Applying chemical engineering concepts to non-thermal plasma reactors

Process scale-up remains a considerable challenge for environmental applications of non-thermal plasmas.Undersanding the impact of reactor hydrodynamics in the performance of the process is a key step to overcome this challenge.In this work,we apply chemical engineering concepts to analyse the impact that different non-thermal plasma reactor configurations and regimes,such as laminar or plug flow,may have on the reactor performance.We do this in the particular context of the removal of pollutants by non-thermal plasmas,for which a simplified model is available.We generalise this model to different reactor configurations and,under certain hypotheses,we show that a reactor in the laminar regime may have a behaviour significantly different from one in the plug flow regime,often assumed in the non-thermal plasma literature.On the other hand,we show that a packed-bed reactor behaves very similarly to one in the plug flow regime.Beyond those results,the reader will find in this work a quick introduction to chemical reaction engineering concepts.     

Retrofit of RC hollow piers with CFRP sheets

Hollow bridge piers, particularly those built before the seventies, often have insufficient shear capacity due to inadequate transverse reinforcement details. Therefore, special attention must be given to this very important aspect when reinforced concrete (RC) piers with hollow sections are analysed and retrofitted. This paper covers the experimental analysis of retrofit solutions using CFRP sheets along the piers’ entire height to prevent shear failure. Experimental cyclic tests were carried out to evaluate the shear retrofit strategy efficiency on a set of RC piers with square hollow sections. This work also covers the study of design procedures for CFRP shear retrofitting and the evaluation of the associated ductility capacity improvement. The various transverse reinforcement detailing scenarios were assessed to determine their shear-failure prevention efficiency. The corresponding cyclic response behavior was also evaluated. The most relevant experimental information is presented in the paper, such as the evolution of the outer damage pattern. Finally, shear retrofit solutions, with a 40% increase over the maximum flexural force, show that this strategy is adequate to allow satisfactory ductility behavior.     

An application framework for developing collaborative handheld decision-making tools

This paper describes an application framework supporting collaborative handheld decision-making (CHDM). The main characteristics of the framework are: (1) extensive usage of visual elements and gestures; and (2) independence from specific decision-making methods, processes and tasks. The research departed from the analysis and systematisation of several CHDM scenarios, highlighting repeatable behaviour across multiple decision-making contexts. From these scenarios, we distilled a coherent set of common functional requirements organised in three main categories: process, macro- and micro-functionality. The proposed framework has been validated at length through the development of several CHDM tools. Six different tools are described in the paper. The main contribution of this work is a common foundation for developing CHDM tools.     

Data‐driven bounded‐error fault detection

In this paper, a new data‐driven fault‐detection method is proposed. This method is based on a new nonparametric system identification approach, which constitutes the principal contribution to this work. The fault‐detection method is a parametric model‐free approach that can be applied to nonlinear systems that work at various operating points. Not only can the fault‐detection process be applied to the steady state of each operating point, but it can also be applied to the transient state resulting from a change in the operating point. In order to detect faults, the proposed method uses an interval predictor based on bounded‐error techniques. The utilization of techniques based on bounded error enables system uncertainties to be included in an explicit way. This in turn leads to the possibility of obtaining interval predictions of the behaviour of the system, which include information on the reliability of the prediction itself. In order to show the effectiveness of the fault‐detection method, two examples are presented: in the form of a simulated process (counter‐flow shell‐and‐tube heat‐exchanger system) and an example of a real application (two‐tanks system). A comparison with two fault‐detection methods has also been included. Copyright © 2013 John Wiley & Sons, Ltd.     

Synthesis and characterization of Cu-doped polymeric carbon nitride

Polymeric carbon nitride doped with copper through a solid-state reaction was characterized by several techniques, among them are UV-visible spectroscopy, infrared spectroscopy, X-ray photoelectron spectroscopy, etc. The material is a semiconductor with a wide band gap of 2.74 eV. Sites of both Cu(I) and Cu(II) were detected, apparently only coordinated by the polymer. The material comprises crumpled nanosheets, and is substantially an amorphous layered material with a prevalent 2D structure with low inter-planar interactions, as shown by X-ray diffractometry and TeraHertz spectroscopy. Photo-oxidation of benzyl alcohol was used to probe the active sites of the material, comparing them with the non-doped material. The higher activity and selectivity toward salicylic alcohol of the non-doped material can be due to both a more localized electron transfer and a longer lifetime of the hole–electron pair. Cu-CN favored the oxidation of hydroxymethyl group. Therefore, the presence of copper can favor different reaction pathways with respect to the non-doped material.