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61.
The phenomenon of spontaneous bubble nucleation in extremely supersaturated (superheated) polymer–solvent systems has been studied experimentally. Spontaneous boiling-up temperatures T* for polystyrene and poly(ethylene glycol) solutions in a number of solvents have been measured at different values of pressure p and weight fraction of polymer c by the pulse heating method. The heating rate Ṫ varied from 105 to 107 K/s. For all systems studied, the values of T* have been found to increase with increasing p and c. The T*(p, c) dependence is discussed with the use of the data on the degree of compatibility of components. The peculiarities of polymeric solutions manifest themselves in the region c → 1, as follows: (i) an abrupt increase (by 1–2 orders of magnitude) in the slope of the T*(c) dependence, and (ii) the appearance of the dependence of T* values on the heating rate. Our approach to the interpretation of this result assumes a change in the initial composition of a solution in the course of heating due to polymer decomposition. An example of the extended phase diagram of a polymer–solvent system including the kinetic surface of T*(p, c) is given. © 1996 John Wiley & Sons, Inc. 相似文献
62.
This article presents an effective analytical model for determining the moisture diffusivities and moisture transfer coefficients for solid objects (namely, infinite slab, infinite cylinder, sphere; and also for irregularly shaped objects, by using a shape factor) subject to drying applications in a medium. The unsteady-state moisture diffusion analysis is used on the basis of two important criteria: 0·1 <Bi < 100 and Bi > 100. The drying coefficients and lag factors were employed. The analytical models are then verified using available experimental data taken from the literature. The results show that the method presented here can be used to determine the moisture diffusion coefficients and moisture transfer coefficients for such solid objects in a simple and accurate manner for a variety of drying applications. 相似文献
63.
Libor Uttl Tom Hloek Pavel Mare Tom Plení
ek Hana Kubov 《International journal of molecular sciences》2022,23(1)
In spite of use of cannabidiol (CBD), a non-psychoactive cannabinoid, in pediatric patients with epilepsy, preclinical studies on its effects in immature animals are very limited. In the present study we investigated anti-seizure activity of CBD (10 and 60 mg/kg administered intraperitoneally) in two models of chemically induced seizures in infantile (12-days old) rats. Seizures were induced either with pentylenetetrazol (PTZ) or N-methyl-D-aspartate (NMDA). In parallel, brain and plasma levels of CBD and possible motor adverse effects were assessed in the righting reflex and the bar holding tests. CBD was ineffective against NMDA-induced seizures, but in a dose 60 mg/kg abolished the tonic phase of PTZ-induced generalized seizures. Plasma and brain levels of CBD were determined up to 24 h after administration. Peak CBD levels in the brain (996 ± 128 and 5689 ± 150 ng/g after the 10- and 60-mg/kg doses, respectively) were reached 1–2 h after administration and were still detectable 24 h later (120 ± 12 and 904 ± 63 ng/g, respectively). None of the doses negatively affected motor performance within 1 h after administration, but CBD in both doses blocked improvement in the bar holding test with repeated exposure to this task. Taken together, anti-seizure activity of CBD in infantile animals is dose and model dependent, and at therapeutic doses CBD does not cause motor impairment. The potential risk of CBD for motor learning seen in repeated motor tests has to be further examined. 相似文献
64.
Seung Min Lee Benjamin P. McCarthy Pavel Hrma Jaehun Chun Richard Pokorny Jaroslav Klouzek Albert A. Kruger 《Journal of the American Ceramic Society》2020,103(3):1615-1630
During the final stages of conversion of melter feed (glass batch) to molten glass, the glass-forming melt becomes a continuous liquid phase that encapsulates dissolving solid particles and gas bubbles that produce primary foam at the bottom of the cold cap (the reacting melter feed in an electric glass-melting furnace). The glass-forming melt viscosity plays a dominant role in primary foam formation, stability, and eventual collapse, thus affecting the rate of melting (the glass production rate per cold-cap area). We have traced the glass-forming melt viscosity during the final stages of feed-to-glass conversion as it changes in response to changing temperature and composition (resulting from dissolving solid particles). For this study, we used high-level waste melter feeds—taking advantage of the large amount of data available to us—and a variety of experimental techniques (feed expansion test, evolved gas analysis, thermogravimetric analyzer-differential scanning calorimetry, X-ray diffraction, and viscometer). Starting with a relatively low value at the moment when the melt connects, melt viscosity reached maximum within the primary foam layer and then decreased to its final melter operating temperature value. At the cold-cap bottom—the boundary between the primary foam layer and the thermal boundary layer—where physicochemical reactions of a melter feed influence the driving force of the heat transfer from the melt to the cold cap, the melt viscosity affects the rate of melting predominantly through its effect on the temperature at which primary foam is collapsing. 相似文献
65.
