Effect of Maleic‐Anhydride Grafting on the Physical and Mechanical Properties of Poly(L‐lactic acid)/Starch Blends

MA is grafted onto both PLLA and starch in an internal mixer in the presence of DCP in a one‐step reactive compatibilization process. The effect of maleation of MA on the physical and mechanical properties and morphology of the blends was assessed. The onset decomposition temperature of the PLLA/starch blends decreased as the starch content increases due to the lower thermal stability of starch and the low effect of the maleation reaction on the thermal stability of the blends. PLLA/starch blends without grafted MA showed higher crystallinity as the starch content increased. Reactive compatibilized blends with less than 20 wt% starch had higher storage modulus, indicating that the compatibility between the two phases was improved.

     

Rubber Particles from Tires Out of Use as Toughness Modifiers of Epoxy-Based Thermosets

Rubber particles from tires out of use (TOU) were used to modify an epoxy-based thermoset. The effect of size and particle content were evaluated. Three bending point and Charpy tests were carried out to study the mechanical behavior of the materials. A steady decrease in the critical stress intensity factor, K_Ic, with the content of TOU was observed, being attributed to the fact that the particles might also act as defects in the polymer matrix. Fractographic analysis confirmed that filled specimens showed localized shear yielding at the end of the particles along the crack propagation direction. No signs of cavitation mechanism were found on the surfaces of fracture, evidencing an extraordinary interfacial adhesion. The total energy absorbed at break increased as the size of TOU particles decreased, pointing out that particle size is crucial for the performance of these materials. Matrix yielding and plastic deformation were considered to be the main toughness mechanisms.     

LINEAR PI TEMPERATURE-CONCENTRATION CASCADE CONTROL FOR TUBULAR REACTORS

In this article we explore the application of linear PI cascade control schemes to improve the performance of industrial PI/PID controllers for controlling outlet reactor concentration. By departing from simple I/O first-order dynamical models obtained from step responses, it is shown that the incorporation of a secondary loop for regulating the reactor temperature at a given interior position significantly improves the control performance in the face of feed composition and temperature disturbances. The effects of the temperature sensor location and the usage of multiple temperature measurements are also evaluated.     

Enhanced microbial oil production by activated sludge microorganisms via co‐fermentation of glucose and xylose

The co‐fermentation of glucose and xylose by activated sludge microorganisms for the production of microbial oils for use as biodiesel feedstock was investigated. Various carbon sources at initial concentration of 60 g/L and C:N ratio 70:1 were investigated: xylose, glucose, and 2:1 and 1:2 (by mass) glucose/xylose mixtures. Oil accumulation ranged between 12 to 22% CDW, the highest of which was obtained when xylose was the sole substrate used. Kinetic modeling of the fermentation data showed that specific growth and oil accumulation rates were similar in all substrate types and the lipid coefficient ranged from 0.02 to 0.06 g/g of sugar consumed. The fatty acid methyl ester yield and composition of the lipids showed their suitability for conversion to biodiesel. Based on the results, lignocellulose sugars could be used as fermentation substrates by activated sludge microorganisms for enhancing the oil content of sewage sludge for its use as a sustainable biofuel feedstock source. © 2013 American Institute of Chemical Engineers AIChE J, 59: 4036–4044, 2013     

Study,Mechanical Characterization and Mathematical Modeling of Compatible SEBS Blends for Industrial Applications in Orthopedics and Childcare

In this work, a system of compatible blends based on two commercial grades of a thermoplastic elastomer, styrene-ethylene/butylene-styrene (SEBS), with extreme Shore A hardness values (5 and 90), was studied in order to obtain a range of different performance blends for orthopedic and childcare applications, where usually liquid silicone rubber is used. Mechanical properties of different blends were obtained, and Equivalent Box Model (EBM) was used for the prediction of the mechanical behavior. The results show good agreement between the theoretical model and experimental data of new blends of SEBS.     

Internal Mass Transfer during Isothermal Drying of a Porous Solid Containing Multicomponent Liquid Mixtures

Abstract

Internal mass transfer in a porous solid partially saturated with multicomponent liquids has been experimentally and theoretically studied. Isothermal drying experiments were performed using a jacketed wind tunnel where the transient composition profiles and total liquid content of a cylindrical sample were determined. Sand samples wetted with the ternary liquid mixtures water-methanol-ethanol and 2-propanol-methanol-ethanol were dried at two different initial compositions and temperatures. A mathematical model including mass transfer by capillary movement of the liquid and interactive diffusion in both gas and liquid phase was developed. To simulate the capillary movement of liquid mixtures, parameters experimentally determined for single liquids where weighed according to liquid composition. A fairly good agreement between theoretical and experimental liquid composition profiles was obtained provided that axial dispersion is included in the model.     

Modeling of Drying Curves for Some Foodstuffs Using a Kinetic Equation of High Order

ABSTRACT

Non-linear regression was used to fit a high order kinetic model to drying curves for mango and cassava. For comparison purposes, the same experimental data were also adjusted by non-lines regression to a model based on exponential series, and to another exponential model by simple linear regression. The high order model fit the experimental data with higher precision (r2 Al.98) than the other exponential series models. The proposed higher order model is mathematically simple as compared to the exponential series, and could be used for simulation of drying processes.     

IrO2–SnO2 mixtures as electrocatalysts for the oxygen reduction reaction in alkaline media

In this work, SnO₂ + IrO₂ mixed oxides are studied as electrocatalysts for the oxygen reduction reaction (ORR) in alkaline media by means of voltammetric techniques under controlled mass transfer conditions thanks to the use of rotating (ring) disk electrodes (RDE/RRDE). The oxides, prepared by sol–gel methodology, are supported on the disk electrodes using a thin layer of anionic exchange polymer as gluing agent. The amount of deposited polymer was optimized to avoid any limitation due to the diffusion of reactant/products across the film thickness. The mixed oxides were prepared at the following mole fractions of IrO₂: $ x_{{{\text{IrO}}_{ 2} }} $  = 0.15, 0.31, 0.55, 0.73, and 1. The role of composition was studied in terms of the reaction pathways and the relevant fraction of H₂O₂ production, together with the potentials of the onset of ORR. The fraction of sites able to give proton/hydroxyl and electron transfers is also determined and discussed. The results point to the best performance of low-Ir containing mixtures and to their low sensitivity to the presence of methanol, a key feature in the case of crossover in alkaline direct alcohol fuel cells.