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排序方式: 共有218条查询结果,搜索用时 15 毫秒
1.
Antonio Sanchez‐Solis Andres Garcia‐Rejon Mirna Estrada Antonio Martinez‐Richa Guadalupe Sanchez Octavio Manero 《Polymer International》2005,54(12):1669-1672
The production and properties of blends of poly(ethylene terephthalate) (PET) and poly(ethylene naphthalene 2,6‐dicarboxylate) (PEN) with three modified clays are reported. Octadecylammonium chloride and maleic anhydride (MAH) are used to modify the surface of the montmorillonite–Na+ clay particles (clay–Na+) to produce clay–C18 and clay–MAH, respectively, before they are mixed with the PET/PEN system. The transesterification degree, hydrophobicity and the effect of the clays on the mechanical, rheological and thermal properties are analysed. The PET–PEN/clay–C18 system does not show any improvements in the mechanical properties, which is attributed to poor exfoliation. On the other hand, in the PET–PEN/clay–MAH blends, the modified clay restricts crystallization of the matrix, as evidenced in the low value of the crystallization enthalpy. The process‐induced PET–PEN transesterification reaction is affected by the clay particles. Clay–C18 induces the largest proportion of naphthalate–ethylene–terephthalate (NET) blocks, as opposed to clay–Na+ which renders the lowest proportion. The clay readily incorporates in the bulk polymer, but receding contact‐angle measurements reveal a small influence of the particles on the surface properties of the sample. The clay–Na+ blend shows a predominant solid‐like behaviour, as evidenced by the magnitude of the storage modulus in the low‐frequency range, which reflects a high entanglement density and a substantial degree of polymer–particle interactions. Copyright © 2005 Society of Chemical Industry 相似文献
2.
Roberto Nicolsky Miguel Octavio Sonio Frota-Pessôa 《Journal of Low Temperature Physics》1985,58(1-2):11-26
We present a simple model to simulate small three-dimensional superconducting constrictions of variable thickness (VTBs) for which the cross-sectional dimensions are of the same order as the length, and both are less than (T). We study the behavior of the modulus of the order parameterf and the supercurrent densityJ
s
as a function of the various dimensions. We find that the extent to whichf is depressed in the banks depends on the ratio of width to length of the constriction. We show that even for very abrupt geometries,J
s
is not zero andf does not reach its equilibrium value immediately outside the constriction. On the basis of our results, we propose a more general expression for the effective length valid also when all dimensions are of the same order. The calculated values ofdI
c
/dT are consistent with experimental data from well-characterized VTBs. We suggest that the discrepancy between the calculated and experimental values ofI
c
R
n
may be due to the nonuniformity of the normal current density in the constriction. 相似文献
3.
Angelo Lucia Peter A. DiMaggio Meghan L. Bellows Leah M. Octavio 《Computers & Chemical Engineering》2005,29(11-12):2363
Normal alkanes show very complicated phase transition kinetics and macroscopic phase equilibrium behavior. This paper focuses on the phase stability and equilibrium of complicated mixtures like n-alkanes and on the enabling global optimization technologies needed to gather problem knowledge. The new ideas contained in this paper include:
- (1) novel level set methods for gathering encoded knowledge;
- (2) the differential geometry for uncovering pathways to more subtle knowledge;
- (3) all supporting non-linearly constrained optimization techniques;
- (4) all data handling needed to unravel complex solution structure.
4.
