Chemical analysis of ozonized theobroma fat

Ozonized theobroma fat is used as raw material in the manufacture of pessaries and cosmetic creams. Ozonization of theobroma fat with water was carried out at different applied ozone dosages, and the resultant PV, acid value, iodine value, total hydroperoxide content, and FA content were determined. PV and total hydroperoxide content showed a notable increase with applied ozone dosage up to 35.7 mg/g. Acid value varied slightly from 4.1 to 9.9 mg KOH/g, and the iodine value fell to zero. PV and total hydroperoxide content increased slightly with a higher applied ozone dosage. The comparison of total hydroperoxide measurement using ferrous oxidation in xylenol orange assay and traditional iodometric assay for PV determination showed a significant linear correlation. Small amounts of oleic acid were found in ozonized theobroma fat samples with iodine value equaling zero, which demonstrated that iodine value determination is an inexact assay. During ozonization of theobroma fat, an increase in acid value of 18.9-fold with respect to the initial value was observed owing to decomposition of peroxide.     

Data collection in global software engineering research: learning from past experience

Global Software Engineering has become a standard in today’s software industry. Research in distributed software development poses severe challenges that are due to the spatial and temporal distribution of the actors, as well as to language, intercultural and organizational aspects. These challenges occur in addition to “traditional” challenges of the domain itself in large-scale software projects, like coordination and communication issues, requirements volatily, lack of domain knowledge, among others. While several authors have reported empirical studies of global software development projects, the methodological difficulties and challenges of this type of studies have not been sufficiently discussed. In this paper, we share our experiences of collecting and analysing qualitative data in the context of Global Software Engineering projects. We discuss strategies for gaining access to field sites, building trust and documenting distributed and complex work practices in the context of several research projects we have conducted in the past 9 years. The experiences described in this paper illustrate the need to deal with fundamental problems, such as understanding local languages and different cultures, observing synchronous interaction, or dealing with barriers imposed by political conflicts between the sites. Based on our findings, we discuss some practical implications and strategies that can be used by other researchers and provide some recommendations for future research in methodological aspects of Global Software Engineering.     

Enantiospecific synthesis of (R)-1,7-dioxaspiro [5.5]undecane [major component of olive fruit fly (Dacus Oleae) sex pheromone] from d-Fructose

The synthesis of the title compound13 has been carried out through the preparation of its precursor, (3R,4R,5S,6R)-3,4,5-trihydroxy-1,7-dioxaspiro[5.5]undecane (6), obtained fromd-fructose using Wittig's methodology, reduction, and spiroketalation. Compound6 was transformed into13 by a Barton deoxygenation at C-5 followed by a Corey dideoxygenation at C-3,4 of the appropriately protected derivatives.Enantiospecific synthesis of spiroacetals. Part II. For Part I, see Izquierdo and Plaza (1990).     

An investigation of the synergistic effect between magnetite nanoparticles and polypyrrole in nanostructured layer-by-layer films

In this paper, we report the controlled fabrication of layer-by-layer (LbL) films deposited on gold substrates with three different supramolecular architectures using polypyrrole (Ppy) and magnetite nanoparticles (Fe₃O₄-np), besides conventional poly(allylamine hydrochloride) (PAH) e poly(vinyl sulfonic acid) (PVS) polyelectrolytes, demonstrating the synergistic effect between Ppy and Fe₃O₄-np such as a result of their interaction. Modified gold electrodes were analyzed by contact angle (wettability), surface plasmon resonance (SPR), raman spectroscopy, cyclic voltammetry, and electrochemical impedance spectroscopy. The (Fe₃O₄-np/Ppy)₃ architecture was also evaluated by scanning electron microscopy. The modified gold electrodes present more homogeneous covering, higher electron transfer and a decrease of resistance with the incorporation of the nanostructured materials such as Ppy and Fe₃O₄-np forming (Fe₃O₄-np/Ppy)₃ LbL film. The results carried out in this study suggest that the (Fe₃O₄-np/Ppy)₃ LbL film can be applied as a possible electrochemical or optical non-enzymatic sensor for analytical detection.     

