Occurrence patterns of alien freshwater turtles in a large urban pond ‘Archipelago’ (Rome,Italy): Suggesting hypotheses on root causes

The patterns of the occurrence and distribution of alien freshwater turtle species in an urban pond archipelago (Rome, Italy) were analysed, with the aim of exploring the role of a set of factors (type of ponds, landscape context, size area, distance from the nearest road) with a generalized linear model approach. A total of 311 ponds subdivided in three types (fountains, small basins, lakes) embedded in different landscape contexts (public parks, private parks, urban areas) at differing distances from the nearest road were sampled. Six non‐native freshwater turtle species in 31 sites were recorded (9.97%). Lakes exhibited the highest occurrence rates of alien freshwater turtles, compared to small basins and fountains. Freshwater turtle species in urbanized areas were only observed in parks (both public and private). In both the public and private parks, the lakes exhibited the highest percentage of occupied sites, with fountains being the lowest. A direct and significant relationship was observed between pond size and species richness. The distance from the nearest road did not appear to affect species richness. A first interpretation of the data from this study facilitated the postulation of two a posteriori hypotheses that should be tested, as follows: (i) the causal process of turtle release is random, and the rate of extinction (and recapture) is higher in smaller ponds, thus producing the observed pattern; and (ii) the turtle release is not random, and people actively select the ponds they consider more suitable for their pet animals. In this study, it appears the lakes were perceived by those who abandon their pets as the most ecologically suitable habitats among other pond types to accommodate the different species of turtles. Knowledge of people's attitudes in regard to releasing pet animals also might assist managers of public green spaces to develop strategies aimed to preserve local biodiversity, and to educate the public about the conservation issue represented by the alien species.     

Synthesis and characterization of polyurea microcapsules containing essential oils with antigerminative activity

In this paper we report on the preparation and characterization of polyurea‐based microencapsulated systems, containing essential oils as core materials, for potential applications in controlled‐release formulations of agrochemicals. Microcapsules were synthesized by interfacial polymerization in o/w emulsion between polyfunctional isocyanates and diamines, to investigate the effect of the monomer kind on the morphology and properties of the produced samples. The synthetic conditions that gave the best results were used to microencapsulate four essential oils, able to interfere with the seed germination and radicle elongation of some test plants. The produced samples were characterized, with the aim to analyze their morphology and to verify the effectiveness of essential oil microencapsulation. Moreover, preliminary bioassay based on seed germination and subsequent radical growth were carried out to study the effects of the microencapsulated essential oils. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Surface properties of fluorinated hybrid coatings

A commercial perfluoropolyether containing alkoxysilane functionalities was employed to prepare organic–inorganic hybrid coatings by using the sol‐gel process in the presence of tetraethoxysilane. Contact angle analysis revealed a strong hydrophobic and oleophobic character of the coatings almost independently from the molecular weight of the starting fluorinated oligomer. Surface tension values were in the range of 14–16 mN/m, suggesting a preferential segregation of fluorinated segments onto the surface of the coating. Atomic force microscopy showed the presence very smooth surfaces permitting to neglect the contribution of the surface roughness to wettability. Friction coefficient values were markedly lower with respect to the value of uncoated glass substrate. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1483–1488, 2006     

Kinetic modeling of pentachlorophenol adsorption from aqueous solution on activated carbon fibers

The adsorption equilibrium data of pentachlorophenol (PCP) onto activated carbon fiber (ACF) in felt form were obtained in a batch adsorber at T = 25 °C and pH 12 and the Langmuir isotherm fitted reasonably well with the experimental data. The rate of adsorption of PCP on ACF was investigated in this work and the experimental concentration decay data were obtained in a differential column batch adsorber. The overall rate of adsorption of PCP was interpreted by a diffusional model that takes into account the external mass transport and intrafiber diffusion. The experimental concentration decay can be described quite well with the diffusional model if the overall rate of adsorption is mainly controlled by intrafiber diffusion and the external mass transport is not important to the overall rate of adsorption. Moreover, intrafiber diffusion was significantly affected by restricted diffusion since the molecular diameter of the PCP was closed to 55% of the average pore diameter. The effect of restricted diffusion was estimated using correlations reported in the literature. The molecules of PCP adsorbed on the surface of the pore also hindered the diffusion of PCP molecules inside the pores.     

An ensemble evolutionary constraint-based approach to understand the emergence of metabolic phenotypes

Constraint-based modeling is largely used in computational studies of metabolism. We propose here a novel approach that aims to identify ensembles of flux distributions that comply with one or more target phenotype(s). The methodology has been tested on a small-scale model of yeast energy metabolism. The target phenotypes describe the differential pattern of ethanol production and O₂ consumption observed in “Crabtree-positive” and “Crabtree-negative” yeasts in changing environment (i.e., when the upper limit of glucose uptake is varied). The ensembles were obtained either by selection among sampled flux distributions or by means of a search heuristic (genetic algorithm). The former approach provided indication about the probability to observe a given phenotype, but the resulting ensembles could not be unambiguously partitioned into “Crabtree-positive” and “Crabtree-negative” clusters. On the contrary well-separated clusters were obtained with the latter method. The cluster analysis further allowed identification of distinct groups within each target phenotype. The method may thus prove useful in characterizing the design principles underlying metabolic plasticity arising from evolving physio-pathological or developmental constraints.     