Beatriz Gutiérrez‐Rivera Krzysztof Waliszewski‐Kubiak Octavio Carvajal‐Zarrabal Maria Guadalupe Aguilar‐Uscanga 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2012,87(2):263-270
BACKGROUND: Efficient conversion of glucose/xylose mixtures from lignocellulose is necessary for commercially viable ethanol production. Oxygen and carbon sources are of paramount importance for ethanol yield. The aim of this work was to evaluate different glucose/xylose mixtures for ethanol production using S. cerevisiae ITV‐01 (wild type yeast) and P. stipitis NRRL Y‐7124 and the effect of supplying oxygen in separate and co‐culture processes. RESULTS: The complete conversion of a glucose/xylose mixture (75/30 g L?1) was obtained using P. stipitis NRRL Y‐7124 under aerobic conditions (0.6 vvm), the highest yield production being Yp/s = 0.46 g g?1, volumetric ethanol productivity Qpmax = 0.24 g L?1 h?1 and maximum ethanol concentration Pmax = 34.5 g L?1. In the co‐culture process and under aerobic conditions, incomplete conversion of glucose/xylose mixture was observed (20.4% residual xylose), with a maximum ethanol production of 30.3 g L?1, ethanol yield of 0.4 g g?1 and Qpmax = 1.26 g L?1 h?1. CONCLUSIONS: The oxygen present in the glucose/xylose mixture promotes complete sugar consumption by P. stipitis NRRL Y‐7124 resulting in ethanol production. However, in co‐culture with S. cerevisiae ITV‐01 under aerobic conditions, incomplete fermentation occurs that could be caused by oxygen limitation and ethanol inhibition by P. stipitis NRRL Y‐7124; nevertheless the volumetric ethanol productivity increases fivefold compared with separate culture. Copyright © 2011 Society of Chemical Industry 相似文献
5.
Sodium phthalamates as corrosion inhibitors for carbon steel in aqueous hydrochloric acid solution 总被引:2,自引:0,他引:2
Eugenio A. Flores Octavio Olivares Natalya V. Likhanova Marco A. Domínguez-Aguilar Noel Nava Diego Guzman-Lucero Mónica Corrales 《Corrosion Science》2011,53(12):3899-3913
Three compounds of N-alkyl-sodium phthalamates were synthesized and tested as corrosion inhibitors for carbon steel in 0.5 M aqueous hydrochloric acid. Tests showed that inhibitor efficiencies were related to aliphatic chain length and dependent on concentration. N-1-n-tetradecyl-sodium phthalamate displayed moderate efficiency against uniform corrosion, 42–86% at 25 °C and 25–60% at 40 °C. Tests indicated that compounds behave as mixed type inhibitors where molecular adsorption on steel followed Langmuir isotherm, whereas thermodynamic suggested that a physisorption process occurred. XPS analysis confirmed film formation on surface, where Fe+2 complexes and Fe+2 chelates with phthalamates prevented steel from further corrosion. 相似文献
6.
Octavio Cota‐Arriola Mario Onofre Cortez‐Rocha Armando Burgos‐Hernández Josafat Marina Ezquerra‐Brauer Maribel Plascencia‐Jatomea 《Journal of the science of food and agriculture》2013,93(7):1525-1536
The control of micro‐organisms responsible for pre‐ and postharvest diseases of agricultural products, mainly viruses and fungi, is a problem that remains unresolved, together with the environmental impact of the excessive use of chemicals to tackle this problem. Current efforts are focused on the search for efficient alternatives for microbial control that will not result in damage to the environment or an imbalance in the existing biota. One alternative is the use of natural antimicrobial compounds such as chitosan, a linear cationic biopolymer, which is biodegradable, biocompatible and non‐toxic, has filmogenic properties and is capable of forming matrices for the transport of active substances. The study of chitosan has attracted great interest owing to its ability to form complexes or matrices for the controlled release of active compounds such as micro‐ and nanoparticles, which, together with the biological properties of chitosan, has allowed a major breakthrough in the pharmaceutical and biomedical industries. Another important field of study is the development of chitosan‐based matrices for the controlled release of active compounds in areas such as agriculture and food for the control of viruses, bacteria and fungi, which is one of the least exploited areas and holds much promise for future research. © 2013 Society of Chemical Industry 相似文献
7.
