Crystallization kinetics by differential scanning calorimetry for PCL/starch and their reinforced sisal fiber composites

Calorimetric results obtained by differential scanning calorimetry (DSC) have been used to develop a kinetic model for the crystallization behavior of PCL/starch and their composites with sisal fibers. The model takes into account the effects of nucleation and crystal growth, and it is able to describe the isothermal and non‐isothermal conditions, especially for the low cooling rates. The effect of the sisal fiber has also been analyzed. The Avrami exponent was 2.0 for the crystallization of PCL/starch and sisal fiber reinforced composite. The activation energy of the crystallization process was 4.3 and 4.0 kJ/mol for PCL/starch and sisal composite, respectively. The induction time of the crystallization and the crystallization rate was not influenced by the presence of sisal fiber.     

Isolation of Non-methylene Interrupted or Acetylenic Fatty Acids from Seed Oils Using Semi-preparative Supercritical Chromatography

Preparative scale supercritical fluid chromatography was used for isolating and purifying uncommon non-methylene interrupted or acetylenic polyunsaturated fatty acids ethyl esters from seed oils. Fractionation of Biota orientalis seed oil ethyl esters was performed by supercritical fluid chromatography to obtain juniperonic acid [(5Z,11Z,14Z,17Z)-eicosa-5,11,14,17-tetraenoic acid], a non-methylene interrupted polyunsaturated fatty acid. Fractionation of sandalwood seed oil ethyl esters yielded ximenynic acid [(E)-octadec-11-en-9-ynoic acid], an acetylenic polyunsaturated fatty acid. The effects of CO₂ flow rate, column stationary phase and particle size were explored to optimize ximenynic and juniperonic ethyl ester recovery and purity from ethyl ester mixtures using online UV/Vis detection. Particle size, followed by the stationary phase, were found to be the most important parameters to achieving good separation. Under optimized conditions, ximenynic and juniperonic ethyl ester purities greater than 99 and 95%, respectively, were achieved in a one step process without co-solvent. The isolation and recovery of juniperonic acid from biota seed oil free fatty acids was also attempted. Using free fatty acids as the feed material, the non-methylene interrupted polyunsaturated sciadonic acid was also able to be separated from other compounds including juniperonic acid under some conditions, and gave an increase in concentration of more than 17 times.     

The effect of stocking density during 4 hour transport to slaughter on behaviour, blood constituents and carcass bruising in Friesian steers

The aim of this work was to assess the response of Friesian steers to road transportation at low, medium and high (ca 200, 300 and 600 kg/m(2)) stocking densities in terms of physiology, behaviour and carcass bruising. Stocking density was determined by adjusting the number of animals per pen (3 runs) or by adjusting pen size (3 runs). Plasma cortisol and glucose increased (P < 0·001) with stocking density, as did plasma CK activity (P < 0·001) and carcass bruising (P < 0·01) both of which indicate muscle damage. At constant stocking density stress increased with pen location towards the tail of the truck, as reflected by a significant increase in plasma cortisol. Stocking density influenced standing orientation within the truck. At low stocking density animal movement was unrestricted and the preferred orientation was standing parallel to the direction of travel; there was a strong bias against diagonal orientations. Losses of balance were associated with specific driving events, notably braking and cornering. Minor losses of balance were observed at all stocking densities, but major losses of balance including animals going down underfoot were associated with high density. When an animal went down at high stocking density it did so involuntarily and was sometimes trapped down, destabilizing other members of the group in a domino effect. Exploratory, sexual and aggressive behaviours were inhibited at high stocking density, with the exception of mounting and pushing, which increased in frequency with stocking density. It was concluded that the high stocking density adversely affected animal welfare and lowered carcass quality when compared with the medium and low stocking densities.     

