全文获取类型
收费全文 | 1657篇 |
免费 | 91篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 27篇 |
综合类 | 1篇 |
化学工业 | 619篇 |
金属工艺 | 23篇 |
机械仪表 | 24篇 |
建筑科学 | 47篇 |
矿业工程 | 8篇 |
能源动力 | 70篇 |
轻工业 | 181篇 |
水利工程 | 6篇 |
石油天然气 | 6篇 |
无线电 | 107篇 |
一般工业技术 | 273篇 |
冶金工业 | 74篇 |
原子能技术 | 3篇 |
自动化技术 | 280篇 |
出版年
2024年 | 5篇 |
2023年 | 14篇 |
2022年 | 116篇 |
2021年 | 167篇 |
2020年 | 58篇 |
2019年 | 59篇 |
2018年 | 74篇 |
2017年 | 65篇 |
2016年 | 93篇 |
2015年 | 54篇 |
2014年 | 105篇 |
2013年 | 120篇 |
2012年 | 74篇 |
2011年 | 82篇 |
2010年 | 62篇 |
2009年 | 66篇 |
2008年 | 74篇 |
2007年 | 60篇 |
2006年 | 43篇 |
2005年 | 37篇 |
2004年 | 47篇 |
2003年 | 31篇 |
2002年 | 27篇 |
2001年 | 18篇 |
2000年 | 15篇 |
1999年 | 13篇 |
1998年 | 11篇 |
1997年 | 15篇 |
1996年 | 8篇 |
1995年 | 15篇 |
1994年 | 11篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 13篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1987年 | 7篇 |
1986年 | 3篇 |
1985年 | 8篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 11篇 |
1980年 | 7篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1971年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有1749条查询结果,搜索用时 0 毫秒
91.
Malgorzata Pastusiak Piotr Dobrzynski Janusz Kasperczyk Michal Sobota Bozena Kaczmarczyk Henryk Janeczek 《Polymer International》2017,66(9):1259-1268
Ethylzinc(II ) ethoxide is a highly active and efficient initiator for the bulk polymerization of 1,3‐trimethylene carbonate and its copolymerization with ? ‐caprolactone. This initiator allows one to obtain (co)polymers with high molar masses in quite a short time. Significant difference in co‐monomer reactivity and relatively low participation of intermolecular transesterification processes lead to the obtained copolymers being characterized by a gradient chain microstructure. In 13C NMR spectra, in all regions, we observed the presence of triads which were distinctly represented by four peaks for the carbonyl signal. Mechanical tests showed that copolymers containing 70% and more of ? ‐caprolactone presented a relatively high Young's modulus and a very high maximum elongation factor; therefore these materials are promising in many biomedical applications. Due to the high reaction rate, we also made an attempt at copolymerization using reactive extrusion which gave promising results. © 2017 Society of Chemical Industry 相似文献
92.
Stanisław Sadło Ewa Szpyrka Bartosz Piechowicz Piotr Antos Radosław Józefczyk 《臭氧:科学与工程》2017,39(2):97-103
Intensive use of plant protection products in modern agriculture and horticulture often results in increasing residue levels of active ingredients of plant protection products in fruits and vegetables. Even if the maximum residue levels are not exceeded, the synergic effects of various compounds may have a serious impact on consumers' health. In particular, more sensitive consumer groups, e.g., children, may be affected. Therefore, it is important to develop an effective method that could be utilized for reduction of pesticide residue levels in food products of plant origin. In this work, possible application of ozone to reduce pesticide residue levels in apples has been investigated. The fruits were treated with ozone in gaseous state, in ozonized water, and in water alone, which was used for rinsing the fruits. The experiments included tests on apples that were subjected to a protection program using captan, boscalid and pyraclostrobin. The ozonized water and treatment with a gaseous ozone were found to be not more efficient in reducing the pesticide content on the fruits than simple washing procedures, e.g., 81–95% reduction of captan residue or 40–67% reduction of boscalid residue and 20–42% reduction of pyraclostrobin residue. Still, ozonation of water used for rinsing prevented fruits from consecutive contamination by pesticide residues present in water after several rinsing cycles. It was proven that application of ozonation process as a part of post-harvest treatment of apples may be beneficial for the fruit quality. 相似文献
93.
ABSTRACT The aim of this work was to investigate rheological properties of apple cubes undergoing convective drying. Compression-relaxation test was used to follow changes of properties under investigation. Raw apple appeared to be very heterogeneous material from the rheological point of view. The relationship between stress and strain was concave downwards and the concavity increased until water content of 2·5 g/g d.m. was reached. Then the relationship begun to straighten and for dry material developed stress was linearly dependent on strain. The resistance of deformation decreased with decreasing water content. Analysis of relaxation showed that the rate of relaxation increased with decreasing water content and the unrelaxed stress was smaller the lower was the water content. Apple cubes undergoing drying are pictured as material composed of three compartments with different rheological properties. The outer layer is dry, inelastic and difficult to deform. Underneath is moist material with no turgor and relatively easy to compress, and the core with properties of raw apples. During drying the second layer grows in expense of the core and porous structure with many voids filled with air is formed. Share of each compartment in the volume of apple cube undergoing drying affects average rheological properties of the material. 相似文献
94.
