A study on the characteristics of electrical discharge textured skin pass mill work roll

Electrical discharge texturing induces a recast white layer on the skin pass mill work roll surface, which forms the surface topography required for outer autobody steel strips and a heat-affected zone beneath it. The characteristics of these thermally influenced layers were studied by means of optical and scanning electron microscopes, X-ray diffractometer, radio frequency-glow discharge optical emission spectrometer and microhardness tester. It was found that the electrical discharge texturing led to a dramatic hardness drop in the white layer, which was attributed to the high amount of retained austenite. Moreover, softening was observed in over tempered section within heat-affected zone. Sub-zero and cryogenic treatments seem to be potential methods in order to restore the hardness of white layer and over tempered zone with an increase in both. Additionally, de-ionised water was found to be a promising dielectric liquid to abstain from retained austenite.     

Ozonation of Spent Reactive Dye-Baths: Effect of HCO3?/CO32? Alkalinity

The effect of carbonate and bicarbonate alkalinity (soda ash buffer as 5,180 mg/L HCO3? alkalinity at pH 7 and as 5,100 mg/L CO32? alkalinity at pH 12) on the ozonation of reactive vinylsulphone dyestuffs in a simulated spent dye-bath has been studied at varying pHs. Adsorbable organic halogen (AOX) formation due to the high chloride content of the effluent and detoxification, which was evaluated in terms of the relative toxicity index Itox determined from the ED50 values for the marine photobacteria Vibrio fischeri, were also evaluated. Highest total organic carbon (56%), chemical oxygen demand (44%), and UV254 (77%) removals were achieved at pH 7 in the presence of HCO3? alkalinity. The fastest decolorization was observed for the case pH 2, the first order decolorization rate constant found as k620 = 0.16?min?1, closely followed by the pH 12 case with soda ash (k620 = 0.12?min?1) case. No positive correlation was evident between AOX, whose maximum value (=1.3 mg/L) appeared after 40 min ozonation at pH 7 and decreased to 0.54 mg/L after 120 min treatment, and Itox, which decreased to 0.16 at t = 50?min and increased rapidly thereafter. The Itox values were more related to color abatement kinetics. The maximum relative toxicity index of Itox = 0.83 occurred after 120 min. It was also established that the presence of alkalinity in the spent reactive dye-bath had no negative impact on the oxidation rates. In contrast, its absence seriously inhibited treatment efficiency. It is speculated that, with added soda ash, the carbonate radicals HCO3? and CO3??, which are more stable and selective than OH?, were produced and promoted the oxidation process.     

Electrorheological properties of kaolinite,polyindole, and polyindole/kaolinite composite suspensions

In this study, polyindole (PIN) and polyindole/kaolinite (PIN/KAO) composite were synthesized by free radical polymerization using FeCl₃ as an initiator. Average particle sizes (d₅₀) of PIN and PIN/KAO composite were determined by dynamic light scattering (DLS) as 7.2 and 6.2 μm, respectively. The samples were characterized by FTIR, elemental analysis, DSC/TGA and SEM measurements. Suspensions of KAO, PIN, and PIN/KAO composite were prepared in silicone oil (SO) and the sedimentation stabilities were determined. Electrorheological (ER) properties of these suspensions were studied as a function of dispersed phase concentration, shear rate, shear stress, and temperature; and yield stresses and excess shear stresses determined. Further, dielectric properties of KAO, PIN, and PIN/KAO composite were investigated. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Effects of growth rate and temperature gradient on the microstructure parameters in the directionally solidified succinonitrile–7.5 wt.% carbon tetrabromide alloy

Succinonitrile (SCN)–7.5 wt.% carbon tetrabromide (CTB) alloy was unidirectionally solidified with a constant growth rate (V = 33 μm/s) at five different temperature gradients (G = 4.1–7.6 K/mm) and with a constant temperature gradient (G = 7.6 K/mm) at five different growth rates (V = 7.2–116.7 μm/s). The primary dendrite arm spacings, secondary dendrite arm spacings, dendrite tip radius and mushy zone depths were measured. Theoretical models for the microstructure parameters have been compared with the experimental observations, and a comparison of our results with the current theoretical models and previous experimental results have also been made.     

