Seasonal influence on sulfate reduction and zinc sequestration in subsurface treatment wetlands

To characterize the effects of season, temperature, plant species, and chemical oxygen demand (COD) loading on sulfate reduction and metals removal in treatment wetlands we measured pore water redox potentials and concentrations of sulfate, sulfide, zinc and COD in subsurface wetland microcosms. Two batch incubations of 20 day duration were conducted in each of four seasons defined by temperature and daylight duration. Four treatments were compared: unplanted controls, Typha latifolia (broadleaf cattail), and Schoenoplectus acutus (hardstem bulrush), all at low COD loading (267 mg/L), plus bulrush at high COD loading (534 mg/L). Initial SO4-S and zinc concentrations were 67 and 24 mg/L, respectively. For all treatments, sulfate removal was least in winter (4 degrees C, plant dormancy) greatest in summer (24 degrees C, active plant growth) and intermediate in spring and fall (14 degrees C), but seasonal variation was greater in cattail, and especially, bulrush treatments. Redox measurements indicated that, in winter, plant-mediated oxygen transfer inhibited activity of sulfate reducing bacteria, exacerbating the reduction in sulfate removal due to temperature. Doubling the COD load in bulrush treatments increased sulfate removal by only 20-30% when averaged over all seasons and did not alter the basic pattern of seasonal variation, despite tempering the wintertime increase in redox potential. Seasonal and treatment effects on zinc removal were broadly consistent with sulfate removal and presumably reflected zinc-sulfide precipitation. Results strongly suggest that interactive effects of COD loading rate, temperature, season, and plant species control not only sulfate reduction and zinc sequestration, but also the balance of competition between various microbial consortia responsible for water treatment in constructed wetlands.     

A Dual Luminescent Sensor Material for Simultaneous Imaging of Pressure and Temperature on Surfaces

A novel kind of composite material for simultaneous luminescent determination of air pressure and temperature is presented. The dual sensor consists of a fluorinated platinum porphyrin complex (PtTFPP) as an oxygen‐sensitive probe, and of the highly temperature‐sensitive europium complex Eu(tta)₃(dpbt) as temperature probe. Both are incorporated into different polymer microparticles to control response characteristics and to avoid interferences. Encapsulation of PtTFPP in poly(styrene‐co‐acrylonitrile) (PSAN) results in a broad dynamic range from 0.05 to 2.00 bar for pressure measurements. The europium complex was incorporated into poly(vinyl chloride) to reduce the cross sensitivity towards oxygen. This system represents a new class of luminescent sensor system, where the signals are separated via the different luminescence lifetimes of the indicators. It is possible to monitor the emission of the temperature‐sensitive probe by means of time‐resolved fluorescence imaging without interferences, because the luminescence lifetime of the temperature indicator is tenfold longer than that of the oxygen indicator. The temperature image can then be used to compensate cross sensitivity of the pressure indicator towards temperature. In combination with an appropriate time‐resolved measurement technique, this material enables simultaneous imaging of pressure (or oxygen partial pressure) and temperature distributions on surfaces. It is distinguished from other approaches of dual pressure and temperature sensitive paints because it avoids the need of signal separation by application of different cameras or by use of different optical filters or light sources.     

Schlagregensicherheit von Steildachkonstruktionen – europäische und nationale Bewertungsverfahren für den Regeneintrag in gedeckte Dächer und die Schlagregensicherheit von Unterdeck‐ und Unterspannbahnen

Resistance to driving rain of pitched roof structures ‐ German and European assessment methods for rain penetration into tiled roofs and the resistance to driving rain of covering underlays and self supporting underlays. Resistance to driving rain describes the ability of an external component to offer protection against ingress of water into the component or the building under specified wind force, rainfall and rain duration. Standardised tests already exist for assessing and classifying the resistance to driving rain of components such as windows, external doors and gates, while for covered pitched roof structures no such tests have been established as yet. This applies to the actual roof covering consisting of small‐sized roofing elements such as tiles as well as covering underlays and self supporting underlays, which are exposed to the weather during the construction phase and during alterations or refurbishment. Over recent years great efforts have been made to try and compare the resistance to driving rain of covered pitched roof structures and exposed covering underlays and self supporting underlays used as temporary roof covering.     

