Steam hydration-reactivation of FBC ashes for enhanced in situ desulphurization

Bed and fly ashes originating from industrial-scale fluidized bed combustors (FBCs) were steam hydrated to produce sorbents suitable for further in situ desulphurization. Samples of the hydrated ash were characterized by X-ray diffraction analysis, scanning electron microscopy and porosimetry. Bed ashes were hydrated in a pressure bomb for 30 and 60 min at 200 °C and 250 °C. Fly ash was hydrated in an electrically heated tubular reactor for 10 and 60 min at 200 °C and 300 °C. The results were interpreted by considering the hydration process and the related development of accessible porosity suitable for resulphation. The performance of the reactivated bed ash as sulphur sorbent improved with a decrease of both the hydration temperature and time. For reactivated fly ash, more favourable porosimetric features were observed at longer treatment times and lower hydration temperatures. Finally, it was shown that an ashing treatment (at 850 °C for 20 min) promoted a speeding up of the hydration process and an increase in the accessible porosity.     

Toward multimodal notation for mathematics: Why and how

Notation is a tool of thought, recording and communicating concepts and activities related to a domain of knowledge. In the history of mathematical notation, written notation is usually considered. However, to be an effective thinking tool, notation must be properly perceived. Blind and partially sighted people run into difficulty in making, exploring and understanding mathematical concepts conceived for being represented in multi-dimensional space. In this paper, we capitalize on the multifaceted nature of digital symbols to define multimodal digital notation for graph structures that allows blind and partially sighted people to represent graph structures, reason about them and communicate their reasoning with sighted people as well as each other. As support tool for notation proposed we have designed a multimodal interactive system, in which haptic signals play a crucial role. An evolutionary prototype of the system has been developed and evaluated according to the star life cycle model.     

A design methodology for high-order class-D audio amplifiers

This paper presents a design methodology for high-order class-D amplifiers, based on their similarity with sigma–delta ( $\Upsigma\Updelta$ ) modulators, for which established theory and toolboxes are available. The proposed methodology, which covers the entire design flow, from specifications to component sizing, is validated with three design examples, namely a second-order, a third-order, and a fourth-order class-D amplifier. Moreover, the third-order class-D amplifier has been integrated on silicon and characterized, further confirming the validity of the whole design flow. The achieved results demonstrate that high-order class-D amplifiers can achieve total-harmonic-distortion (THD) performance compatible with the specifications of high-end audio applications (THD  ≈ 90 dB), which would be unfeasible with conventional first-order class-D amplifiers.     

Upflow turbulent mixed convection heat transfer in vertical pipes

The present work deals with the results of an experimental investigation on heat transfer in water cooled vertical pipes, for thermal–hydraulic conditions ranging from forced convective flow to mixed convective flow. The flow of water in the pipe is upwards.Experimental data confirm the reduction in the heat transfer rate for mixed convection in upward heat flow, mainly due to the laminarization effect in the near-wall region (buoyancy effect) . They are in a very good agreement with numerical methods, such as the k–-model.A new method for the calculation of the heat transfer coefficient in upward mixed convection heated flow is proposed. It is based on the well-known superposition method (heated downflow) modified accounting for the phenomenology of the upward heated flow in comparison with downflow heated conditions.     

Modeling of flexural behavior of RC beams strengthened with mechanically fastened FRP strips

An alternative to fiber reinforced polymer (FRP) materials adhesively bonded to the concrete substrate is the implementation of mechanically fastened FRP (MF-FRP) systems using steel anchors to secure the laminate to the substrate. The benefit of MF-FRP, compared to adhesive bonding for FRP flexural strengthening, is the speed of installation with unskilled labor, minimal or absent surface preparation under any meteorological condition and immediate use of the strengthened structures. Some of the potential shortcomings are: possible concrete damage during anchoring and limited opportunity of installation in the presence of congested internal reinforcement in the members to be strengthened. Laboratory testing and a number of field applications have shown the effectiveness of the MF-FRP method. In this paper, an analytical model is discussed for reinforced concrete (RC) members strengthened with MF-FRP strips. The model accounts for equilibrium, compatibility and constitutive relationships of the constituent materials; in particular, it accounts explicitly for the slip between the substrate surface and the FRP strip due to the behavior of the fasteners. The proposed flexural model, coupled with the computation algorithm, is able to predict the fundamentals of the behavior of RC flexural members strengthened with MF-FRP strips, in terms of both ultimate and serviceability limit states. Comparisons between the analytical predictions and the experimental results have been successfully performed.     

