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991.
Is there a direct relationship between oral astringency and human salivary protein binding? 总被引:1,自引:0,他引:1
For decades, it is believed that astringency is due to the polyphenol-induced complexation of proline-rich salivary proteins
in the oral cavity. In order to compare for the first time the human sensory threshold concentrations and the salivary protein
binding activity of a series of astringent stimuli, human saliva protein was incubated for 5 min at 37 °C in the presence
of astringent food-derived compounds and, after micro-centrifugation, the amount of the target molecules in the supernatant
was quantitatively determined by HPLC-UV/Vis. Significant protein binding was observed for (−)-epigallocatechin-3-gallate,
(−)-gallocatechin-3-gallate, (+)-gallocatechin, and (−)-catechin-3-gallate, all of which containing at least one galloyl moiety
in the molecule and exhibiting rather high sensory thresholds of more than 200 μmol/L. In comparison, (+)-catechin and procyanidin
B2, both lacking in any galloyl function, showed only comparatively low binding activity and, most interestingly, quercetin-3-O-α-l-rhamnopyranosyl-(1 → 6)-β-d-glucopyranoside and 3-carboxymethyl-indole-1-N-β-d-glucopyranoside did not show any protein binding at all, although the later N- and O-glycosides exhibited extraordinarily low sensory threshold concentrations of less than 0.001 and 0.0003 μmol/L, respectively.
The data give some first evidence that the quantity of the non-bound, “free” astringent stimulus in the saliva liquid might
be more closely related to the sensory perception of astringency than the amount complexed or precipitated by proteins. It
is therefore questionable as to whether oral perception of astringency is related to the complexation and/or precipitation
of salivary proteins. 相似文献
992.
This paper presents an investigation on a single-mode-multimode-single-mode fiber structure. A one-way guided-mode propagation analysis for the circular symmetry waveguide is employed to model the light propagation and the approximated formulations are derived and evaluated concerning the accuracy. Phase conjunction of the multimode interference within the fiber structure is revealed. A simple way to predict and analyze the spectral response of the structure is presented through the space to wavelength mapping with the derived approximated formulations. The prediction of spectral response is verified numerically and experimentally. 相似文献
993.
Ricardo Beristain‐Cardoso Anne‐Claire Texier Reyes Sierra‐Álvarez Jim A Field Elías Razo‐Flores Jorge Gómez 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(9):1197-1203
BACKGROUND: Simultaneous removal of sulfur, nitrogen and carbon compounds from wastewaters is a commercially important biological process. The objective was to evaluate the influence of the CH3COO?/NO3? molar ratio on the sulfide oxidation process using an inverse fluidized bed reactor (IFBR). RESULTS: Three molar ratios of CH3COO?/NO3? (0.85, 0.72 and 0.62) with a constant S2?/NO3? molar ratio of 0.13 were evaluated. At a CH3COO?/NO3? molar ratio of 0.85, the nitrate, acetate and sulfide removal efficiencies were approximately 100%. The N2 yield (g N2 g?1 NO3?‐N consumed) was 0.81. Acetate was mineralized, resulting in a yield of 0.65 g inorganic‐C g?1 CH3COO?‐C consumed. Sulfide was partially oxidized to S0, and 71% of the S2? consumed was recovered as elemental sulfur by a settler installed in the IFBR. At a CH3COO?/NO3? molar ratio of 0.72, the efficiencies of nitrate, acetate and sulfide consumption were of 100%, with N2 and inorganic‐C yields of 0.84 and 0.69, respectively. The sulfide was recovered as sulfate instead of S0, with a yield of 0.92 g SO42?‐S g?1 S2? consumed. CONCLUSIONS: The CH3COO?/NO3? molar ratio was shown to be an important parameter that can be used to control the fate of sulfide oxidation to either S0 or sulfate. In this study, the potential of denitrification for the simultaneous removal of organic matter, sulfide and nitrate from wastewaters was demonstrated, obtaining CO2, S0 and N2 as the major end products. Copyright © 2008 Society of Chemical Industry 相似文献
994.