Equalization for discrete multitone transceivers to maximize bitrate

In a discrete multitone receiver, a time-domain equalizer (TEQ) reduces the intersymbol interference (ISI) by shortening the effective duration of the channel impulse response. Current TEQ design methods such as the minimum mean-squared error (MMSE), maximum shortening SNR (MSSNR), and maximum geometric SNR (MGSNR) do not directly maximize bit rate. We develop two TEQ design methods to maximize the bit rate. First, we partition an equalized multicarrier channel into its equivalent signal, noise, and ISI paths to develop a new subchannel SNR definition. Then, we derive a nonlinear function of TEQ taps that measures the bit rate, which the proposed maximum bit rate (MBR) method optimizes. We also propose a minimum-ISI method that generalizes the MSSNR method by weighting the ISI in the frequency domain to obtain higher performance. The minimum-ISI method is amenable to real-time implementation on a fixed-point digital signal processor. Based on simulations using eight different carrier-serving-area loop channels, (1) the proposed methods yield higher bit rates than MMSE, MGSNR, and MSSNR methods; (2) the proposed methods give three-tap TEQs with higher bit rates than 17-tap MMSE, MGSNR, and MSSNR TEQs; (3) the proposed MBR method achieves the channel capacity (as computed by the matched filter bound using the proposed subchannel SNR model) with a five-tap TEQ; and (4) the proposed minimum-ISI method achieves the bit rate of the optimal MBR method     

A bis-selenophene substituted alkoxy benzene derivative as a highly stable novel electrochromic polymer

Up to date there are few studies reporting the use of selenophene derivatives as electrochromic polymers. This report highlights the synthesis of a selenophene containing multi-ring aromatic polymer which possesses reasonable optical contrasts at both visible and near-IR regions. Electrochemical synthesis of a conducting polymer from a multi-ring aromatic monomer, 2-(2,5-bis(hexyloxy)-4-(selenophen-2-yl)phenyl)selenophene (BSB(OC₆H₁₃)₂), was achieved at a lower potential than its corresponding parent, selenophene. The strong absorption band for the undoped polymer was 474 nm and the onset energy for the π–π^* transition (Eg) was 1.9 eV (645 nm).A novel dual-polymer electrochromic device was constructed in sandwich configuration where poly(BSB(OC₆H₁₃)₂) was used as the anodically coloring material. It is the first electrochromic device where a selenophene-containing polymer was used as an active layer. The device switches between a rose-colored state and a blue-colored state with a fast response time (less than 1 s).     

Osteosclerosis due to endemic fluorosis

Endemic water borne fluorosis is a public health problem in Isparta, a city located in southern Turkey. In order to investigate the association between osteosclerosis and fluorosis, we retrospectively screened the results of lumbar spine and femur neck bone mineral density (BMD) of 1500 patients who were examined before, for any reason in between 2001-2003. Sixty nine patients (67 females and 2 males, mean age 52.6+/-10.2) with vertebra T-scores>or=+2 were found only except a patient with osteoid osteoma in the femur neck (femur T-score+6.64). Thirty-four of the patients could be reexamined with lateral vertebra BMD and investigated for fluorosis and the other etiologic causes of osteosclerosis. Of 34 patients, 14 had either mottled tooth enamel or urine fluoride level greater than 1.5 mg/l. Other etiologic causes were hypothyroidism (2), hypoparathyroidism (1), history of lumbar fracture (1), use of retinoids (1), vitamin D (7), oral calcium preparations (9), and bisphosphanates (3). Lateral lumbar vertebral T-score was greater than+2 in 12 patients (35.3%). Femur T-score was greater than+2 in 7 patients (20.6%). Fourteen patients (41.2%) had lateral vertebral or femur T-score>or=+2. Five (35.7%) of these patients had signs of fluorosis, as discussed before. Mean body mass index of individuals with fluorosis was 36.4+/-7.9 and this result was significantly higher than other osteosclerotic subjects (31.6+/-4.4). In conclusion we believe that approximately one third of the osteosclerosis in our region was due to endemic skeletal fluorosis and obesity may enhance this osteosclerotic type bone changes in endemic fluorosis.