Overlapping of heterogeneous and purely thermally activated solid-state processes in the combustion of a bituminous coal

Mechanistic studies of coal combustion have long highlighted the variety of reaction pathways along which gasification may take place. These involve chemisorption of reactants, formation of surface oxides, surface mobility of chemisorbed species, and product desorption. At the same time, exposure of the solid fuel to high temperatures is associated with solid-state thermally activated processes. Altogether, the course of gasification may be profoundly affected by the overlapping and interplay of heterogeneous oxidation with purely thermally activated solid-state reactions. In the present work the combustion of a South African bituminous coal is analyzed in the framework of a simplified reaction network that embodies heterogeneous oxidative and thermally activated processes (pyrolysis, thermal annealing, coal combustion, char combustion, oxygen chemisorption) active both on the raw coal and on its char. The kinetics of each process of the network is assessed by a combination of thermogravimetric and gas analysis on coal and char samples. The analysis is directed to the determination of the prevailing combustion pathway, established from the interplay of oxidative and solid-state thermally activated processes, as a function of combustion conditions (temperature, heating rate, particle size).     

Current noise in MgB2 superconducting thin films

In this paper we present some experimental results concerning the current noise produced during the resistive transition in MgB₂ thin films. Preliminary investigations evidenced the presence of electrical noise whose power spectrum has a region of the 1/fⁿ type with n 3. We suggest that the noise may originate from abrupt rearrangement of the current distribution inside the specimen during the percolative process of a diphasic system. Experimental measurements of the spectral components of the current noise taken during the resistive transition will be given and discussed.     

Patterns of neuropsychological impairment in mild dementia: a comparison between Alzheimer''s disease and multi-infarct dementia

Left ventricular wall motion abnormalities secondary to stress-induced myocardial ischemia can be detected with difficulty by mentally comparing echocardiographic images sequentially recorded on videotape. Digital stress-echocardiography, a combination of ultrasound imaging and digital archiving technologies, at least partially can overcome this problem: the technique is based on reviewing images at rest and after stress (exercise or pharmacological) side by side in dual- or quad-screen digital format, in a synchronized cine-loop, as if obtained simultaneously. This technique however is presently not widely used, due to the high cost of most commercially available systems. We have developed a digital stress-echo system, which is easy to use and relatively inexpensive, running on a Macintosh II personal computer with 8-bit graphics. The 2-D echocardiographic images recorded on videotape are digitized offline using a video digitizing board. The image can be displayed and analyzed using the public domain NIH image software developed by Wayne Rasband, without loss in image quality and resolution, particularly if using Super-VHS videotape. We have made a macro procedure for the montage in a quad-screen format of four digital recorded echocardiographic cardiac cycles of six frames that takes only a little more time than commercially available systems. In conclusion, the use of a personal computer and low-cost software may help to make digital stress-echo techniques more widely feasible in the clinical setting and increase the diagnostic power of the ultrasound technique in the evaluation of patients with known or suspected coronary artery disease.     

Network and single user performance evaluation of a mobile data system over flat fading transmission channels

In this paper the contrasting effects of transmission impairments and capture on both the network and single user performance of a slotted Aloha system are investigated in a mobile radio environment, accounting for frequency non-selective random propagation phenomena, and employing the packet error probability in order to define packet losses and capture. With this study we demonstrate that it is possible to generalize in a real propagation context a method previously proposed in literature for evaluating the network behavior in terms of steady-state throughput, backlog and stability in conventional transmission conditions, i.e., when all the transmission channels were error-free and the collisions caused the loss of all the packets involved. Moreover, we indicate under which specific constraints on the terminal mobility we can apply this method to analytically predict the single user performance, which we show being an important design parameter. Through the numerical results reported we quantitatively point out that in the absence of coding capture increases system stability and moderately improves the overall system throughput and backlog. We also outline the trade-off between an increased capture gain obtained by means of coding and the corresponding system cost in terms of complexity and bandwidth occupancy. Furthermore, we demonstrate the unfairness which affects the single user performance and the consequent need for countermeasures in order not to discriminate among users differently located within the network; yet, this last solution is detrimental as regards the positive capture effects.This work was supported by M.U.R.S.T. and C.N.R. (Italy).     

Mortality of Tribolium confusum J. du Val (Coleoptera: Tenebrionidae) in controlled atmospheres at different oxygen percentages

Since the 1990s an ecologically friendly alternative to insecticide treatments for controlling stored-product insect pests has been available: the methods of modified and controlled atmospheres, which involve reducing the quantity of oxygen (O₂) in the air in order to kill insects by anoxia. This study examines the effect of treatments with controlled atmospheres, considering the time necessary to obtain total mortality of insects at percentages of O₂ higher than those normally used in controlled atmospheres and estimating the possible positive influence of a temperature increase in order to compensate for the effects of the reduced anoxia.Adult populations of Tribolium confusum J. du Val were treated at various O₂ percentages (1, 3, 5, 6, 7, 8 and 10%) and temperatures (23, 26, 29, 32, 35, 37 and 40 °C). The relative humidity was very low (<18%) in all the treatments considered.Lethal exposure times varied from less than one day to a week (longer times were not considered).A multiple regression procedure was applied to the experimental data, considering the time necessary to obtain total mortality as the dependent variable. The analysis provided a good fit to the experimental data and indicated a positive correlation with the percentage of O₂ and an inverse one with temperature.