Smart ultrasonic sensors systems: potential of aluminum nitride thin films for the excitation of the ultrasound at high frequencies

We investigated the potential of the aluminum nitride films to excite ultrasonic waves at frequencies >50?MHz. The deposition process of the aluminum nitride thin film layers on silicon substrates was investigated and optimized regarding their piezoelectric behavior. Large single element transducers were deposited on silicon substrates with aluminum electrodes, under different parameters for the magnetron sputter process, like pressure and bias voltage. Special test setup and a measuring station were created to characterize the sensors. Acoustical measurements were carried out in pulse echo mode up to 500?MHz and the values of piezoelectric charge constant (d₃₃) were determined. As a result, two parameter sets were found for the sputtering process to obtain an excellent piezoelectric charge constant of about 7.2?pC/N maximum. Then the sputtering process with these parameters was used to deposit sensors on various substrate materials and with different electrode sizes.     

Effects of material thickness and processing method on poly(lactic-co-glycolic acid) degradation and mechanical performance

In this study, the effects of material thickness and processing method on the degradation rate and the changes in the mechanical properties of poly(lactic-co-glycolic acid) material during simulated physiological degradation were investigated. Two types of poly(lactic-co-glycolic acid) materials were considered: 0.12?mm solvent-cast films and 1?mm compression-moulded plates. The experimental results presented in this study were compared to the experimental results of Shirazi et al. (Acta Biomaterialia 10(11):4695–703, 2014) for 0.25?mm solvent-cast films. These experimental observations were used to validate the computational modelling predictions of Shirazi et al. (J Mech Behav Biomed Mater 54: 48–59, 2016) on critical diffusion length scale and also to refine the model parameters. The specific material processing methods considered here did not have a significant effect on the degradation rate and the changes in mechanical properties during degradation; however, they influenced the initial molecular weight and they determined the stiffness and hardness of the poly(lactic-co-glycolic acid) material. The experimental observations strongly supported the computational modelling predictions that showed no significant difference in the degradation rate and the changes in the elastic modulus of poly(lactic-co-glycolic acid) films for thicknesses larger than 100?μm.     

Gas Chromatographic Enantiomer Separation of Polychlorinated Biphenyls (PCBs): Methods,Metabolisms, Enantiomeric Composition in Environmental Samples and their Interpretation

The year 2016 not only marks the 50^th anniversary of the first successful discovery of gas chromatographic (GC) enantiomer separations in 1966 by Gil-Av, but also the less appraised 50^th anniversary of the discovery of polychlorinated biphenyls (PCBs) in the environment. This article reports on GC enantiomer separations of axially stable, chiral PCBs (PCB atropisomers) with modified cyclodextrins. Nineteen atropisomeric PCBs exist, but most data exists for four PCB atropisomers (PCB 95, PCB 132, PCB 149, and PCB 136), which can be resolved without significant coelutions on three columns coated with modified cyclodextrins. Nonracemic compositions of PCB atropisomers and their hydroxylated metabolites have been documented in various studies. However, the measured enantiomer fractions are currently difficult to interpret und understand. The most plausible reasons for these difficulties are discussed and interpreted with the help of selected examples from the literature.     

Evaluation of microalgae-based biorefinery alternatives

Microalgae-based biorefineries for the production of renewable biofuels like biodiesel, upgraded bio-oil, biochar, biogas and other high-value chemicals have received great attention in recent decades as potential major sources of energy for the future. Microalgae are a suitable species to produce biodiesel and other high energy density by-products; however, it is questionable whether a net energy gain can be realized or not considering the whole processing chain. In the present study, the energy balances of different algae-based biofuel and bioenergy production technologies are investigated in detail and compared to each other corresponding to a cradle-to-grave overall energetic analysis. The study includes cultivation, harvesting, cell pretreatments (cell disruption, drying, grinding), lipid extraction, transesterification, gasification and hydrothermal liquefaction with bio-oil stabilization and hydroprocessing. The energy consumption and energy gain are estimated for each operational step to determine the net energy ratio (NER, energy output over energy input) for the overall technologies studied. Our detailed investigation enables to detect the most energy consuming unit operation, that is, the bottleneck point(s) of the microalgae-based technologies which should be still improved in the future for the sake of more efficient algae-based biorefineries. The investigation makes also possible to evaluate and compare the different large scale alternatives for biomass transformation. Positive energy balances with a NER value of 1.109 and 1.137 are found in two already existing processes: open raceway ponds and closed photobioreactors, respectively. Our work gives also a detailed algorithm that can be followed at the evaluation of other microalgae-based biorefineries.     

A Danish case: portfolio evaluation and its impact on energy efficiency policy

A political agreement from 2005 stated that an evaluation of the entire Danish energy efficiency policy portfolio must be carried out before the end of 2008, with the aim to assess the following: (1) Is the policy portfolio sufficient to meet the energy efficiency targets? (2) Do the policies enable the national goals to be met in a cost-effective manner? (3) Is the overall design of the policy portfolio appropriate? The evaluation gave recommendations on how to improve and develop the portfolio, mainly using cost-effectiveness as criteria. The evaluation was completed in December 2008, and this paper presents the main findings and the subsequent impact on Danish policy. A key lesson learned is the importance of including all energy efficiency policies in the evaluation. Examining the entire portfolio of policies (as opposed to only selected policies) gave way to findings that would otherwise not have been captured. With its broad perspective, the evaluation found that the policy instruments prioritised the commercial and industrial sectors less than the household and public sectors. The recommendations made by the authors contributed to the implementation of new taxes for the commercial and industrial sectors together with the reform of the Electricity Saving Trust to a Centre for Energy Savings charged with energy savings within all sectors, except transport—both which have been important steps towards a more cost-effective solution.     

Synthesis of Supported Catalysts by Atomic Layer Deposition

A promising new method of catalyst synthesis is atomic layer deposition (ALD). ALD is a variation on chemical vapor deposition wherein metals, oxides and other materials are deposited on surfaces via a sequence (usually binary) of self-limiting reactions. The self-limiting character of the reactions makes it possible to achieve uniform deposits on high-surface-area porous solids and, hence, produce practical catalytic materials. The ability to deposit uniform layers in a sequence makes it possible to fabricate the support and then construct the catalytic metal and/or metal oxide species and add modifier layers in any desired order. This article will provide a short introduction to the technique of ALD and its application to the synthesis of supported catalytic metal nanoparticles and oxide monolayers.     

Dynamics of safety performance and culture: A group model building approach

The management of occupational health and safety (OHS) including safety culture interventions is comprised of complex problems that are often hard to scope and define. Due to the dynamic nature and complexity of OHS management, the concept of system dynamics (SD) is used to analyze accident prevention. In this paper, a system dynamics group model building (GMB) approach is used to create a causal loop diagram of the underlying factors influencing the OHS performance of a major drilling and mining contractor in Australia. While the organization has invested considerable resources into OHS their disabling injury frequency rate (DIFR) has not been decreasing. With this in mind, rich individualistic knowledge about the dynamics influencing the DIFR was acquired from experienced employees with operations, health and safety and training background using a GMB workshop. Findings derived from the workshop were used to develop a series of causal loop diagrams that includes a wide range of dynamics that can assist in better understanding the causal influences OHS performance. The causal loop diagram provides a tool for organizations to hypothesize the dynamics influencing effectiveness of OHS management, particularly the impact on DIFR. In addition the paper demonstrates that the SD GMB approach has significant potential in understanding and improving OHS management.