Jatuporn Wittayakun Pongtanawat Khemthong Sanchai Prayoonpokarach 《Korean Journal of Chemical Engineering》2008,25(4):861-864
Rice husk silica (RHS) in amorphous phase with 98% purity was prepared from a waste rice husk from rice milling by leaching
with hydrochloric acid and calcination. The RHS was used effectively as a silica source for the synthesis of zeolite Y in
sodium form (NaY). The zeolite in pure phase was obtained from a two-step synthetic route in which the starting gels were
mixed, aged for 24 h at room temperature and crystallized for 24 h at 90 °C. The diameter of single crystal particles from
a scanning electron microscope was approximately 1.0 μm, whereas the average particle diameter from laser diffraction particle
size analyzer was approximately 10 μm because of the agglomeration of small crystals. Longer crystallization time in this
route resulted in a mixed phase containing NaY and zeolite P in sodium form (NaP). In addition, a one-step synthetic route
(no aging) was studied and the product was also a mixed phase zeolite. 相似文献
995.
A novel method for the fabrication of highly ordered nanopore arrays with very small diameter of 14 nm was demonstrated by
using low-temperature anodization. Two-step anodization was carried out at 25 V, sulfuric acid concentration of 0.3 M, and
electrolyte temperature of −15 °C. After anodization, a regular pore array with mean diameter of 14 nm and interpore distance
of 65 nm was formed. The pore diameter and regular arrangement were confirmed by scanning electron microscopy (SEM) and fast
Fourier transformation (FFT), respectively. The present results strongly suggest that the diameter of pores in a highly ordered
alumina template can be reduced by lowering the anodization temperature. 相似文献
996.
Different and alternative methods for the preparation of Ni/pillared clays based on impregnation and encapsulation procedures are reported. Several nickel precursors and metal loadings are considered in order to evaluate their influence on the structural, textural and catalytic properties of the resulting solids. The behaviour of the optimum solids as catalysts has been proved in the selective catalytic reduction of nitrogen oxides with propene, and the relevance of the oxidant nature was checked by changing the composition of the oxidant mixture. Of all the factors studied, the nature of the nickel precursors appears as the most important one, owing to the formation of different active nickel species during the synthesis procedure. 相似文献
997.
In this work, the kinetics and mechanism of free-radical polymerisation of glycidyl methacrylate (GMA) using potassium peroxydisulphate
(PDS) as water soluble initiator in the presence of synthesized 1, 4-Bis (tributyl methyl ammonium) benzene dichloride (TBMABDC)
as multi-site phase transfer catalyst (MPTC) was studied. The polymerisation reactions were carried out under inert and unstirred
conditions at constant temperature of 60 ± 1°C in cyclohexane/water biphase media. The role of concentrations of monomer,
initiator, catalyst and volume fraction of aqueous phase, solvent polarity and temperature on the rate of polymerisation (Rp)
was ascertained. The order with respect to monomer and initiator was found to be unity. The order with respect to catalyst
was found to be 0.51. The rate of polymerisation is independent of ionic strength and pH of the medium. However, an increase
in the polarity of solvent has slightly increased the Rp value. Based on the results obtained, a suitable kinetic scheme has
been proposed to account for the experimental observations and its significance discussed. 相似文献
998.
The specific features of SPPA-T3000, a new instrumentation and control system intended for automation of processes in power engineering, are briefly described. Distinctive features of the system architecture, central to which is using the model of web systems, are singled out. 相似文献
999.
In this paper, we present a general method to calculate the inverse and direct dynamic models of parallel robots. The models
are expressed in a closed form by a single equation in which all the elements needed are expressed. The solution is given
in terms of the dynamic models of the legs, the dynamics of the platform and some Jacobian matrices. The proposed method is
applied in this paper on two parallel robots with different structures.
Categories (2), (3). 相似文献
1000.
A new chromosome encoding method, named fuzzy coding, is proposed for representing real number parameters in a genetic algorithm. Fuzzy coding provides the value of a parameter on the basis of the optimum number of selected fuzzy sets and their effectiveness in terms of degree of membership. Thus, it represents the knowledge associated with each parameter and is an indirect method of encoding compared with alternatives, where the parameters are directly represented in the encoding. Fuzzy coding is described and compared with conventional binary coding, gray coding, and floating-point coding. Two test examples, along with neural identification of a nonlinear pH process from experimental data, are studied. It is shown that fuzzy coding is better than the conventional methods and is effective for parameter optimization in problems where the search space is complicated. 相似文献