Deflections of Timoshenko beam with varying cross-section

Closed form solutions are presented for bending beams with linearly and (in the binomial form) parabolically varying depth and for bending beams with linearly varying width along the beam's length. The solutions are developed taking into account the shear deformation of the beam. The solutions are achieved, in an original way, by transforming the fourth-order differential equations with variable coefficients into fourth-order differential equations with constant coefficients. Though the solutions presented refer to three recurrent variations in the beam cross-section shape, the procedure outlined can be applied to beams with binomial variation (with any exponent) in the depth or width of the cross-section. Moreover, the solutions can be achieved for polynomial, exponential and sinusoidal load conditions. The solutions can be utilized to obtain the stiffness factors and the flexibility coefficients of beams in the analysis of frames. Closed form solutions for longitudinal displacements are also presented. The analytical solutions are applied to four recurrent beams commonly used in civil engineering practice and a comparison with a numerical procedure is made.     

Current methods for mycotoxins analysis and innovative strategies for their reduction in cereals: an overview

Mycotoxins are secondary metabolites produced by moulds in food that are considered a substantial issue in the context of food safety, due to their acute and chronic toxic effects on animals and humans. Therefore, new accurate methods for their identification and quantification are constantly developed in order to increase the performance of extraction, improve the accuracy of identification and reduce the limit of detection. At the same time, several industrial practices have shown the ability to reduce the level of mycotoxin contamination in food. In particular, a decrease in the amount of mycotoxins could result from standard processes naturally used for food processing or by procedures strategically introduced during processing, with the specific aim of reducing the amount of mycotoxins. In this review, the current methods adopted for accurate analyses of mycotoxins in cereals (aflatoxins, ochratoxins, trichothecenes, fumonisins) are discussed. In addition, both conventional and innovative strategies adopted to obtain safer finished products from common cereals intended for human consumption will be explored and analysed. © 2018 Society of Chemical Industry     

New insights into the psychological dimension of wood–human interaction

The effect a wooden-built environment exerts on the physical and psychological well-being of people has mostly been investigated by evaluation, through a limited number of sensory modalities, of small size stimuli. In this research, two real-size wooden and plaster indoor settings were used to examine the influence of wood on people’s emotions and perceptions. Three questionnaires assessed participants’ multimodal sensory, affective, and cognitive responses to the settings (Semantic Differential questionnaire), their emotional state (Positive and Negative Affect Schedule), and their environmental behaviour and biophilia degree (Nature Relatedness Scale). The results revealed that wood induces more positive emotions than plaster, and that individual biophilia degree appears to influence the tactile, auditory, and olfactory evaluation of the settings. It furthermore indicates how wood used in real buildings positively influences human psychological well-being and highlights the importance of considering multiple sensory modalities when investigating wood–human interaction.     

Occurrence of biogenic amine-forming lactic acid bacteria in wine and cider

A collection of 810 lactic acid bacteria (LAB) strains isolated from wine and cider was screened for potential biogenic amine (BA) producers by combining molecular and phenotypic approaches. A newly developed multiplex PCR method allowed for the simultaneous detection of four genes involved in the production of histamine (histidine decarboxylase, hdc), tyramine (tyrosine decarboxylase, tyrdc) and putrescine (via either ornithine decarboxylase, odc, or agmatine deiminase, agdi) while TLC and HPLC analysis allowed for BA-production determination. One hundred and fifty-eight LAB strains were monitored by the molecular/phenotypic double approach and revealed a good correlation between genotypic and phenotypic data. Eighteen per cent of the tested strains were positive for at least one BA target gene with up to three detected simultaneously, in particular amongst Lactobacillus brevis and Lactobacillus hilgardii isolates for the tyrdc and agdi genes. The most frequent gene corresponded to the agdi gene detected in 112 strains (14% of all LAB strains) of 10 different LAB species. The tyrdc gene was detected in 67 strains represented by 7 different LAB species (8% overall), especially those isolated from wine. Lower levels of hdc⁺ (2% of strains) and especially odc⁺ (0.5% of strains) strains were observed. Interestingly, species that have never been described to carry BA-producing pathway genes were identified in this study. Furthermore, only one cadaverine-producer was detected and corresponded to Lactobacillus 30a, a collection strain not found in fermented beverages, although cadaverine is commonly detected in wines.     

