 《Chemical Engineering Research and Design》2014
Despite benefiting from vast fuel reserves, combustion of low-rank coals is commonly characterized by low thermal efficiency and high pollutant emissions, partly due to high moisture content of the coals in question. Thus, removal of moisture from low-rank coals is deemed an important quality upgrading method. The paper provides an overview of the current status of low-rank coal upgrading technologies, particularly with respect to utilization of drying and dewatering procedures. In order to examine the influence of relevant parameters on the moisture removal process, a model of convective coal drying in a packed, as well as in a fluid bed combustion arrangement, is developed and presented. Product-specific data (intraparticle mass transfer, gas–solid moisture equilibrium) related to the coal variety addressed herein (lignite) are obtained through preliminary investigations. Effective thermal conductivity of the packed bed as defined by Zehner/Bauer/Schlünder is used to define heat transfer mechanisms occurring in the packed bed. Similar two-phase fluidization model has been validated for different types of biomaterials. 相似文献
76.
Veljko R. Djokić Aleksandar D. Marinković Ovidiu Ersen Petar S. Uskoković Rada D. Petrović Velimir R. Radmilović Djordje T. Janaćković 《Ceramics International》2014
Nanostructural TiO2/modified multi-wall carbon nanotubes photocatalysts were prepared by hydrolysis of Ti(iso-OC3H7)4 providing chemical bonding of anatase TiO2 nanoparticles onto oxidized- or amino-functionalized multi-wall carbon nanotubes (MWCNT). The processes of functionalization of the MWCNT and the deposition of TiO2 influence the photocatalytic activity of the synthesized nanocomposites. The phase composition, crystallite size, and the structural and surface properties of the obtained TiO2/modified-MWCNT nanocomposite were analyzed from XRD, FEG-SEM, TEM/HRTEM and FTIR data, as well low temperature N2 adsorption. In the photocatalytic study, the TiO2/oxidized-MWCNT catalyst showed the highest and the TiO2/amino functionalized-MWCNT catalysts somewhat lower degradation rates, indicating that the enhancement of photocatalysis was supported by the more effective electron transfer properties of the oxygen- than amino-containing functional groups, which support the efficient charge transportation and separation of the photogenerated electron-hole pairs. 相似文献
77.
The aim of this study was to investigate the usefulness of combined application of quality by design tools such as central composite design (CCD), response surface methodology (RSM), and artificial neural networks (ANN) in the characterization, modeling, and optimizaton of spray drying of a poorly soluble drug : cyclodextrin complex. Models were developed by RSM and ANN from different pools of data. The model with best predictability was the ANN multilayer perceptron (MLP)1 model developed from the largest group of data (R 2 for response yield 0.854, moisture content 0.886). On the other hand, analysis of equations derived from the application of RSM contributed in better understanding the complex relationships between input and output variables. By application of a desirability function approach, optimal process parameters that resulted in the best process yield (86%) and minimal moisture content in the powder (3.3%) were established (25% feed concentration, 180°C inlet air temperature, 10% pump speed). 相似文献
78.
Cereal-based confectionery products being consumed through whole human life are considered mainly to be a source of carbohydrates, that is energy, although cereals are a rich source of minerals as well. To evaluate some hard biscuits produced in Croatia as a source of different trace elements in nutrition, in this study Zn and Cu contents were determined in classic wheat flour biscuits and in dietetic biscuits enriched with whole wheat grain flour or whole wheat grain grits, soya flour and skimmed milk. Zn was determined by flame atomic absorption spectrometry (AAS); Cu was determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES). The results show that the Zn content in different kinds of biscuits ranges from 5.89 up to 17.64 mg/kg and the Cu content ranges from 1.15 up to 2.79 mg/kg depending on the type of wheat milling products and mineral content of other ingredients used. Enriched dietetic biscuits produced from wheat flour type 850 and whole wheat grain flour and/or soya flour and skimmed milk were almost 200% and 150% higher in Zn and Cu, respectively, in comparison to classic white wheat flour biscuits and can be considered as good sources of Zn and Cu in nutrition. 相似文献
79.
In 2007 and 2008, a monitoring study was carried out in Poland to examine the occurrence of thermotolerant Campylobacter spp. in raw and cooked chicken products available on the retail market. A total of 912 samples were tested: 443 samples of raw chicken meat, 146 samples of giblets, and 323 ready-to-eat poultry products (150 samples of spit-roasted chicken, 56 samples of smoked chicken, and 117 samples of paté and cold meats). A high level of contamination of raw chicken meat (51.7% of samples) and chicken giblets (47.3% of samples) was detected. However, thermotolerant Campylobacter spp. were found in only 1.2% of the ready-to-eat poultry products. 相似文献
80.
Gorica Vuković Deyana Shtereva Vojislava Bursić Rositsa Mladenova Sanja Lazić 《LWT》2012,49(2):312-319
Babies and small children are especially sensitive population to the exposure to environmental contaminants. Their small mass and developing systems, including brain development may show adverse health effects from even low levels of contamination on a chronic or single dose case. In this paper one extraction method and two chromatographic techniques for the determination of pesticide residues in baby food were evaluated. A liquid chromatography–tandem mass spectrometry technique combined with electrospray ionization (ESI), (LC–MS/MS) and gas chromatography–mass spectrometry detection (GC–MSD) technique were applied in the detection of 50 pesticides in baby food. So-called QuEChERS (quick, easy, cheap, effective, rugged and safe) method was used as a sample preparation procedure. The recoveries were investigated at three levels (5, 10 and 50 μg/kg) and the results obtained showed compliance with the contemporary EU requirements with a few exceptions. LOQs for most of the tested pesticides were below the EU MRLs (10 μg/kg), except deltamethrin, cypermethrin, fenvalerate, phosalone and beta-cyfluthrin (LOQs were 10 μg/kg). Both techniques were applied in the analysis of 50 samples of baby food manufactured in Serbia. 相似文献