Mathematical analysis was performed on equations describing water vapor sorption isotherms. It was shown that an identity exists between the Blahovec and Yanniotis (BY), D'Arcy and Watt (DW), and generalized D'Arcy and Watt (GDW) models. The original BY model has been modified to account for temperature dependence of the model parameters. This modification enables the application of this model to describe sorption data obtained at different temperatures. A new method for classification of sorption isotherms has been proposed that is much simpler than the classification established by Blahovec and Yanniotis. 相似文献
95.
Agnieszka Ciurzyńska Dariusz Piotrowski Andrzej Lenart Piotr Łukasik 《Drying Technology》2013,31(8):850-858
This work demonstrates the influence of changes in parameters of vacuum drying (temperature and pressure) on the sorption properties of dried strawberries. Fruits were dried at 50 and 70°C under pressures of 4 and 16 kPa. Vacuum drying was also conducted during the first 4 h at 70°C and then the temperature was decreased to 50°C at a pressure of 4 kPa. The other combination included increasing the pressure after the first 4 h from 4 to 16 kPa at a drying temperature of 70°C. Sorption isotherms were determined in the dried strawberries. It was shown that with increasing drying temperatures, there was a notable deterioration in the capacity for absorbing water vapor by the vacuum-dried fruit. On the other hand, the pressure at which vacuum drying proceeded did not significantly affect water vapor absorption. Changing the parameters of vacuum drying—that is, temperature in the range of 50–70°C and pressure in the range of 4–16 kPa—affected the shape and structure of the resultant dried strawberries. The combination of vacuum drying with convective drying also influenced the shape and structure of the dried fruit. 相似文献
96.
Piotr Sobota 《Polymer-Plastics Technology and Engineering》2013,52(5-6):493-510
Most of the research in the field of olefin polymerization is focused on TiC1, catalysts on a specially prepared MgCl, support. In order to combine a high polymer yield with good stereoselectivity, a complexed cocatalyst is used. Most frequently it is a mixture of AIEtzCl or AlEt, with an electron donor such as tetrahydrofuran (THF) or ethyl benzoate for ethylene and propylene polymerization, respectively. 相似文献
97.
Michał Piotr Kwiatkowski Mariusz Kłonica Józef Kuczmaszewski Saburoh Satoh 《臭氧:科学与工程》2013,35(3):220-228
The purpose of this article is to present energetic properties of surface Ti6Al4V titanium as well as surface EN-AW-2017A(PA6) aluminum alloy layers. Values of surface free energy after selected mechanical operations and ozonation were compared. In addition, the influence of different values of ozone concentration on surface layer energetic activation was analyzed. Dispersive and polar components of surface free energy were of particular concern. Comparative evaluation of shearing strength of Ti6Al4V titanium and EN-AW-2017A(PA6) aluminum alloy single-lap adhesive bonded joints were presented. Results can be used as pro-ecological methods of titanium and aluminum alloys preparing for applications where adhesive phenomenon is important. 相似文献
98.
One of the strategies in the search for safe and effective analgesic drugs is the design of multitarget analgesics. Such compounds are intended to have high affinity and activity at more than one molecular target involved in pain modulation. In the present contribution we summarize the attempts in which fentanyl or its substructures were used as a μ-opioid receptor pharmacophoric fragment and a scaffold to which fragments related to non-opioid receptors were attached. The non-opioid ‘second’ targets included proteins as diverse as imidazoline I2 binding sites, CB1 cannabinoid receptor, NK1 tachykinin receptor, D2 dopamine receptor, cyclooxygenases, fatty acid amide hydrolase and monoacylglycerol lipase and σ1 receptor. Reviewing the individual attempts, we outline the chemistry, the obtained pharmacological properties and structure-activity relationships. Finally, we discuss the possible directions for future work. 相似文献
99.
100.
Lucjan Chmielarz Piotr Kutrowski Alicja Rafalska-asocha Roman Dziembaj 《Applied catalysis. B, Environmental》2005,58(3-4):235-244
The selective catalytic oxidation of ammonia to nitrogen (NH3-SCO) has been studied over hydrotalcite derived mixed metal oxides containing Cu, Co, Fe or Ni. XRD, BET, NH3-TPD and TPR techniques were used for catalysts characterization. Results of NH3-SCO were compared with those of selective catalytic reduction of NO with NH3 (NO-SCR). Reaction mechanism was studied by temperature-programmed surface reaction (TPSR) and activity tests with a various contact time. Catalytic performance of the studied samples depends on both kind and loading of transition metals in the mixed metal oxide system. The Cu-containing samples have been found to be the most active catalysts of the NH3-SCO process. Transition metal loading strongly influences distribution of ammonia oxidation products. The highest selectivity to N2 was measured for the catalysts with the lowest transition metal content. 相似文献