Low-threshold, high-power zero-order lateral-mode DQW-SCH metal-clad ridge waveguide (AlGa)As/GaAs lasers

Metal-clad ridge waveguide (MCRW), double quantum well, separately confined heterostrucuture (DQW-SCH) lasers have been fabricated having continuous-wave (CW) threshold currents of 10?12 mA and external differential quantum efficiencies of 41?46% per uncoated facet. Light/current characteristics are linear to >70 mW, and zero-order lateral mode operation was measured at 56 mW. The CW burn-off power density is nearly double the best previously reported value.     

The greening of materials science and engineering

The field of materials science and engineering is advancing at a revolutionary pace. It is now generally recognized as being among the key emerging technological fields propelling our world societies into the twenty-first century. The driving forces for this revolutionary pace are at once social, economic, political, and technological. For example, relatively recent changes in United States federal policies in environmental control, hazardous waste management, and energy conservation along with heightened international trade competition have resulted in major changes in material processing and use patterns. These changing patterns are creating new requirements for material developments, substitutions, and associated processes. This paper traces the emergence of materials policy and technological developments through four sub-periods of history: the birth and development of engineering in the United States (1825–1900), the evolution of a national research infrastructure (1900–1945), the evolution of a national science policy (1945–1973), and the intensification of global interdependency (1973-present). Future trends in materials developments and future policy requirements are outlined. Technical Resources, of TRW, Inc., began his professional career in 1954 as a research metallurgist and reactor project engineer with General Electric Co. at the Hanford Atomic Products Operation in Richland, WA. In 1965 he joined Battelle Memorial Institute as a manager of the metallurgy research department and three years later became manager of the fuels and materials department. In 1970 Dr. Bement joined the faculty of Massachusetts Institute of Technology as professor of nuclear materials. From 1974 to 1976 he served as a member of the U.S.-U.S.S.R. Bilateral Exchange Program in Magnetohydrodynamics and was the organizer and principal investigator of the M.I.T. Fusion Technology Program. In 1976 Dr. Bement became Director of the Materials Sciences Office of the Defense Advanced Research Projects Agency and in 1979 was appointed Deputy Under-Secretary of Defense for Research and Engineering. Dr. Bement has co-authored one book, edited three books, and authored over 90 articles on materials science, energy, and defense technology. He is a Fellow of the American Nuclear Society, the American Society for Metals, and the American Institute of Chemists. In addition, he is a member of the American Institute for Mining, Metallurgical and Petroleum Engineers, and the American Society for Testing and Materials. He has received outstanding achievement awards from the Colorado Engineering Council in 1954, the Defense Advanced Research Projects Agency in 1977, and the Colorado School of Mines in 1984. In 1980 he was awarded the Distinguished Civilian Service Medal by the Secretary of Defense. He is a member of the National Academy of Engineering. Dr. Bement is chairman of the National Materials Advisory Board and a member of the Board of Army Science and Technology, the Board on Engineering Sciences, the Board on Assessment of National Bureau of Standards Programs, and the Board on Science and Technology for International Development of the National Research Council. Dr. Bement received an Engineer of Metallurgy (E. Met.) degree in 1954 from the Colorado School of Mines. He received an M.S. in Metallurgical Engineering from the University of Idaho in 1959, and a Ph.D. from the University of Michigan in 1963. He is a Lt. Colonel (ret.) in the U.S. Army Corps of Engineers. Dr. Bement and his family reside in Mayfield Village, OH.     

Convergence of genetic algorithms

The mean convergence of various versions of a genetic algorithm are considered. A number of convergence statements are formulated and relevant estimates are obtained. A hypothesis concerning the form of these estimates under variation of the structure of a genetic algorithm is put forward. Roman Riviyanovich Sharapov. Born 1981. Graduated from the Faculty of Mechanics and Mathematics, Ural State University, in 2003. Presently, a postgraduate at the Department of Mathematical Economics at the same university. Scientific interests: genetic algorithms, neural networks, and financial mathematics. Aleksandr Vyacheslavovich Lapshin. Born 1980. Graduated from the Faculty of Mechanics and Mathematics, Ural State University, in 2003. Presently, a postgraduate at the Department of Mathematical Economics at the same university. Scientific interests: financial mathematics, genetic algorithms, and neural networks.     