Reaction sintering of Fe-Al-Si alloys

The present study concerns the production of multiphase alloys of the Fe-Al-Si system using a powder metallurgical approach. Several compositions have been considered based on α-Fe, α′-FeAl; and α″-Fe₃Al intermetallic phases. Elemental powder mixtures were compacted and sintered in a dilatometer. In this way, the dimensional changes involved with thermally induced transformations could be followed during continuous heating runs up to the sintering temperature. The effect of heating rate has been considered. The characterization of the final products was based mainly on x-ray diffraction (XRD) analyses, particularly as concerns the quantification of the crystalline phases present in the final products. Grain and porosity morphologies were characterized by scanning electron microscopy (SEM). In this way, clear indications of the reaction and densification processes occurring during the sintering treatments were obtained.     

A new thermomechanical model of cutting applied to turning operations. Part I. Theory

In this paper, an analytical approach is used to model the thermomechanical process of chip formation in a turning operation. In order to study the effects of the cutting edge geometry, it is important to analyse its global and local effects such as the chip flow direction, the cutting forces and the temperature distribution at the rake face. To take into account the real cutting edge geometry, the engaged part in cutting of the rounded nose is decomposed into a set of cutting edge elements. Thus each elementary chip produced by a straight cutting edge element, is obtained from an oblique cutting process. The fact that the local chip flow is imposed by the global chip movement is accounted for by considering appropriate interactions between adjacent chip elements. Consequently, a modified version of the oblique cutting model of Moufki et al. [Int. J. Mech. Sci. 42 (2000) 1205; Int. J. Mach. Tools Manufact. 44 (9) (2004) 971] is developed and applied to each cutting edge element in order to obtain the cutting forces and the temperature distributions along the rake face. The material characteristics such as strain rate sensitivity, strain hardening and thermal softening, the thermomechanical coupling and the inertia effects are taken into account in the modelling. The model can be used to predict the cutting forces, the global chip flow direction, the surface contact between chip and tool and the temperature distribution at the rake face which affects strongly the tool wear. Part II of this work consists in a parametric study where the effects of cutting conditions, cutting edge geometry, and friction at the tool–chip interface are investigated. The tendencies predicted by the model are also compared qualitatively with the experimental trends founded in the literature.     

A new thermomechanical model of cutting applied to turning operations. Part II. Parametric study

In Part I of this work, Molinari and Moufki [Int. J. Mach. Tools Manufact., this issue], an analytical model of three-dimensional cutting is developed for turning processes. To analyse the influences of cutting edge geometry on the chip formation process, global effects such as the chip flow direction and the cutting forces, and local effects such as the temperature distribution and the surface contact at the rake face have been investigated. In order to accede to local parameters, the engaged part in cutting of the rounded nose is decomposed into a set of cutting edge elements. Thus each elementary chip, produced by a straight cutting edge element, is obtained from an oblique cutting process defined by the corresponding undeformed chip section and the local cutting angles. The present approach takes into account the fact that for each cutting edge element the local chip flow is imposed by the global chip movement. The material characteristics such as strain rate sensitivity, strain hardening and thermal softening, the thermomechanical coupling and the inertia effects are considered in the modelling. A detailed parametric study is provided in this paper in order to analyse the effects of cutting speed, depth of cut, feed, nose radius and cutting angles on cutting forces, global chip flow direction and temperature distribution at the rake face. The influence of friction at the tool–chip interface is also discussed.     

Introduction: In-Use,In-Situ: Extending Field Research Methods—Part 2

This study used protocol analyses and user drawings of their models of the system to investigate the “getting lost” problem in hypertext navigation. The “getting lost” problem is viewed as occurring when routine expectations of naive users, concerning appropriate linear sequences, are violated. Several ways in which users persistently attempt to work within a linear model, despite its inapplicability, are examined. The transition to more hierarchical user models is described.     

Fault detection for discrete event systems using Petri nets with unobservable transitions

In this paper we present a fault detection approach for discrete event systems using Petri nets. We assume that some of the transitions of the net are unobservable, including all those transitions that model faulty behaviors. Our diagnosis approach is based on the notions of basis marking and justification, that allow us to characterize the set of markings that are consistent with the actual observation, and the set of unobservable transitions whose firing enable it. This approach applies to all net systems whose unobservable subnet is acyclic. If the net system is also bounded the proposed approach may be significantly simplified by moving the most burdensome part of the procedure off-line, thanks to the construction of a graph, called the basis reachability graph.