Numerical study on thermal impacts of different void patterns on performance of chip-scale packaged power device

Chip scale package (CSP) technology offers promising solutions to package power device due to its relatively good thermal performance among other factors. Solder thermal interface materials (STIMs) are often employed at the die bond layer of a chip-scale packaged power device to enhance heat transfer from the chip to the heat spreader. Nonetheless, the presence of voids in the solder die-attach layer impedes heat flow and could lead to an increase in the peak temperature of the chip. Such voids which form easily in the solder joint during reflow soldering process at manufacturing stage are primarily occasioned by out-gassing phenomenon and defective metallisation. Apparently, the thermal consequences of voids have been extensively studied, but not much information exist on precise effects of different patterns of solder die-attach voids on the thermal performance of chip-level packaged power device. In this study, three-dimensional finite element analysis (FEA) is employed to investigate such effects. Numerical studies were carried out to characterise the thermal impacts of various voids configurations, voids depth and voids location on package thermal resistance and chip junction temperature. The results show that for equivalent voiding percentage, thermal resistance increases more for large coalesced void type in comparison to the small distributed voids configuration. In addition, the study suggests that void extending through the entire thickness of solder layer and voids formed very close to the heat generating area of the chip can significantly increase package thermal resistance and chip junction temperature. The findings of this study indicate that void configurations, void depth and void location are vital parameters in evaluating the thermal effects of voids.     

Emotion dysregulation in the intergenerational transmission of romantic relationship conflict.

The role of emotion dysregulation in the intergenerational transmission of romantic relationship conflict was examined using multimethod and multiagent prospective longitudinal data across 21 years for 190 men and their mothers and fathers. As predicted, an individual’s emotion dysregulation was a key mediator in the transmission of relationship conflict, along with poor parenting skills. Parents’ emotion dysregulation was directly related to their son’s emotion dysregulation, which was in turn associated with the son’s later relationship conflict. Additionally, parents’ emotion dysregulation was significantly related to their poor discipline skills, which were linked to the son’s emotion dysregulation and eventual relationship conflict. Findings highlight emotion dysregulation as a significant mechanism explaining the continuity of romantic relationship conflict across generations. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

设计灵感就在你的脑中

设计工程是一个以客户为中心的行业,其中新标准由终端客户的需求驱动.当演变到为电子工程设计和制造元器件时,它就再也不是"一种产品适合所有应用"的模式了.这就在国际上引发了一场工程师们观念上的革命.尽管在过去功能、成本控制和效率是工程师主要的着眼点,而现在一个元器件的外表形状正获得更高的关注度.     

MEMS振荡器与石英技术

严格根据应用情况选择合适类型 从简单的精度约30 000ppm的R C振荡器,到精度优于0.001ppb的原子钟,有很多满足不同应用要求的时钟选项.多年以来,体声波(BAW)晶体振荡器可用以满足大多数要求,它提供的精度在10ppm范围内.精度低一些的选择,如SAW振荡器、陶瓷振荡器以及IC振荡器,它们各自具有其满足特定需求的优势.     

Predictors of high-risk alcohol consumption in young offenders on community orders: Policy and treatment implications.

The present study examined the relationship between a set of individual and contextual variables and high-risk alcohol use among young offenders placed on community orders in New South Wales, Australia. Participants (n = 777) were compared on a set of factors known to be strong predictors of high-risk alcohol use among adolescents. The authors assessed the strength of the relationship between gender, age, ethnicity, geographical region of residence, school attendance, father absence, history of childhood trauma, and the presence of severe conduct disorder on weekly levels of alcohol use. Living in rural locations, not currently attending school, being female, and not having been raised with a biological father present were associated with significantly increased odds of alcohol abuse. Father absence was a more important risk factor for rural young offenders, but school dropout was associated with more hazardous drinking among young offenders in urban areas. Accordingly, the authors suggest family-focused intervention programs for young offenders living in rural areas and school-based programs for vulnerable young people living in urban areas, although programs should consider including both factors for both groups if feasible and warranted. (PsycINFO Database Record (c) 2010 APA, all rights reserved)