Internal oxidation of dilute Cu–Al alloy powers with oxidant of Cu2O

The mechanisms responsible for the nucleation, growth and coarsening of Al₂O₃ particles in dilute Cu–Al alloys during internal oxidation have been investigated, and the alumina morphologies produced have been studied by electron microscopy using two-stage preshadowed carbon replica method. The alumina particle size has been observed to increase with increasing temperature of oxidation, with increasing time of oxidation, and with decreasing oxygen resource coefficient over the experimental range. These results indicate that the alumina particle size is determined by a competition between the rate of nucleation as the internal oxidation front passes and the subsequent growth and coarsening rates of the particles.     

Research on Processes and Adhesion of Electroless Plating Ni-Cu-P Coating

In order to improve the corrosion and wear resistance of the coatings of electroless plating Ni-Cu-P and broaden its application, an optimizing mathematical theory test has been applied in this research. The processing parameters have been optimized and some Ni-Cu-P coatings have been obtained with smooth and glittering appearance. At the same time,the composite complexants can prevent copper from depositing first and obtain coatings with strong adhesion. The porosity of Ni-Cu-P coating (20 μm) ranked class 9. The changing color time of the coating is more than 800 seconds with HNO3 dropthan 0.5 g/L. The surface appearance of deposition is typical cystiform cells by SEM,which rank close and neatly.     

The Influence of Nitrogen and Boron Implant into Silicon Substrate on the Phase and Internal Stress of c-BN Films

Cubic boron nitride(c-BN) film was deposited on a Si (100) substrate by the RF-magnetron sputtering.The mainly problems for fabrication of c-BN films are the low purity and high intrinsic compressive stress. In order to solve the two problems, the c-BN film with the buffer interlayer was deposited on the substrate which had been implanted with nitrogen and/or boron ions. The results show: the implantation of nitrogen ions can obviously increase c-BN content and reduce the internal stress slightly; while the implantation of boron shows no obvious improvement to the content of c-BN, which can reduce the internal stress in the film obviously. In addition, it is suggested that the implantation of nitrogen and boron shows the best result, which not only can increase the content of c-BN, but also reduce the internal stress in the c-BN film obviously.     

The Study of Low Surface Energy Fluorocarbon Coatings with Fluor Content Being Lower

A kind of low surface energy fluorocarbon coatings from the synthesized fluoro-acrylic resin was developed.The molecule orientation principle of nonpolar and polar functional groups in the coatings was analyzed. The contact angles of pure water drops on the surfaces of various fluoro-monomer homopolymers and interpolymers were measured. The relation of coatings' fluoro-content with the surface energy was determined. The distribution of fluoric functional groups in the coatings was investigated. The test results show that though the total content of fluor of the fluorocarbon coatings is relative few, their surface energy is really low due to the enrichment of fluoro-chains on the surfaces.     

A review of anode materials development in solid oxide fuel cells

High temperature solid oxide fuel cell (SOFC) has prospect and potential to generate electricity from fossil fuels with high efficiency and very low greenhouse gas emissions as compared to traditional thermal power plants. In the last 10 years, there has been significant progress in the materials development and stack technologies in SOFC. The objective of this paper is to review the development of anode materials in SOFC from the viewpoint of materials microstructure and performance associated with the fabrication and optimization processes. Latest development and achievement in the Ni/Y₂O₃-ZrO₂ (Ni/YSZ) cermet anodes, alternative and conducting oxide anodes and anode-supported substrate materials are presented. Challenges and research trends based on the fundamental understanding of the materials science and engineering for the anode development for the commercially viable SOFC technologies are discussed.     

软化学法合成层状结构LiMnO2阴极材料

研究了以氢氧化锂和醋酸锰为原料,用软化学法制备锂离子蓄电池阴极材料LiMnO2。用X射线衍射法确定了材料的结构及其结构转变,结合循环伏安法研究了材料组织结构与电化学性能之间的关系。实验结果显示,层状结构LiMnO2的最佳热合成温度是600 ℃,随着温度升高,材料由层状结构向尖晶石结构转变,层状结构中Mn原子的最密排原子面(003)重排成为尖晶石结构的(111)面;而部分层状结构材料(104)原子面上的Li原子发生转移,Mn原子重排形成尖晶石LiMn2O4的(400)原子面,这两个原子面的面间距不一样,造成XRD图谱上(104)峰的位置上出现新的衍射峰,并且由于原子面上原子种类和排布方式的不同,衍射峰强度也发生变化。热处理温度升高,使材料中相伴出现杂相Li2MnO3和尖晶石型的LiMn2O4,破坏材料的层状结构,降低电化学性能。     

110kV及以上高压电缆工程建设管理探讨

城市110kV及以上高压电缆的敷设里程迅速增长,在供电系统中负担起越来越重要的任务。为保证高压电缆工程的建设质量,建设者需要对电缆的技术特点、对工程施工管理有较深入的了解,采取科学的工程管理方法,才能提高高压电缆工程建设质量,满足电力系统供电可靠性的要求。     

功能性丝素共混膜的研究现状与进展

丝素是一种性能优良的天然高分子，在生物、医药等很多方面有着广泛的应用。本文综述了国内外学者在丝素的结构、性能尤其在共混方面的研究及成果。     

《电路与电子技术》课程教学方法的改革

电路与电子技术基础是计算机类专业一门重要课程,课程内容涉及面广且较复杂,包含了电路和电子技术的知识。通过对该课程在教学方法、辅导方式、实践技能培养和考核方式的改革,利用有限的学时完成该课程的教学任务,不但了提高课程教学质量,而且提高了学生的综合思维和分析问题、解决问题的能力。     

板坯连铸中间包钢液洁净度的水力学模拟和应用

为改善太钢 10 4 0mm× 16 0mm连铸不锈钢板坯质量 ,通过水力学模拟研究了中间包内钢液的流动 ,并用直径 0 .5～ 1.0mm ,密度 0 .99mg/mm3 的聚苯乙烯塑料粒子模拟钢中直径 5 0～ 10 0 μm夹杂物的排除情况 ,确定了在中间包内设置挡渣墙和坝流控制方案 ,并进行 4 0 9不锈钢 10 4 0mm× 16 0mm连铸板的工业试验 ,结果表明 :中间包设置挡渣墙和坝后 ,铸坯夹杂物总量比中间包无控流装置生产的铸坯降低 6 6 %。