Synthesis, Characterization, and Formation Process of Na-X Zeolite from Coal Fly Ash

Using the SiO₂ and Al₂O₃ components of the amorphous phase in coal fly ash (Fa), Fa was converted to Na-X zeolites in NaOH-NaAlO₂ solutions by stirring at 35°C for 72 hr and then aging at 85°C for a given period. The molar ratio SiO₂/Al₂O₃ of the starting materials was controlled from 2.0 to 13.2. The resulting materials were characterized by various means. Increasing the SiO₂/Al₂O₃ ratio of the starting material increased the degree of crystallinity of faujasite, exhibiting a maximum at SiO₂/Al₂O₃ = 8.0. The faujasite formed was identified as Na-X zeolite with Si/Al = 1.20. The amorphous phase in Fa was dissolved during the stirring to form a precursor of zeolite, such as amorphous aluminosilicate. The Na-X zeolite was formed by aging for 24 hr, and the degree of crystallinity of this material was increased with the increasing aging period. The cation exchange capacity and specific surface area were increased with the increasing degree of crystallinity of the Na-X zeolites.     

Comparison of Solutions of the Problems of Elasticity Theory for Different Near-Boundary Elements

We consider three types of near-boundary elements: curvilinear quadrangles and families of arcs and points, and their application to a two-dimensional problem of the static theory of elasticity with boundary conditions in displacements. The comparison of the theoretical and numerical aspects of the obtained solutions is performed. It is shown that the accuracy of evaluation of the components of the vector of displacements increases in the following cases: in the case of complete quantization of the near-boundary region (but not in the case of its partial quantization or quantization with overlapping), in the case where the numbers of arcs and points increase, and in the case of simultaneous application of different types of near-boundary elements (specifically, quadrangles and families of arcs).     

Optimization of Automated Synthesis of 2-[18F]Fluoro-2-deoxy-D-glucose Involving Base Hydrolysis

Synthesis of 2-[¹⁸F]fluoro-2-deoxy-D-glucose ([¹⁸F]FDG) involving base hydrolysis was optimized. Fluorine-18 was isolated from irradiated water to more than 90% by sorption of [^{1 8}F]fluoride on QMA anion-exchange resin, which was followed by elution with a 96 : 4 (by volume) acetonitrile-water mixture containing Kryptofix 2.2.2 and potassium carbonate (molar ratio 2 : 1). This composition is the best for preparing the complex [K/K2.2.2]^{+ 18}F^- used in nucleophilic fluorinations. No additional azeotropic drying is required. Base hydrolysis under optimized conditions (40-45°C), followed by neutralization with HCl, removal of traces of the solvent, and purification of the final product on a combined SCX/Alumina N column, yielded [^{1 8}F]FDG of high radiochemical (>99%) and chemical purity with minimal product loss. With an RB-86 robotic system (Anatech, Sweden), the synthesis time was 38 min. The procedure is used in the Institute of Human Brain, Russian Academy of Sciences for routine synthesis of FDG; the radiochemical yield of the product by the end of synthesis (EOS) is reproducibly high: 63±3% (n = 40).     

Top-Seeded Melt-Growth of YBa2Cus3Ox Crystals for Neutron Diffraction Studies

We have grown cubic centimeter-size crystals of YBa₂Cu₃O _x suitable for neutron studies, by a top-seeded melt-growth technique. Growth conditions were optimized with an eye toward maximizing phase purity. It was found that the addition of 2% Y₂BaCuO₅ and 0.5% Pt (by mass) were required to prevent melt loss and to obtain the highest crystallinity. A neutron diffraction study on a mosaic of six such crystals found that the final Y₂BaCuO₅ concentration was 5%, while other impurity phases comprised less than 1% by volume. The oxygen content was set to x = 6.5, the crystals were detwinned, and then carefully annealed to give the well-ordered ortho-II phase. The neutron study determined that 70% of the mosaic's volume was in the majority orthorhomic domain. The neutron (006) and (110) rocking curve widths were ～1° per crystal and ～2.2° for the mosaic, and the oxygen chain correlation lengths were >100 Å in the a- and b-directions and ～50 Å in the c-direction.     

Numerical simulation of Zn coating solidification

A numerical model, which simulates nucleation and growth of Zn grains, has been developed in order to describe quantitatively the solidification of Zn coatings during the hot-dipping process. The inputs of the model are the nucleation distribution, which has been measured by electron backscattered diffraction (EBSD), and the dendritic growth kinetics, calculated with an analytical model of a parabolic dendrite tip modified to account for the interactions with the coating interfaces. The model predicts the shapes of the grain envelopes as a function of the grain orientation and the texture induced by growth. Three types of grain envelopes have been evidenced, depending on the angle between the c-axis and the normal to the coating plane. Moreover, it has been shown that growth reinforces the already existing {00.1} nucleation texture, in good agreement with experimental data. The model also predicts the cooling curve, including recalescence, and the grain size. Thus, it is used to describe the effects of Pb additions on solidification. In particular, it has been shown that Pb increases the nucleation undercooling and strongly decreases the density of active nuclei, thus resulting in a much larger grain size.