Realization of complex digital filters based on the LBC two-pair extraction procedure

The synthesis of real digital filters based on the lossless bounded real (LBR) two-pair extraction procedure is extended to the complex domain. the only component then required is a first-order reciprocal lossless bounded complex (LBC) two-pair. This two-pair permits the synthesis of any bounded complex (BC) or lossless bounded complex (LBC) digital transfer function. Lastly, a unitary implementation in terms of Givens (planar) rotation modules is given for the proposed two-pair.     

A Parallel Optimization Approach to ATM Network Survivability

This paper describes a new model for routing in survivable ATM networks and a new parallel projection algorithm for solving the corresponding optimization problem. The proposed algorithm has application in general linear programming (LP). Numerical results for medium size networks are presented and discussed.     

Water transport through subnanopores in the ultimate size limit: Mechanism from molecular dynamics

Ab initio and classical molecular dynamics simulations show that water can flow through graphdiyne—an experimentally fabricated graphene-like membrane with highly dense (2.4 × 10¹⁸ pores/m²), uniformly ordered, subnanometer pores (incircle diameter 0.57 nm and van der Waals area 0.06 nm²). Water transports through subnanopores via a chemical-reaction-like activated process. The activated water flow can be precisely controlled through fine adjustment of working temperature and pressure. In contrast to a linear dependence on pressure for conventional membranes, here pressure directly modulates the activation energy, leading to a nonlinear water flow as a function of pressure. Consequently, high flux (1.6 L/Day/cm²/MPa) with 100% salt rejection efficiency is achieved at reasonable temperatures and pressures, suggesting graphdiyne can serve as an excellent membrane for water desalination. We further show that to get through subnanopores water molecule must break redundant hydrogen bonds to form a two-hydrogen-bond transient structure. Our study unveils the principles and atomistic mechanism for water transport through pores in ultimate size limit, and offers new insights on water permeation through nanochannels, design of molecule sieving and nanofluidic manipulation.

     

Treatment of brines by combined Fenton's reagent-aerobic biodegradation. II. Process modelling

Process modelling of the integrated Fenton's reagent-aerobic biodegradation system has been carried out by considering a detailed reaction mechanism for the chemical oxidation step and the generalised Monod equation for the biological treatment. Chemical oxygen demand has been contemplated as a pseudo-component for simulation purposes. The proposed mechanism takes into consideration different features experimentally found. Thus, the inefficient hydrogen peroxide decomposition into oxygen and water, the influence of temperature and other operating variables and the role of oxygen have been considered. The aerobic biodegradation of the effluent after the chemical oxidation has taken place has been well simulated by Monod equation with no inhibitory terms. Dependency on temperature has been correlated by Arrhenius expression.     

Invariant-driven specifications in Maude

This work presents a general mechanism for executing specifications that comply with given invariants, which may be expressed in different formalisms and logics. We exploit Maude’s reflective capabilities and its properties as a general semantic framework to provide a generic strategy that allows us to execute Maude specifications taking into account user-defined invariants. The strategy is parameterized by the invariants and by the logic in which such invariants are expressed. We experiment with different logics, providing examples for propositional logic, (finite future time) linear temporal logic and metric temporal logic.     

C for Econometricians

Fortran has long been the mother-tongue of the scientific community. This note looks at the C programming language from the viewpoint of numerical computing with the emphasis placed on econometric applications. C can be used as a replacement for other lower level programming languages, and also a replacement or as a complement to higher level matrix programming languages such as GAUSS, MATLAB, Ox, and S-PLUS.     

Interactions of <Emphasis Type="Italic">Bacillus mojavensis</Emphasis> and <Emphasis Type="Italic">Fusarium verticillioides</Emphasis> with a Benzoxazolinone (BOA) and its Transformation Product,APO

The benzoxazolinones, specifically benzoxazolin-2(3H)-one (BOA), are important transformation products of the benzoxazinones that can serve as allelochemicals providing resistance to maize from pathogenic bacteria, fungi, and insects. However, maize pathogens such as Fusarium verticillioides are capable of detoxifying the benzoxazolinones to 2-aminophenol (AP), which is converted to the less toxic N-(2-hydroxyphenyl) malonamic acid (HPMA) and 2-acetamidophenol (HPAA). As biocontrol strategies that utilize a species of endophytic bacterium, Bacillus mojavensis, are considered efficacious as a control of this Fusarium species, the in vitro transformation and effects of BOA on growth of this bacterium was examined relative to its interaction with strains of F. verticillioides. The results showed that a red pigment was produced and accumulated only on BOA-amended media when wild type and the progeny of genetic crosses of F. verticillioides are cultured in the presence of the bacterium. The pigment was identified as 2-amino-3H-phenoxazin-3-one (APO), which is a stable product. The results indicate that the bacterium interacts with the fungus preventing the usual transformation of AP to the nontoxic HPMA, resulting in the accumulation of higher amounts of APO than when the fungus is cultured alone. APO is highly toxic to F. verticillioides and other organisms. Thus, an enhanced biocontrol is suggested by this in vitro study.     

Determination of the bound conformation of a competitive nanomolar inhibitor of mycobacterium tuberculosis type II dehydroquinase by NMR spectroscopy

The synergy between tuberculosis and the AIDS epidemic, along with the surge of multidrug-resistant isolates of M. tuberculosis, has reaffirmed tuberculosis as a primary public health threat. It is therefore necessary to discover new, safe, and more efficient antibiotics against this disease. On the other hand, mapping the dynamic interactions of inhibitors of a target protein can provide information for the development of more potent inhibitors and consequently, more potent potential drugs. In this context, the conformational binding of our previously reported nanomolar inhibitor of M. tuberculosis type II dehydroquinase, the 3-nitrophenyl derivative 1, was studied using saturation transfer difference (STD) and transferred NOESY experiments. These studies have shown that in the bound state, one conformation of those present in solution of the competitive nanomolar inhibitor 3-nitrophenyl derivative 1 is selected. In the bound conformation, the aromatic ring is slightly shifted from coplanarity, with the double bond and the nitro group of 1 oriented towards the double bond side.