Metabolic profile and biological activities of Lavandula pedunculata subsp. lusitanica (Chaytor) Franco: Studies on the essential oil and polar extracts

We investigated the metabolic profile and biological activities of the essential oil and polar extracts of Lavandula pedunculata subsp. lusitanica (Chaytor) Franco collected in south Portugal. Gas chromatography–mass spectrometry (GC–MS) analysis revealed that oxygen-containing monoterpenes was the principal group of compounds identified in the essential oil. Camphor (40.6%) and fenchone (38.0%) were found as the major constituents. High-performance liquid chromatography with diode array detection (HPLC–DAD) analysis allowed the identification of hydroxycinnamic acids (3-O-caffeoylquinic, 4-O-caffeoylquinic, 5-O-caffeoylquinic and rosmarinic acids) and flavones (luteolin and apigenin) in the polar extracts, with rosmarinic acid being the main compound in most of them. The bioactive compounds from L. pedunculata polar extracts were the most efficient free-radical scavengers, Fe²⁺ chelators and inhibitors of malondialdehyde production, while the essential oil was the most active against acetylcholinesterase. Our results reveal that the subspecies of L. pedunculata studied is a potential source of active metabolites with a positive effect on human health.     

Detection of frozen salt in pipes using gamma-ray spectrometry of potassium self-activity

Solar plants that use molten salts as heat transfer fluid need careful control to avoid the freezing of the salt in the pipes; if such a problem occurs, a diagnostic instrument to localize where is the frozen salt plug and to determine its length is useful. If the salt contains potassium (as is the case of the most common mixture used in solar plants, NaNO₃/KNO₃ 60/40% by weight), the gamma decay of the natural unstable isotope ⁴⁰K can be exploited to detect the frozen salt in a non-invasive way. Simulations and experimental results regarding the detectability of such plugs with different masses/lengths are presented.     

Be radioactive beam production at CIRCE and its utilization in basic and applied physics

A pure ⁷Be beam with an energy E = 1-8 MeV is available for nuclear and applied physics at the 3 MV Pelletron tandem accelerator CIRCE in Caserta. The beam is produced using an offline technique. Typical analyzed beam intensities are about 2 ppA, using cathodes with an activity of the order of 200 MBq. The ⁷Be implantation has been used for both fundamental nuclear physics and applied physics. In particular, different metals have been implanted with ⁷Be in order to study the influence of the chemical composition and of the number of quasi-free electrons of the host material on the ⁷Be half-life. In the field of applied physics, the ⁷Be implantation turns out to be very interesting for wear measurement. In fact, in this case ⁷Be is used as a depth-sensitive tracer. The continuous detection of the sample activity during the wear allows a high sensitivity measurement of wearing speed. The ⁷Be beam production at CIRCE, the implantation procedure and the results obtained from the ⁷Be half-life measurements and the wear characterization of implanted steel samples are described.     

Hydrogen production by photoreforming of formic acid in aqueous copper/TiO2 suspensions under UV-simulated solar radiation at room temperature

A new photocatalytic system consisting of two subsystems – Cu⁰/Cl⁻/H⁺/UV_ssr and Cu^II/H⁺/TiO₂/formic acid/UV_ssr – is proposed as a tool to produce hydrogen by reforming an organic species. Formic acid is used as hole scavenger during the experimental runs. An experimental campaign is carried out to demonstrate that the systems can generate hydrogen and to assess how the generation rate depends upon experimental conditions such as copper and TiO₂ loads, chloride and proton ions, and formic acid concentrations. A strong dependence of the Cu⁰/Cl⁻/H⁺/UV_ssr subsystem reactivity upon copper load, chloride concentration and pH is observed. The investigation on the complete system, starting from zero-valent copper, indicates that the addition of TiO₂ and formic acid to the Cu⁰/Cl⁻/H⁺/UV_ssr subsystem does not result into any gain in terms of hydrogen produced and, renders the system totally unreactive under some conditions. On the other hand, when a complete system, starting from cupric ions, is adopted, hydrogen production is observed also for prolonged reaction times with a surplus of hydrogen production with respect to that generated by the Cu⁰/Cl⁻/H⁺/UV_ssr subsystem with the same Cu⁰ starting load and in absence of TiO₂ and sacrificial agent.     

Degradation of lincomycin in aqueous medium: Coupling of solar photocatalysis and membrane separation

The photocatalytic oxidation of a common antibiotic, the lincomycin was carried out in aqueous suspensions of polycrystalline TiO₂ Degussa P25 irradiated by sunlight. In order to improve the performance of the lincomycin degradation a hybrid system consisting of a solar photoreactor with the photocatalyst in suspension coupled with a membrane module, used to confine both photocatalyst and pollutants in the reaction environment, was tested.A preliminary study was carried out in order to determine some kinetics parameters of the drug photodegradation. The influence of initial substrate concentration on the lincomycin photooxidation rate was investigated. The photooxidation rate follows a pseudo-first order kinetics with respect to the lincomycin concentration under the used experimental conditions. The presence of the membrane reactor allows the catalyst separation and to operate in continuous mode as the membranes rejection for lincomycin and its oxidation products was quite high.