稀土与L-酪氨酸甘氨酸三元固态配合物的合成与表征

在乙醇溶液中合成了四种稀土与 L-酪氨酸、甘氨酸的三元固态配合物 RE( Tyr) 1.5 ( Gly) 4 ( Cl O4) 3( RE=La3+、Ce3+、Gd3+、Y3+) ,并通过摩尔电导、热分析、红外光谱等进行了表征。     

有机硅密封胶粘附性能的改善

研究了交联剂、催化剂、填料等对单组分有机硅密封胶性能的影响。     

Fe^3＋对TiO2的自然光催化降解性能影响

采用溶胶-凝胶法制备了TiO2光催化材料,在太阳光的照射下进行了加有 Fe^3 的染料溶液的光催化降解。实验结果表明,加有Fe^3 后,TiO2的自然光催化活性显著高于未加Fe^3 的染料溶液,其与TiO2在紫外灯下的催化活性相当。并对其催化机理进行了讨论。     

3,3′,5,5′-四甲基联苯胺与钒(V)显色反应的研究

:研究了 3,3′,5 ,5′-四甲基联苯胺 (TMB)和钒 (V)的显色反应。在 HCl介质中 ,溶液于波长 430 nm处有最大吸收 ,表观摩尔吸光系数为 2 .5× 10 4L· mol- 1· cm- 1 ,钒 (V)量在 0～ 2 .5 mg/ L 范围内服从比尔定律。     

可再生能源多能互补的分布式能源系统两级超结构模型

针对现有分布式能源系统设计受区域、资源和政策差异性的影响,建立了一套考虑可再生能源多能互补的超结构模型框架和通用求解方法.通过对系统流程结构和单元设备物理特性的逻辑描述,确定模型输入输出参数.引入强制进化随机游走算法,实现不同用能负荷需求、可再生能源形式和区域条件的求解计算.将提出的优化模型应用于具体算例,根据资源、设...     

具有整体围带和凸台拉筋汽轮机长叶片阻尼振动特性实验研究

阻尼围带和凸台拉筋结构在大型汽轮机叶片中被广泛采用来增加叶片阻尼,降低其振动应力.设计并建造了阻尼结构叶片振动特性实验台,对一具有阻尼围带和凸台拉筋汽轮机长叶片的阻尼器接触面施加不同转速下的正压力进行了振动特性测试,得到了不同转速正压力下叶片的频响曲线和模态阻尼比.试验结果表明:只有围带接触时,随着转速的增加,叶片模态阻尼比先增后减;围带和拉筋都接触时,也存在同样的现象.当转速大于2 600r/min后,叶片的共振频率基本不变且模态阻尼比与自由叶片时基本一致.     

Effects of buffer gas composition on low temperature ignition of iso-octane and n-heptane

Experimental and numerical studies have been performed on the thermal and chemical effects of buffer gas composition on low temperature ignition of iso-octane and n-heptane. Experiments were conducted using a recently developed rapid compression machine in the temperature range of 600–850 K. Three buffer gases were studied including nitrogen (N₂), argon (Ar), and a mixture of Ar and carbon dioxide (CO₂) at a mole ratio of 65.1%/34.9%. Iso-octane was studied at 20 bar, ? = 1, and a dilution level of buffer gas to O₂ of 3.76:1 (mole ratio). n-Heptane was studied at 9 bar, ? = 1, and a dilution level of buffer gas to O₂ of 5.63:1 (mole ratio). For experiments where two-stage ignition was observed, the buffer gas composition had no impact on the first-stage ignition time but, as expected, it caused differences in the total heat release, pressure and temperature rise after the first-stage ignition. As a consequence, significant differences were observed for the total ignition delay time as a function of the buffer gas composition, with up to 40% and 42.5% faster total ignition time for iso-octane and n-heptane, respectively, by using Ar instead of N₂. The chemical effects of the buffer gas composition were studied experimentally by comparing the results of the N₂ and Ar/CO₂ (65.1%/34.9%) mixtures, recognizing that while the Ar/CO₂ mixture has the same heat capacity as N₂, its predicted combined third-body collision efficiency is about 76% higher than N₂. The experimental results showed negligible chemical effects on the first-stage and total ignition delay times. Numerical simulations were carried out over a wider range of temperatures for pure N₂, Ar, and CO₂ as buffer gases. Results showed that thermal effects are very pronounced and dominated at the negative temperature coefficient and two-stage ignition conditions, which is consistent with the experimental results and previous studies in the literature. However, the simulation results also showed at temperatures higher than 850 K, the chemical effects of CO₂ became more important than the thermal effects.     

GFS降雨预报图数值化处理算法在洪水预报中的应用

鉴于大部分气象系统对外发布的降雨预报信息均为降雨预报图的形式而不能直接用于水库调度,设计了一种GFS降雨预报图数值化处理算法,可计算出降雨预报图中任意像素点的降雨数值预报信息,然后利用计算出的GFS降雨数值预报信息与洪水预报模型耦合来进行洪水预报,并以桓仁水库2010年的一场洪水为例进行了验证。结果表明,利用该算法计算出的降雨数值预报信息可应用于洪水预报,具有较好的应用前景。     

基于激光加热技术的活塞热负荷试验方法研究

通过对发动机活塞实际工作温度场分布规律与冷却特点的分析,提出了以激光作为热源,应用能量分配与光学转换技术模拟再现活塞温度场分布及热负荷作用的试验方法.研究结果表明该方法对活塞顶部不同区域温度可控,瞬态温度模拟真实,损伤监测到位,试验效率高.为今后开展活塞热损伤,热疲劳机理研究及提高活塞热负荷评估试验的置信度奠定了基础.     

发酵工程教学中培养学生专业能力的探索

基于专业人才培养目标和行业需求,在发酵工程课程教学中,我们提出了培养学生三层次的专业能力的目标,即综合能力、专项能力和单项能力。通过改革教学内容,改进教学方法,完善实践教学体系、开展课外科技活动,学生增强了专业能力的适应性、应用性和创新性。