Pavel P. Fedorov Vera Y. Proydakova Sergey V. Kuznetsov Valery V. Voronov Alexandr A. Pynenkov Konstantin N. Nishchev 《Journal of the American Ceramic Society》2020,103(5):3390-3400
The thermal analysis and X-ray powder diffraction studies of the Li2SO4–Na2SO4 system, including the high-temperature X-ray diffraction technique, have elucidated four phases of variable composition: three solid solutions based on the α-Li2SO4, α-Na2SO4, and α-LiNaSO4 high-temperature polymorphs, and a low-temperature β-LiNaSO4 phase. α-Na2SO4-Base solid solution disintegrates into two phases via a monotectoid phase transformation. It is quite probable that the monotectoid process is related to the conversion of the second-order phase transition to the first-order phase transition. 相似文献
66.
Chitosan-based fiber-sponge materials as a promising tool for microalgae harvesting from Lake Baikal
Timofei E. Grigoriev Ksenia I. Lukanina Pavel M. Gotovtsev Kirill V. Gorin Anna A. Melnikova Christina G. Antipova Roman Kamyshinsky Sergei N. Chvalun 《应用聚合物科学杂志》2020,137(40):49209
Mass eutrophication of microalgae and cyanobacteria is observed in Lake Baikal in the past decade. In this paper, the concept of replaceable adsorption filter material based on chitosan flocculant filler and chlorinated polyvinyl chloride polymer nonwoven material are proposed. Functional and mechanical properties and morphology of the material are investigated depending on a packing density and a degree of chitosan filling. The introduction of 45% chitosan increases the Young's modulus up to 10 times, and it makes the material more rigid in 2.8 times. The high efficiency of sorption and growth inhibition of cumulative biomass culture was shown. The biomass source is taken from the coast of Barguzinsky Bay of Lake Baikal. Dominant species is microalgae of Scenedesmus genus. 相似文献
67.
A sensitive and rapid method for the quantitative detection of bovine-, ovine-, swine-, and chicken-specific mitochondrial DNA sequences based on real-time PCR has been developed. The specificity of the primers and probes for real-time PCR has been tested using DNA samples of other vertebrate species that may also be present in rendered products. The quantitative detection was performed with dual-labeled probes (TaqMan) using absolute quantification with external standards of single species meat-and-bone meals. This method facilitates the detection of 0.01% of the target species-derived material in concentrate feed mixtures and fish meals. 相似文献
68.
Rapid fabrication of poly(ε‐caprolactone) nanofibers using needleless alternating current electrospinning
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Caitlin Lawson Andrei Stanishevsky Manikandan Sivan Pavel Pokorny David Lukáš 《应用聚合物科学杂志》2016,133(13)
Poly(ε‐caprolactone) ( PCL) biopolymer nanofibers and micro‐fibers have been fabricated for the first time at the rates up to 14.0 g per hour using a needleless and collectorless alternating current electrospinning technique. By combining the ac‐voltage, “green” low toxicity glacial acetic acid (AA) as the solvent and sodium acetate (NaAc) as an additive, beadless PCL fibers with diameters tunable from 150 nm to 2000 nm, varying surface morphology and degree of self‐bundling are obtained. In this new approach, the addition of NaAc plays a crucial role in improving the spinnability of PCL solution and fiber morphology. NaAc reveals the concentration‐dependent effect on charge transfer and rheological properties of the PCL/AA precursor, which results in broader ranges of spinnable PCL concentrations and ac‐voltages suitable for rapid manufacturing of PCL‐based fibers. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43232. 相似文献
69.
A diffusion couple of an oxidized molybdenum disk and a glass cylinder was used to measure the solubiiity and effective binary diffusion coefficient of MoO2 in a non-alkali aluminosilicate glass. At 1400°C, the solubility limit was 8.4 mol%; the value of the diffusion coefficient (4.1 × 10−16 m2 /s) was significantly lower than that estimated from the Stokes-Einstein relation. 相似文献
70.
Dmitry D. Zaitsev Ekaterina A. Gravchikova Pavel E. Kazin Yury D. Tretyakov Martin Jansen 《International Journal of Applied Ceramic Technology》2006,3(4):279-283
Glass samples with nominal compositions SrFe12 O19 +(12− n )SrB2 O4 +nSrSiO3 , n =3, 6, 9 were prepared by rapid quenching of the melt. Processes of glass devitrification were studied. The samples were annealed at temperatures of 600–900°C, and the resulting glass–ceramics was characterized by XRD, SEM, EDX, and magnetic measurements. SrFe12 O19 crystallizes above 700°C and forms nano- and submicron platelet particles with the aspect ratio depending on the thermal treatment conditions. The glass–ceramic samples annealed at 900°C show coercive force values in the range of 422–455 kA/m. 相似文献