Aramid pulp treated with imidazolium ionic liquids as a filler in rigid polyurethane bio-foams

This article reports an aramid pulp (AP) treated with two ionic liquids (IL), namely 1-n-butyl-3-methylimidazolium chloride (C₄.Cl) and 1-carboxymethyl-3-methylimidazolium chloride (HO₂C), and its use as a filler in reinforced rigid polyurethane foams (RPUF). The RPUF were incorporated with the treated AP at three weight fractions (c.a. 0.1, 0.5, and 1.0 wt%) and were produced by the free rising method. The results showed that the studied IL promoted a better interaction between the AP and the RPUF system, which increased the overall reactivity, imparting a higher cell anisotropy. This also yielded a positive effect in mechanical properties and thermal stability of the RPUF. Compared to the neat RPUF, outstanding increases of approximately 50 and 20% were achieved in compressive modulus and strength, respectively. In all, the use of IL promoted increased compatibility between matrix and reinforcement, especially that HO₂C IL.     

An approach based on current and sound signals for in-process tool wear monitoring

This paper presents a tool condition monitoring system (TCMS) for on-line tool wear monitoring in turning. The proposed TCMS was developed taking into account the necessary trade-off between cost and performance to be applicable in practice, in addition to a high success rate. The monitoring signals were the feed motor current and the sound signal. The former was used to estimate the feed cutting force using the least squares version of support vector machines (LS-SVM). Singular spectrum analysis (SSA) was used to extract information correlated with tool wear from the sound signal. The estimated feed cutting force and the SSA decomposition of the sound signal alone with the cutting conditions constitute the input data to the TCMS. Again LS-SVM was used to estimate tool condition and its reliability for on-line implementation was validated by experiments using AISI 1040 steel. The results showed that the proposed TCMS is fast and reliable for tool condition monitoring.     

Effect of rinsing and drying on silicon surface cleaning for epitaxial growth

We investigated the effect of the rinsing and drying technique on the oxygen and carbon concentration on a silicon surface. Rinsing in deionized water increased the interfacial oxygen concentration and helped generate defects. Blow-drying was more efficient than spin-drying in reducing interfacial oxygen concentration. Exposure to the atmosphere was detrimental to obtaining high crystallinity in the epitaxial layer. We evaluated the effectiveness of the cleaning process by observing the grown epilayer and the epilayer/substrate interface.     

Factors of low individual degree polynomials

Kaltofen (Randomness in computation, vol 5, pp 375–412, 1989) proved the remarkable fact that multivariate polynomial factorization can be done efficiently, in randomized polynomial time. Still, more than twenty years after Kaltofen’s work, many questions remain unanswered regarding the complexity aspects of polynomial factorization, such as the question of whether factors of polynomials efficiently computed by arithmetic formulas also have small arithmetic formulas, asked in Kopparty et al. (2014), and the question of bounding the depth of the circuits computing the factors of a polynomial. We are able to answer these questions in the affirmative for the interesting class of polynomials of bounded individual degrees, which contains polynomials such as the determinant and the permanent. We show that if \({P(x_{1},\ldots,x_{n})}\) is a polynomial with individual degrees bounded by r that can be computed by a formula of size s and depth d, then any factor \({f(x_{1},\ldots, x_{n})}\) of \({P(x_{1},\ldots,x_{n})}\) can be computed by a formula of size \({\textsf{poly}((rn)^{r},s)}\) and depth d + 5. This partially answers the question above posed in Kopparty et al. (2014), who asked if this result holds without the dependence on r. Our work generalizes the main factorization theorem from Dvir et al. (SIAM J Comput 39(4):1279–1293, 2009), who proved it for the special case when the factors are of the form \({f(x_{1}, \ldots, x_{n}) \equiv x_{n} - g(x_{1}, \ldots, x_{n-1})}\). Along the way, we introduce several new technical ideas that could be of independent interest when studying arithmetic circuits (or formulas).