Interactions of human endothelial cells with gold nanoparticles of different morphologies

The interactions between noncancerous, primary endothelial cells and gold nanoparticles with different morphologies but the same ligand capping are investigated. The endothelial cells are incubated with gold nanospheres, nanorods, hollow gold spheres, and core/shell silica/gold nanocrystals, which are coated with monocarboxy (1-mercaptoundec-11-yl) hexaethylene glycol (OEG). Cell viability studies show that all types of gold particles are noncytotoxic. The number of particles taken up by the cells is estimated using inductively coupled plasma (ICP), and are found to differ depending on particle morphology. The above results are discussed with respect to heating efficiency. Using experimental data reported earlier and theoretical model calculations which take into account the physical properties and distribution of particles in the cellular microenvironment, it is found that collective heating effects of several cells loaded with nanoparticles must be included to explain the observed viability of the endothelial cells.     

Mechanical behavior of a cellular composite under quasi-static, static, and cyclic compression loading

The quasi-static, static, and cyclic compressive behavior of a novel epoxy matrix cellular composite reinforced with glass foam granules is investigated. Three different grain-size fractions of the granules are used: 0.5–1, 1–2, and 2–4 mm. The density of the cellular composite varies between 0.65 and 0.82 g/cm3. The material exhibits high specific compressive strength and stiffness within the class of cellular materials; these properties can be varied using appropriate size of granules. The glass foam granules increase the stiffness of the cellular composite compared to neat epoxy foam with the same weight. The measured elastic properties are in good agreement with results obtained from analytical and numerical homogenization methods. The fatigue behavior is determined in static tests and in cyclic tests at 1 and 20 Hz on one type of cellular composite. The fatigue process for cyclic loading is a result of an interaction between static and cyclic damage. The sensitivity to static damage is found to be higher than to cyclic damage. The damage behavior is investigated by evaluation specimen’s stiffness and using scanning electron microscopy.     

On the effect of grain boundary segregation on creep and creep rupture

The present work investigates the effect of grain boundary chemistry and crystallography on creep and on creep damage accumulation in Cu–0.008 wt.% Bi and Cu–0.92 wt.% Sb at stresses ranging from 10 to 20 MPa and temperatures between 773 and 873 K. Small additions of Bi and Sb significantly reduce the rupture strain and rupture time during creep of Cu. High stress exponents (Cu–Bi) and high apparent activation energies for creep (Cu–Bi and Cu–Sb) are obtained. Sb promotes creep cavitation on random high-angle grain boundaries. Bi, on the other hand, causes brittle failure when small crack-like cavities cause decohesion. Both elements suppress dynamic recrystallization, which occurs during creep of Cu at high stresses and temperatures.     

Two-phase porous silica: Mesopores inside controlled pore glasses

The structural and textural properties of Two-Phase Porous Silica consisting of a mesoporous pore system formed by finely dispersed silica-gel inside the original pores of a macroporous glass framework have been carefully investigated. Nitrogen adsorption at 77 K, Mercury Intrusion, Small Angle X-ray Scattering (SAXS), Temperature-Programmed Desorption (TPD) of ammonia and ²⁷Al MAS NMR spectroscopy were used. Different mesoporous glasses investigated show BET surface areas up to 300 m²/g, a total pore volume of about 0.16 cm³/g and pore sizes of <2–10 nm, depending on the acid leaching conditions of the phase-separated sodium borosilicate initial glass. The texture of the macroporous frame glass was characterized after removing the mesoporous finely dispersed silica-gel phase with alkaline solution. Leaching of the phase-separated initial glass with Al(NO₃)₃ solution and followed by thermal treatment lead to the formation of Brönsted acid sites at the surface of the resulting mesoporous glasses by an incorporation of aluminium in tetrahedral coordination in the silica framework.     

Vergleichende Brandversuche an ungetränkten und mit Feuerschutzmittel getränkten Hölzern

European Journal of Wood and Wood Products -     

Strom-Spannungsspitzen und thermische Belastung der Schaltstücke beim Ein- und Zuschalten von Kondensatoren

Ohne ZusammenfassungMit 11 Textabbildungen