María Dolores Ayala Isaac Abdel Carmen Martínez Francisco Gil Octavio López Albors 《LWT》2010,43(3):465-17
Sea bream, Sparus aurata L., specimens were studied in pre-rigor (3 h) and during the following post-mortem days: 1, 5, 10, 15 and 22. Muscle and textural parameters were evaluated on 6 specimens/stage. Structural results showed scarce fibre-to-fibre detachment on pre-rigor, which increased during the post-mortem degradation. Ultrastructural changes revealed rapid muscle degradation. In pre-rigor myofibrils were detached to both sarcolemma and endomysium. Intermyofibrillar spaces increased and some mitochondriae and sarcoplasmic reticulum were swollen. After 1 day, the sarcolemma appeared occasionally disrupted and the interfibrillar spaces increased. From 5 to 10 days, the I-band and Z line presented some alterations, although these were more severe at 15-22 days. Thus, in these two last stages, loss of I-band, Z line and actin filaments was observed, that coincides with the alteration of the hexagonal arrangement in these advanced stages. Also, the fragmentation of myofibrils increased from 5 to 10 days on. Sarcolemma and endomysium were gradually disrupted throughout the post-mortem stages with total loss at 22 days. Consequently, the interfibrillar spaces increased at last stages. Autophagic mechanisms increased from 5 days on, with an intense destruction of all the intracytoplasmic organelles. Textural parameters decreased from pre-rigor until 5-10 days, mainly associated to detachment of myofibers to sarcolemma-endomysium. 相似文献
8.
E. Michael Thurman Imma Ferrer Octavio Malato Amadeo Rodriguez Fern ndez-Alba 《Food Additives & Contaminants》2006,23(11):1169-1178
Traditionally, the screening of unknown pesticides in food has been accomplished by GC/MS methods using conventional library-searching routines. However, many of the new polar and thermally labile pesticides are more readily and easily analysed by LC/MS methods and no searchable libraries currently exist (with the exception of some user libraries, which are limited). Therefore, there is a need for LC/MS libraries that can detect pesticides and their degradation products. This paper reports an identification scheme using a combination of LC/MS time-of-flight (accurate mass) and an Access database of 350 pesticides that are amenable to positive ion electrospray. The approach differs from conventional library searching of fragment ions. The concept consists of three parts: (1) initial screening of possible pesticides in actual market-place fruit extracts (apple and orange) using accurate mass and generating an accurate mass via an automatic ion-extraction routine, (2) searching the Access database manually for screening identification of a pesticide, and (3) identification of the suspected compound by accurate mass of at least one fragment ion and comparison of retention time with an actual standard. Imazalil and iprodione were identified in apples and thiabendazole in oranges using this database approach. 相似文献
9.
The DiffServ’s Assured Forwarding (af) Per-Hop Behavior (phb) Group defines a differentiated forwarding of packets in four independent classes, each class having three levels of drop precedence. Specific end-to-end services based on thisphb are still being defined. A particular type of service that could assure a given rate to a traffic aggregate has been outlined elsewhere. In such a service, a fair distribution of bandwidth is one of the main concerns. This paper presents experimental work carried out to evaluate howaf distributes bandwidth among flows under different load conditions and traffic patterns. We focused on the effect that marking mechanisms have on bandwidth sharing among flows within a singleaf class. The traffic types we used includeudp flows, individual and aggregatedtcp flows, mix oftcp andudp, tcp sessions with heterogeneous round-trip times, as well as color-blind and color-aware re-marking at the aggregation point fortcp flows. Tests were performed on real and simulated networks. We have found certain conditions under whichaf distributes bandwidth fairly among nonadaptiveudp flows andtcp aggregates. Finally, we evaluate a basic rule for setting the parameters of the two-rate Three-Color Marker conditioning algorithm (trtcm) in order to achieve a better bandwidth distribution fortcp flows. 相似文献
10.
Service composition in multi-Cloud environments must coordinate self-interested participants, automate service selection, (re)configure distributed services, and deal with incomplete information about Cloud providers and their services. This work proposes an agent-based approach to compose services in multi-Cloud environments for different types of Cloud services: one-time virtualized services, e.g., processing a rendering job, persistent virtualized services, e.g., infrastructure-as-a-service scenarios, vertical services, e.g., integrating homogenous services, and horizontal services, e.g., integrating heterogeneous services. Agents are endowed with a semi-recursive contract net protocol and service capability tables (information catalogs about Cloud participants) to compose services based on consumer requirements. Empirical results obtained from an agent-based testbed show that agents in this work can: successfully compose services to satisfy service requirements, autonomously select services based on dynamic fees, effectively cope with constantly changing consumers’ service needs that trigger updates, and compose services in multiple Clouds even with incomplete information about Cloud participants. 相似文献